海水压力对深海用环氧涂层防护性能的影响

doi:10.11949/j.issn.0438-1157.20150427

化工学报 ›› 2015, Vol. 66 ›› Issue (11): 4572-4577.DOI: 10.11949/j.issn.0438-1157.20150427

海水压力对深海用环氧涂层防护性能的影响

高瑾¹, 钱海燕¹, 孙晓华¹, 郭为民², 李晓刚¹

1 北京科技大学腐蚀与防护中心, 北京 100083;
2 中船重工七二五所青岛分部海洋腐蚀与防护国防科技重点实验室, 山东青岛 266101

收稿日期:2015-04-07 修回日期:2015-07-24 出版日期:2015-11-05 发布日期:2015-11-05
通讯作者: 髙瑾
基金资助:
国家重点基础研究发展计划项目(2014CB643300);国家自然科学基金项目(51071027)。

Effect of seawater pressure on protection properties of epoxy coatingused in deep sea

GAO Jin¹, QIAN Haiyan¹, SUN Xiaohua¹, GUO Weimin², LI Xiaogang¹

1 Corrosion and Protection Center, University of Science &Technology Beijing, Beijing 100083, China;
2 State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, Shandong, China

Received:2015-04-07 Revised:2015-07-24 Online:2015-11-05 Published:2015-11-05
Supported by:
supported by the National Basic Research Program of China (2014CB643300) and the National Natural Science Foundation of China (51071027).

摘要/Abstract

摘要：

采用电化学阻抗谱(EIS)技术与局部交流阻抗技术(LEIS)研究了深海环境用重防腐环氧涂层H44-61在深海模拟环境(青岛海水,常压以及6 MPa交变压力)下的腐蚀电化学行为,探讨了交变压力对深海用涂层防护性能的影响。结果表明,涂层在6 MPa交变压力下的涂层电容较常压下高且涂层电阻较低,涂层的防护性能下降,但低频阻抗膜值均在10⁷ Ω·cm²以上,说明涂层仍有较好的防护性能;LEIS的研究表明交变压力下人造缺陷区域的阻抗值较小,缺陷周围涂层的剥离面积较大,说明压力交变能加快电解质溶液向涂层金属界面扩散,加速涂层下金属的腐蚀过程,降低涂层的防护性能。

关键词: 腐蚀, 环氧涂层, 交变压力, 电化学, LEIS

Abstract:

The electrochemical corrosion behavior of the epoxy heavy-duty coating immersed in seawater under the alternating pressure was investigated by electrochemical impedance spectroscopy (EIS) and local electrochemical impedance spectroscopy(LEIS). The results showed that compared with atmospheric pressure, the coating resistance was lower, but the coating capacitance was higher under the alternating pressure. The coating resistance remained above 10⁷ Ω·cm², showing that both coatings had good protective properties. The impedance around the defect region of the coating systems with artificial point defects was lower under the alternating pressure. It indicated that the permeation process of the electrolyte solution to the coating metal interface was easier under the alternating pressure, accelerating the corrosion of the steel under the coatings.

Key words: corrosion, epoxy coating, alternating pressure, electrochemistry, LEIS

中图分类号:

TG174.4

高瑾, 钱海燕, 孙晓华, 郭为民, 李晓刚. 海水压力对深海用环氧涂层防护性能的影响[J]. 化工学报, 2015, 66(11): 4572-4577.

GAO Jin, QIAN Haiyan, SUN Xiaohua, GUO Weimin, LI Xiaogang. Effect of seawater pressure on protection properties of epoxy coatingused in deep sea[J]. CIESC Journal, 2015, 66(11): 4572-4577.

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海水压力对深海用环氧涂层防护性能的影响

Effect of seawater pressure on protection properties of epoxy coatingused in deep sea

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