固体颗粒对流化床多相蒸发海水淡化操作浓缩比及膜传热系数的影响

doi:10.3969/j.issn.0438-1157.2012.08.008

化工学报 ›› 2012, Vol. 63 ›› Issue (8): 2392-2397.DOI: 10.3969/j.issn.0438-1157.2012.08.008

固体颗粒对流化床多相蒸发海水淡化操作浓缩比及膜传热系数的影响

弓凯雷1,2,王德武1,刘燕2,张少峰2

1河北工业大学化工学院，天津 300130；2河北工业大学海水资源高效利用化工技术教育部工程研究中心，天津 300130

收稿日期:2012-01-16 修回日期:2012-03-15 出版日期:2012-08-05 发布日期:2012-08-05
通讯作者: 张少峰

Effects of solid particles on experimental concentration factor of seawater desalination and film heat transfer coefficient in fluidized bed with multi-phase evaporation

GONG Kailei1，2，WANG Dewu1，LIU Yan2，ZHANG Shaofeng2

Received:2012-01-16 Revised:2012-03-15 Online:2012-08-05 Published:2012-08-05
Contact: GONG Kailei

摘要/Abstract

摘要： 提高海水淡化操作浓缩比，不仅可以提高造水比，还可以有效降低淡化后浓海水再利用的后处理成本，故其是实现低成本零排放的关键之一。在一套循环流化床多相蒸发海水淡化实验装置上，分别采用汽-液两相及汽-液-固三相操作，考察固体颗粒对海水淡化操作浓缩比及膜传热系数的影响，并分析垢层的主要成分。实验表明：高温下CaSO4首先析出，是形成垢层的主要成分；采取汽-液两相操作，膜传热系数保持在1.75 kW·m-2·K-1左右，操作浓缩比可达到3.8左右；采取汽-液-固三相操作，固体颗粒强化传热和防除垢的作用显著，加入颗粒体积分数为4%时，在膜传热系数保持在2.3 kW·m-2·K-1左右不降低的情况下，海水淡化操作浓缩比达到5.8以上。

关键词: 海水淡化, 循环流化床, 蒸发, 浓缩比, 防除垢

Abstract: Increasing seawater desalination concentration factor can improve the performance ratio and effectively reduce the post-treatment cost of the concentrated seawater that is reused，therefore，it is one of the keys to realizing low-cost zero discharge of seawater desalination.The experiment was carried out in a multi-phase circulating fluidization bed(CFB)evaporator.It aimed to study the effects of particle volume fraction on seawater desalination concentration factor and film heat transfer coefficient.The main components of the scaling were also analyzed.The operations of vapor-liquid two-phase boiling flow and vapor-liquid-solid three-phase boiling flow were investigated in the experiment.The results showed that calcium sulfate is the main component of the scaling，and it was firstly separated out in the seawater desalination experiment.In the vapor-liquid two-phase boiling flow，the film heat transfer coefficient was kept at 1.75 kW·m-2·K-1 and concentration factor reached 3.8.In the vapor-liquid-solid three-phase boiling flow，the result revealed that solid particles remarkably enhanced heat transfer and improved the prevention and removal of fouling.When particle volume fraction was 4% and film heat transfer coefficient was kept at 2.3 kW·m-2·K-1，seawater desalination concentration factor reached more than 5.8.

Key words: seawater desalination, circulating fluidized bed, evaporator, concentration factor, preventing and removing fouling

弓凯雷1,2,王德武1,刘燕2,张少峰2. 固体颗粒对流化床多相蒸发海水淡化操作浓缩比及膜传热系数的影响[J]. 化工学报, 2012, 63(8): 2392-2397.

GONG Kailei1，2，WANG Dewu1，LIU Yan2，ZHANG Shaofeng2. Effects of solid particles on experimental concentration factor of seawater desalination and film heat transfer coefficient in fluidized bed with multi-phase evaporation[J]. CIESC Journal, 2012, 63(8): 2392-2397.

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固体颗粒对流化床多相蒸发海水淡化操作浓缩比及膜传热系数的影响

Effects of solid particles on experimental concentration factor of seawater desalination and film heat transfer coefficient in fluidized bed with multi-phase evaporation

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