电芬顿降解活性艳红X3B的阳极影响因素

doi:10.3969/j.issn.0438-1157.2012.11.046

化工学报 ›› 2012, Vol. 63 ›› Issue (11): 3694-3699.DOI: 10.3969/j.issn.0438-1157.2012.11.046

电芬顿降解活性艳红X3B的阳极影响因素

胡晶晶, 莫文艳, 孙杰

中南民族大学化学与材料科学学院, 湖北武汉 430074

收稿日期:2012-03-16 修回日期:2012-05-24 出版日期:2012-11-05 发布日期:2012-11-05
通讯作者: 孙杰
作者简介:胡晶晶(1988-),女,硕士研究生。
基金资助:
国家自然科学基金项目(20807057);湖北省杰出青年基金项目(2011CDA106);武汉市工程中心计划项目(200950431227,201160638173)。

Anode effect on X3B degradation in electro-Fenton reaction

HU Jingjing, MO Wenyan, SUN Jie

College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074, Hubei, China

Received:2012-03-16 Revised:2012-05-24 Online:2012-11-05 Published:2012-11-05
Supported by:
supported by the National Natural Science Foundation of China(20807057),the Distinguished Young Foundation of Hubei Province(2011CDA106)and the Technology Centre Project of Wuhan City(200950431227,201160638173).

摘要/Abstract

摘要： 以钛基氧化锡纳米涂层(DSA)电极作为阳极,以活性炭纤维(ACF)作为阴极,与石墨板(GE)电极进行组合,形成三组不同的电极对,用于比较研究电芬顿反应中的阳极影响因素。降解模拟染料活性艳红X3B,其脱色率和矿化率均为:电极体系a(阴极/ACF,阳极/DSA)>b(阴极/ACF,阳极/GE)>c(阴极/GE,阳极/DSA)。其中最优电极体系a反应90 min完全脱色,180 min内矿化率和平均电流效率分别为75.3% 和56.7%。XRD和SEM表征表明:DSA电极和ACF电极在电芬顿反应中具有稳定的化学结构。循环伏安扫描的结果表明三组电极体系均无明显的阳极直接氧化反应发生。采用荧光法检测了活性氧化物种,发现三组电极体系生成羟基自由基的数量与其降解效果完全一致。本研究证明DSA 对于电芬顿反应有促进作用,并且这一促进作用是通过催化H₂O₂生成·OH 这一间接途径来实现的。

关键词: 电极, 电芬顿, 活性炭纤维, DSA电极, 染料

Abstract: To study anode effect on electro-Fenton reaction,three kinds of electrode,including SnO₂/Ti electrode with nanocoating(DSA),activated carbon fiber(ACF)and graphite paper(GE)were combined to form three electrode couples,and they were applied to degrade activated brilliant red X3B. The order of decoloration and mineralization rate for these various electrode couples are as follows:a(cathode/ACF,anode/DSA)>b(cathode/ACF,anode/GE)>c(cathode/GE,anode/DSA).Under the optimum conditions,for electrode couple a,X3B was decolored completely in 90 min,mineralization rate and average current efficiency(ACE)in 180 min were 75.3% and 56.7% respectively.XRD and SEM images implied that structure of ACF and DSA were stable for electro-Fenton reaction conditions.The CV curves of electrodes suggested that the direct anodic oxidation was not involved in electro-Fenton system.The flurosence method was used to detect oxidation activity species,the results indicated that result of X3B degradation was in proportional to amount of hydroxyl radical formed.The study demonstrated that DSA can enhance efficiency of electro-Fenton reaction by a pathway activating H₂O₂ to hydroxyl radical.

Key words: electrodes, electro-Fenton, ACF, DSA, dye

中图分类号:

胡晶晶, 莫文艳, 孙杰. 电芬顿降解活性艳红X3B的阳极影响因素[J]. 化工学报, 2012, 63(11): 3694-3699.

HU Jingjing, MO Wenyan, SUN Jie. Anode effect on X3B degradation in electro-Fenton reaction[J]. CIESC Journal, 2012, 63(11): 3694-3699.

参考文献 20

[1]	Qu Jiuhui(曲久辉),Liu Huijuan(刘会娟).Electrochemical Principles and Techniques of Water Treatment[M].Beijing:Science Press,2007:55-74
[2]	Ignasi S,Jose A G,Rosa M R,et al.Catalytic behavior of the Fe3+/Fe2+ system in the electro-Fenton degradation of the antimicrobial chlorophene[J].Applied Catalysis B:Environmental,2007,72:382-394
[3]	Losito I,Amorisco A,Palmisano F.Electro-Fenton and photocatalytic oxidation of phenyl-urea herbicides:an insight by liquid chromatography-electrospray ionization tandem mass spectrometry[J].Applied Catalysis B:Environmental,2008,79:224-236
[4]	Roberto A,Vincenzo C,Amedeo I.Advanced oxidation processes(AOP)for water purification and recovery[J].Catalysis Today,1999,53(1):51-59
[5]	Eloy I C,Jose A G,Rosa M R.Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes[J].J. Phys. Chem. A,2011,115:1234-1242
[6]	Sourour C E,Marco P,Giacomo C.Coumaric acid degradation by electro-Fenton process[J].Journal of Electroanalytical Chemistry,2012,667:19-23
[7]	Yuan S H,Fan Y,Zhang Y C.Pd-catalytic in situ generation of H2O2 from H2 and O2 produced by water electrolysis for the efficient electro-Fenton degradation of Rhodamine B[J].Environ. Sci. Technol.,2011,45:8514-8520
[8]	Jia J,Yang J,Hui J.Treatment of dyeing wastewater with ACF electrodes[J].Water Res.,1999,33(3):881-884
[9]	Wang Aimin(王爱民),Qu Jiuhui(曲久辉),Song Lingling(宋玲玲).Electro-chemical generation of hydroxyl radicals for acid red B degradation by activated carbon fiber eIectrodes[J].Acta Chimica Sinica(化学学报),2006,64(8):767-771
[10]	Gözmen B,Oturan M A,Oturan N,Erbatur O.Indirect electrochemical treatment of Bisphenol A in water via electrochemically generated Fenton’s reagent[J].Environ. Sci. Technol.,2003,37:3716-3723
[11]	Boye B,Dieng M M,Brillas E.Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods[J].Environ. Sci. Technol.,2002,36:3030-3035
[12]	Feng Y.Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution[J].Water Research,2003,37(10):2399-2407
[13]	Brian A,Tian M,Chen A.Design and electrochemical study of SnO2-based mixed oxide electrodes[J].Electrochimica Acta,2009,54(5):1491-1498
[14]	Wang Xunhua(王勋华),Zhou Qi(周琦),Zhang Rong(张蓉),Tong Shaoping(童少平),Ma Chun’an(马淳安).Preparation of Ti/CeO2-PT FE-PbO2 electrode and its electrooxidation performance[J].CIESC Journal(化工学报),2010,61(5):1190-1195
[15]	Chen A,Stephanie N.Influence of a nanoscale gold thin layer on Ti/SnO2-Sb2O5 electrodes[J].J. Phys. Chem. B,2003,107(48):13341-13348
[16]	Chu Yanyang(褚衍洋),Wang Meng(王蒙).Decomposition of H2O2 caused by Ti-based oxide electrode and its influence on oxidation of aniline[J].CIESC Journal(化工学报),2010,61(3):761-766
[17]	Kim J,Lee C,Choi W.Platinized WO3 as an environmental photocatalyst that generates ·OH radicals under visiblelight[J].Environ. Sci. Technol.,2010,44(17):6849-6854
[18]	Sun Jie(孙杰),Yan Xin(闫欣),Pan Huimin(潘慧敏).Catalytic degradation of X3B by titanium dioxide nanotubes with different light source[J].SCUN Journal(中南民族大学学报自科版),2010,30(3):7-9
[19]	Su R,Sun J,Sun Y,Deng K,Cha D,Wang D.Oxidative degradation of dye pollutants over a broad pH range using hydrogen peroxide catalyzed by FePz(dtnCl2)4[J].Chemosphere,2009,77:1146-1151
[20]	Do J S,Yeh W C.Paired electrooxidative degradation of phenol with in situ electrogenerated hydrogen peroxide and hypochlorite[J].J. Appl. Electrochem.,1996,26:673-678

电芬顿降解活性艳红X3B的阳极影响因素

Anode effect on X3B degradation in electro-Fenton reaction

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 20

相关文章 15

编辑推荐

Metrics

本文评价

[1]	何汉兵, 刘真, 陈勇, 王小锋, 曾婧. 直写成型电极锰氧化物粉末的合成与浆料调控[J]. 化工学报, 2023, 74(5): 2239-2247.
[2]	徐东, 田杜, 陈龙, 张禹, 尤庆亮, 胡成龙, 陈韶云, 陈建. 聚苯胺/二氧化锰/聚吡咯复合纳米球的制备及其电化学储能性[J]. 化工学报, 2023, 74(3): 1379-1389.
[3]	苏晨昱, 杨颖, 宋兴福. 岩盐矿提钾老卤中溴离子选择性电氧化过程研究[J]. 化工学报, 2022, 73(7): 3007-3017.
[4]	张文静, 李静, 魏子栋. 介尺度视角下的电催化：从界面、隔膜到多孔电极[J]. 化工学报, 2022, 73(6): 2289-2305.
[5]	黄盼, 练成, 刘洪来. 基于模拟退火算法的真实多孔电极中热-质传递的研究[J]. 化工学报, 2022, 73(6): 2529-2542.
[6]	任玉鑫, 徐润峰, 王婉颖, 陈鹏忠, 彭孝军. 彩色光刻胶用蒽醌染料的合成及稳定性研究[J]. 化工学报, 2022, 73(5): 2251-2261.
[7]	王祺, 房阔, 贺聪慧, 王凯军. 流动电极电容去离子技术综述：研究进展与未来挑战[J]. 化工学报, 2022, 73(3): 975-989.
[8]	王兵兵, 王超, 徐志明. 圆筒电极抑制换热表面CaCO₃污垢沉积特性研究[J]. 化工学报, 2022, 73(2): 634-642.
[9]	张兰河, 汪露, 李梓萌, 唐宏, 郭静波, 贾艳萍, 张明爽. 电极超滤膜生物反应器处理阴离子表面活性剂废水[J]. 化工学报, 2022, 73(10): 4679-4691.
[10]	朱晓兵, 李佳佳, 李怡宁, 杨洪月, 李小松, 刘景林. 氧化锰电催化析氧反应及其电极界面特性[J]. 化工学报, 2021, 72(S1): 398-405.
[11]	张晓, 纪志永, 汪婧, 郭小甫, 刘杰, 赵颖颖, 袁俊生. 电氧化法地下卤水提溴探究及条件优化[J]. 化工学报, 2021, 72(4): 2123-2131.
[12]	唐志强, 石雨, 张亮, 李俊, 付乾, 朱恂, 廖强. 不同基底材料复合电极对热再生氨电池产电性能的影响[J]. 化工学报, 2021, 72(3): 1667-1674.
[13]	王法军, 黄晋培, 徐建鸿. 微反应器内红色基KD重氮化反应动力学研究[J]. 化工学报, 2021, 72(2): 984-992.
[14]	曹佳宁, 高翔, 罗英武, 苏荣欣. 一种用于磷酸铁锂电极的水性黏结剂制备与性能研究[J]. 化工学报, 2021, 72(2): 1169-1180.
[15]	王培灿, 万磊, 徐子昂, 许琴, 王保国. 碱性膜电解水制氢技术现状与展望[J]. 化工学报, 2021, 72(12): 6161-6175.