金属配合物配体上离子取代基对其部分催化性能影响的研究进展

doi:10.3969/j.issn.0438-1157.2013.01.022

摘要/Abstract

摘要： 常规有机取代基在调节催化剂活性方面已经得到广泛的应用与研究。近年来常被用于回收均相催化剂的离子取代基也逐渐被用于调节催化剂的活性。本文着重综述了近十年来离子取代基在调节金属配合物部分催化剂活性方面的研究进展,同时指出了目前离子取代基在调节催化剂催化性能方面存在的问题、挑战及发展方向。

关键词: 离子取代基, 金属配合物, 催化剂

Abstract: Conventional organic substituents on the ligand of metal complex catalysts have been widely used to tune their activities and selectivities.Recently, ionic substituents, which usually enable the homogeneous catalyst dissolve in water and be recovered, are also involved in improving the activity of catalyst.The research progress of how ionic substituents on the ligand of metal complex catalyst tuned its activity in the past decade is reviewed.Furthermore, the problems, challenges, and directions of this field are presented.

Key words: ionic substituent, metal complex, catalyst

中图分类号:

O643.36

胡敬辉, 姚加, 王从敏, 陈志荣, 李浩然. 金属配合物配体上离子取代基对其部分催化性能影响的研究进展[J]. 化工学报, 2013, 64(1): 198-209.

HU Jinghui, YAO Jia, WANG Congmin, CHEN Zhirong, LI Haoran. Research progress of metal complex catalysts with ionic substituents on ligand[J]. CIESC Journal, 2013, 64(1): 198-209.

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