氨法碳捕集过程中氨逃逸控制

doi:10.3969/j.issn.0438-1157.2014.10.044

化工学报 ›› 2014, Vol. 65 ›› Issue (10): 4086-4093.DOI: 10.3969/j.issn.0438-1157.2014.10.044

氨法碳捕集过程中氨逃逸控制

马双忱, 陈公达, 马宵颖, 郭蒙, 韩停停, 宋卉卉

华北电力大学环境学院, 河北保定 071003

收稿日期:2014-03-24 修回日期:2014-06-21 出版日期:2014-10-05 发布日期:2014-10-05
通讯作者: 马双忱
基金资助:
中央高校基本科研业务费专项资金项目（2014ZD39，2014XS84）。

Ammonia escape control in carbon dioxide capture using ammonia method

MA Shuangchen, CHEN Gongda, MA Xiaoying, GUO Meng, HAN Tingting, SONG Huihui

School of Environment, North China Electric Power University, Baoding 071003, Hebei, China

Received:2014-03-24 Revised:2014-06-21 Online:2014-10-05 Published:2014-10-05
Supported by:
supported by the Fundamental Research Funds for the Central Universities of Ministry of Education of China(2014ZD39, 2014XS84).

摘要/Abstract

摘要： 本研究致力于解决再生氨法碳捕集过程中氨的逃逸问题。根据实验室前期研究结果，分别选取抑制效果较好的丙三醇和Co（Ⅱ）进行实验研究。详细分析了其抑制氨逃逸机制，并通过IR、XRD等对物种进行分析。同时探究其对再生氨法碳捕集过程CO₂脱除效率和解吸效果的影响。实验结果表明，丙三醇和Co（Ⅱ）对氨逃逸均有较好的抑制效果，平均抑氨效率在40%以上。二者的引入对吸收过程均无显著影响，且Co（Ⅱ）能使CO₂解吸比例提高。

关键词: 二氧化碳捕集, 氨法, 吸收, 控制

Abstract: This paper focuses on ammonia evaporation in ammonia-based CO₂ capture. Based on our previous research, glycerol and Co(Ⅱ) with promising effect on controlling ammonia escape were studied. The mechanisms of controlling ammonia escape using glycerol and Co(Ⅱ) were analyzed with IR, UV, XRD and the impact on CO₂ removal and desorption was investigated. Both glycerol and Co(Ⅱ) could control ammonia escape with average efficiency of above 40%. Glycerol and Co(Ⅱ) had no significant effect on absorption of carbon dioxide, while Co(Ⅱ) could promote desorption of CO₂.

Key words: CO₂ capture, ammonia method, evaporation, control

中图分类号:

X511

马双忱, 陈公达, 马宵颖, 郭蒙, 韩停停, 宋卉卉. 氨法碳捕集过程中氨逃逸控制[J]. 化工学报, 2014, 65(10): 4086-4093.

MA Shuangchen, CHEN Gongda, MA Xiaoying, GUO Meng, HAN Tingting, SONG Huihui. Ammonia escape control in carbon dioxide capture using ammonia method[J]. CIESC Journal, 2014, 65(10): 4086-4093.

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氨法碳捕集过程中氨逃逸控制

Ammonia escape control in carbon dioxide capture using ammonia method

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