超支化聚酯的端基改性及其涂膜性能

doi:10.3969/j.issn.0438-1157.2013.06.045

化工学报 ›› 2013, Vol. 64 ›› Issue (6): 2240-2246.DOI: 10.3969/j.issn.0438-1157.2013.06.045

• 材料化学工程与纳米技术 • 上一篇下一篇

超支化聚酯的端基改性及其涂膜性能

王勇¹, 朱延安², 瞿金清¹

1. 华南理工大学化学与化工学院,广东广州 510640;
2. 嘉宝莉化工集团股份有限公司,广东江门 529085

收稿日期:2012-09-20 修回日期:2013-01-09 出版日期:2013-06-05 发布日期:2013-06-05
通讯作者: 瞿金清
作者简介:王勇(1988—),男,硕士研究生。

Modification of end groups of hyperbranched polyester and its film properties

WANG Yong¹, ZHU Yan'an², QU Jinqing¹

1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China;
2. Carpoly Chemical Group Co.Ltd., Jiangmen 529085, Guangdong, China

Received:2012-09-20 Revised:2013-01-09 Online:2013-06-05 Published:2013-06-05

摘要/Abstract

摘要： 以三羟甲基丙烷为核多元醇,二羟甲基丙酸为AB₂型单体,对甲苯磺酸为催化剂准一步法合成了第二代超支化聚酯(HBP-0)。HBP-0分别经己内酯和月桂酸改性得到改性超支化聚酯(HBPs)。采用FT-IR、¹H NMR和GPC对HBP-0的结构和相对分子质量进行表征,发现超支化聚酯的支化度为0.43,相对分子量与理论相对分子量比较接近, 相对分子质量分布系数只有1.72。以甲苯二异氰酸酯加成物为交联剂,考察了改性超支化聚酯交联涂膜性能,结果表明,3种改性超支化聚酯的涂膜性能在光泽度、耐冲击性、附着力和柔韧性方面表现十分优异。其中HBP-3同时用己内酯和月桂酸改性具有最佳性能,黏度最低为7500 mPa·s,涂膜表干40 min,且硬度达到F。而单独用己内酯或月桂酸改性的HBP-1和HBP-2的相应数据分别为7×10⁵ mPa·s、20 min和HB及17500 mPa·s、90 min和2B。

关键词: 超支化聚酯, 己内酯, 涂膜性能, 黏度

Abstract: The second generation hyperbranched polyester (HBP-0) was synthesized by the pseudo-one step method with 2,2-bis (hydroxyl-methyl) propionic acid as AB₂ monomer, trimethylolpropane as core monomer and p-toluene sulfonic acid as catalyst.HBP-0 was modified with ε-caprolactone and lauric acid to prepare modified hyperbranched polyesters (HBP-1, HBP-2, and HBP-3).The structure and molecular weight of HBPs were characterized by FT-IR,¹H NMR and GPC.HBP-0 was synthesized with 0.43 degree of branching and its molecular weight approached the theoretical value and distribution factor was 1.72.The film properties of modified HBPs cured by toluene diisocyanate adduct were studied, and the results showed that the modified HBPs displayed excellent film properties in the gross, impact resistance, adhesion and flexibility.HBP-3 modified by both ε-caprolactone and lauric acid exhibited the best properties, including lowest viscosity up to 7500 mPa·s, surface drying time of 40 min and pencil hardness of F.While the corresponding data of HBP-1 and HBP-2 modified only by ε-caprolactone or lauric acid were 7×10⁵ mPa·s, 20 min and HB; 17500 mPa·s, 90 min and 2B, respectively.

Key words: hyperbranched polyester, ε-caprolactone, film properties, viscosity

中图分类号:

O633.14

王勇, 朱延安, 瞿金清. 超支化聚酯的端基改性及其涂膜性能[J]. 化工学报, 2013, 64(6): 2240-2246.

WANG Yong, ZHU Yan'an, QU Jinqing. Modification of end groups of hyperbranched polyester and its film properties[J]. CIESC Journal, 2013, 64(6): 2240-2246.

参考文献 16

[1]	Gao Kaiyuan(高开元), Zhang Aibo(张爱波), Luan Jingfan(栾静繁).Research progress and applications of hyperbranched polymer[J].Journal of Material Science and Engineering(材料科学与工程学报), 2010,28(1):152-155
[2]	Tomalia D A.Birth of a new macromolecular architecture:dendrimers as quantized building blocks for nanoscale synthetic polymer chemistry[J].Progress in Polymer Science, 2005,30:294-324
[3]	Ikladious N E, Mansour S H, Rozik N N, Dirnberger K,Eisenbach C D.New aliphatic hyperbranched polyester polyols based on 1,3,5-tris(2-hydroxyethyl)cyanuric acid as a core[J].Journal of Polymer Science Part B:Polymer Physics, 2008,46:5568-5579
[4]	Tong Shenyi(童身毅), Kou Yuxia(寇玉霞), Liu Xintai(刘新泰), Zeng Guangming(曾光明), Wen Jinsong(温晋嵩).Preparation and properties of amphiphilic hyperbranched poly(ester-amide)[J].Journal of Chemical Industry and Engineering(China)(化工学报), 2006,57(2):457-460
[5]	Luo Yunjun(罗运军), Xia Min(夏敏), Wang Xingyuan(王兴元).Hyperbranched Polyester(超支化聚酯)[M].Beijing:Chemical Industry Press, 2009
[6]	Wang Yanfei(王延飞), Shen Benxian(沈本贤), Zeng Qingjian(曾庆健),Jing Hongde(荆红德).Study on the properties of hyperbranched polymer modified alkyd resin[J].Shanghai Coatings(上海涂料),2006,44(4):1-3
[7]	Bat Erhan,Gunduz Gungor,Duygu Ksakurek,Idris M Akhmedov.Synthesis and characterizaton of hyper-branched and air drying fatty acid based resins[J].Progress in Organic Coatings,2006,55:330-336
[8]	Hong Xiaoyin,Chen Qidao,Zhang Yuemei,Liu Guangrong.Synthesis and characterization of a hyperbranched polyol with long flexible chains and its application in cationic UV curing[J].Journal of Appied Polymer Science,2000, 77:1353-1356
[9]	Smet Mario,Gottschalk Casten,Skaria Sunny,Frey Holger.Aliphatic hyperbranched copolyesters by combination of ROP and AB2-polycondensation[J].Macromolecular Chemistry and Physics, 2005,206:2421- 2428
[10]	Hua Chong, Peng Songming, Dong Changming.Synthesis and characterization of linear-dendron-like poly(ε-caprolactone)-b-poly(ethylene oxide)copolymers via the combination of ring-opening polymerization and click chemistry[J].Macromolecules, 2008,41:6686-6695
[11]	Edwin A M,Pedro P V,Betty L L.Effect of tall oil fatty acids content on the properties of novel hyperbranched alkyd resins[J].Journal of Applied Polymer Science,2011,120:3151-3158
[12]	Pion F,Kishore K J,Shaik A,Ramanuj N,Raju K V S N.Preparation and characterization of waterborne hyperbranched polyurethane-urea and their hybrid coatings[J].Industrial & Engineering Chemistry Research,2010,49(10):4517-4527
[13]	Ema Zagar, Majda Zijon.Aliphatic polyester based on 2,2-bis(methylol)propionic acid-determination of structure, solution and bulk properties[J].Progress in Polymer Science, 2011,36:53-88
[14]	Jena K, Raju K V S N, Prathab B, Aminabhavi T M. Hyperbranched polyesters:synthesis, characterization, and molecular simulations[J].Journal of Physical Chemistry B, 2007,111:8801-8811
[15]	Adam Kowalski, Jan Libiszowski, Tadeusz Biela, Marek Cypryk,Andrzej Duda, Stanislaw Penczek.Kinetics and mechanism of cyclic esters polymerization initiated with tin(Ⅱ)octoate polymerization of ε-caprolactone and L,L-lactide co-initiated with primary amines[J].Macromolecules, 2005,38:8170-8176
[16]	Hanselmann R, Holter D, Frey H.Hyperbranched polymers prepared via the core-dilution/slow addition technique:computer simulation of molecular weight distribution and degree of branching[J].Macromolecules,1998,31(12):3790- 3801

超支化聚酯的端基改性及其涂膜性能

Modification of end groups of hyperbranched polyester and its film properties

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 16

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘爽, 张霖宙, 许志明, 赵锁奇. 渣油及其组分黏度的分子层次组成关联研究[J]. 化工学报, 2023, 74(8): 3226-3241.
[2]	雷博雯, 吴建华, 吴启航. R290低压比热泵高补气过热度循环研究[J]. 化工学报, 2023, 74(5): 1875-1883.
[3]	周必茂, 许世森, 王肖肖, 刘刚, 李小宇, 任永强, 谭厚章. 烧嘴偏转角度对气化炉渣层分布特性的影响[J]. 化工学报, 2023, 74(5): 1939-1949.
[4]	张永泉, 玄伟伟. 碱金属/（FeO+CaO+MgO）对硅酸盐灰熔渣结构和黏度的影响机理[J]. 化工学报, 2023, 74(4): 1764-1771.
[5]	张家庆, 蒋榕培, 史伟康, 武博翔, 杨超, 刘朝晖. 煤基/石油基火箭煤油高参数黏温特性与组分特性研究[J]. 化工学报, 2023, 74(2): 653-665.
[6]	靳志远, 单国荣, 潘鹏举. AM/AMPS/SSS三元共聚物的制备及耐温耐盐性能[J]. 化工学报, 2023, 74(2): 916-923.
[7]	姚翰林, 辛忠. 液相沉淀反应在管式微通道反应器中的流动行为研究[J]. 化工学报, 2022, 73(8): 3518-3528.
[8]	朱晨阳, 刘向阳, 何茂刚, 陈光进. 基于Eyring绝对速率理论的流体混合物黏度推算[J]. 化工学报, 2022, 73(11): 4826-4837.
[9]	张家庆, 刘朝晖, 李宇, 宋晨阳. 碳氢燃料JP-10高温液态黏度测量和推算模型构建方法研究[J]. 化工学报, 2022, 73(1): 153-161.
[10]	许晨怡, 叶恭然, 郭豪文, 庄园, 郭智恺, 韩晓红, 陈光明. 制冷剂R1336mzz（E）液相黏度理论与实验研究[J]. 化工学报, 2021, 72(6): 3261-3269.
[11]	赵峻逸, 薛士东, 韩敬坤, 温荣福, 兰忠, 郝婷婷, 马学虎. 双液滴碰撞行为及调控机制的研究进展[J]. 化工学报, 2021, 72(5): 2354-2372.
[12]	朱倩倩, 靳海波, 郭晓燕, 何广湘, 马磊, 张荣月, 谷庆阳, 杨索和. H₂O₂/乙腈体系下MgO催化环己酮Baeyer-Villiger绿色氧化合成ε-己内酯的研究[J]. 化工学报, 2021, 72(5): 2638-2646.
[13]	曹燕,丁延,郭义仓,汪城,刘英杰,陶磊,李进龙. 溴化锂及离子液体水溶液密度、黏度和表面张力测定与计算[J]. 化工学报, 2021, 72(4): 1874-1884.
[14]	陈裕博, 杨昭, 武晓昆, 吕子建, 张勇. R513A的饱和液相黏度特性研究[J]. 化工学报, 2021, 72(11): 5502-5509.
[15]	沈中杰,郭晓镭,梁钦锋,刘海峰. 基于晶体生长及形貌的煤灰渣黏温模型[J]. 化工学报, 2021, 72(10): 5040-5052.