含导电聚苯胺类锂离子电池复合材料的现状及发展趋势

doi:10.11949/j.issn.0438-1157.20170127

化工学报 ›› 2017, Vol. 68 ›› Issue (7): 2631-2640.DOI: 10.11949/j.issn.0438-1157.20170127

含导电聚苯胺类锂离子电池复合材料的现状及发展趋势

宋刘斌¹, 唐福利¹, 肖忠良¹, 李灵均², 曹忠¹, 胡超明¹, 刘姣¹, 李新宇¹

1 长沙理工大学化学与生物工程学院, 电力与交通材料保护湖南省重点实验室, 湖南长沙 410114;
2 长沙理工大学材料科学与工程学院, 湖南长沙 410114

收稿日期:2017-02-07 修回日期:2017-03-22 出版日期:2017-07-05 发布日期:2017-07-05
通讯作者: 肖忠良
基金资助:
国家自然科学基金项目（21501015，21545010，31527803）；中国科学院环境监测STS项目（KFJ-SW-STS-173）；湖南省自然科学基金项目（2016JJ3007）；湖南省科技计划项目（2015GK1046）。

Current status and development trend of conductive polyaniline lithium-ion battery composites

SONG Liubin¹, TANG Fuli¹, XIAO Zhongliang¹, LI Lingjun², CAO Zhong¹, HU Chaoming¹, LIU Jiao¹, LI Xinyu¹

1 Changsha University of Science and Technology, School of Chemistry and Biological Engineering, Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha 410114, Hunan, China;
2 Changsha University of Science and Technology, College of Materials Science and Engineering, Changsha 410114, Hunan, China

Received:2017-02-07 Revised:2017-03-22 Online:2017-07-05 Published:2017-07-05
Contact: 10.11949/j.issn.0438-1157.20170127
Supported by:
supported by the National Natural Science Foundation of China (21501015, 21545010, 31527803), the STS Project of the Chinese Academy of Sciences (KFJ-SW-STS-173), the Natural Science Foundation of Hunan Province (2016JJ3007) and the Scientific Program of Hunan Province (2015GK1046).

摘要/Abstract

摘要：

导电聚苯胺（PANI）是近十年来研究最多的导电聚合物，具有比容量高、氧化还原可逆性好、电导率高、合成方法简单、成本低等特点，在化学电源和超级电容器中的应用最为广泛。导电聚苯胺复合材料的合成方法主要分为：原位复合法、共混法、自组装和电化学复合法等。导电聚苯胺复合材料可作为高能物质用于研发电极材料，但目前利用导电聚苯胺对锂离子电池三元正极材料进行修饰改性的研究较少。综述了导电聚苯胺及其复合材料的热电化学性能，重点对导电聚苯胺/锂离子电池复合正极材料的性能进行了阐述。最后对导电聚苯胺复合材料的应用和研究方向进行了总结，并简述了导电聚苯胺包覆改性LiNi₁_-x-yCo_xMn_yO₂复合材料的应用和展望。

关键词: 导电聚苯胺, 锂离子电池, 复合材料, 电化学, 热力学

Abstract:

Conductive polyaniline is one of the most studied conductive polymers in recent ten years. It has the characteristics of high specific capacity, good redox reversibility, high conductivity, simple synthesis method, and low cost. It is the most widely used in chemical power supply and supercapacitor. The synthesis method of conductive polyaniline composite material is mainly divided into in situ composite method, blending method, self-assembly, electrochemical recombination method and so on. Conductive polyaniline composite can be used as a high-energy material to develop electrode materials, but there are few studies on the modification of the lithium-ion battery ternary cathode materials by using conductive polyaniline. The thermoelectric properties of conductive polyaniline and its composites are reviewed. The performance of conductive polyaniline/lithium ion battery composite cathode materials are discussed. Finally, the application and prospect of conductive polyaniline composites were summarized, and the application and prospect of conductive polyaniline coated modified LiNi₁_-x_-yCo_xMn_yO₂ composites were briefly introduced.

Key words: conductive polyaniline, lithium ion battery, composites, electrochemistry, thermodynamics

中图分类号:

TM912.9

宋刘斌, 唐福利, 肖忠良, 李灵均, 曹忠, 胡超明, 刘姣, 李新宇. 含导电聚苯胺类锂离子电池复合材料的现状及发展趋势[J]. 化工学报, 2017, 68(7): 2631-2640.

SONG Liubin, TANG Fuli, XIAO Zhongliang, LI Lingjun, CAO Zhong, HU Chaoming, LIU Jiao, LI Xinyu. Current status and development trend of conductive polyaniline lithium-ion battery composites[J]. CIESC Journal, 2017, 68(7): 2631-2640.

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含导电聚苯胺类锂离子电池复合材料的现状及发展趋势

Current status and development trend of conductive polyaniline lithium-ion battery composites

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