CIESC Journal ›› 2020, Vol. 71 ›› Issue (8): 3770-3779.DOI: 10.11949/0438-1157.20200126
• Energy and environmental engineering • Previous Articles Next Articles
Yongsheng ZHANG1,2(),Liang ZHANG1,2(),Jun LI1,2,Qian FU1,2,Xun ZHU1,2,Qiang LIAO1,2,Yu SHI1,2
Received:
2020-02-10
Revised:
2020-03-28
Online:
2020-08-05
Published:
2020-08-05
Contact:
Liang ZHANG
张永胜1,2(),张亮1,2(),李俊1,2,付乾1,2,朱恂1,2,廖强1,2,石雨1,2
通讯作者:
张亮
作者简介:
张永胜(1994—),男,硕士研究生,基金资助:
CLC Number:
Yongsheng ZHANG, Liang ZHANG, Jun LI, Qian FU, Xun ZHU, Qiang LIAO, Yu SHI. Numerical simulation of performance of thermally regenerative ammonia-based battery with copper foam electrode[J]. CIESC Journal, 2020, 71(8): 3770-3779.
张永胜, 张亮, 李俊, 付乾, 朱恂, 廖强, 石雨. 采用泡沫铜电极的热再生氨电池性能数值模拟[J]. 化工学报, 2020, 71(8): 3770-3779.
参数 | 符号 | 数值/mm |
---|---|---|
阳极腔室长度 | LAL | 30 |
阴极腔室长度 | LCL | 30 |
泡沫铜阳极厚度 | LAC | 4 |
泡沫铜阴极厚度 | LCC | 4 |
阴离子交换膜厚度 | LAEM | 1 |
电极高度 | H | 30 |
Table 1 Dimensional parameters of geometrical domain
参数 | 符号 | 数值/mm |
---|---|---|
阳极腔室长度 | LAL | 30 |
阴极腔室长度 | LCL | 30 |
泡沫铜阳极厚度 | LAC | 4 |
泡沫铜阴极厚度 | LCC | 4 |
阴离子交换膜厚度 | LAEM | 1 |
电极高度 | H | 30 |
参数 | 符号 | 数值 | 来源 |
---|---|---|---|
Cu2+扩散系数/(m2/s) | 1.5×10-9 | 文献[ | |
0.6 ×10-9 | 文献[ | ||
NH3扩散系数/ (m2/s) | 1.7×10-9 | 文献[ | |
0.95 ×10-9 | 文献[ | ||
电极孔隙率 | 0.9 | — | |
电极活性比表面积/ (m2/m3) | 4985 | 测量 | |
Cu2+参考浓度/ (mol/L) | 1 | — | |
操作温度/K | T | 298.15 | 测量 |
阳极电解质电导率/ (S/m) | 6.3 | 测量 | |
阴极电解质电导率/ (S/m) | 7.8 | 测量 | |
阳极反应速度常量/ (m/s) | 7 ×10-7 | 文献[ | |
阴极反应速度常量/(m/s) | 5 ×10-6 | 文献[ | |
Cu2+初始浓度/ (mol/L) | 0.1 | — | |
0.5 | — | ||
0.1 | — | ||
NH3?H2O初始浓度/ (mol/L) | 0.6 | — | |
反应(9)阴极传递系数 | 0.36 | — | |
反应(10)阴极传递系数 | 0.64 | — | |
0.5 | — | ||
0.5 | — |
Table 2 Parameters used in the model
参数 | 符号 | 数值 | 来源 |
---|---|---|---|
Cu2+扩散系数/(m2/s) | 1.5×10-9 | 文献[ | |
0.6 ×10-9 | 文献[ | ||
NH3扩散系数/ (m2/s) | 1.7×10-9 | 文献[ | |
0.95 ×10-9 | 文献[ | ||
电极孔隙率 | 0.9 | — | |
电极活性比表面积/ (m2/m3) | 4985 | 测量 | |
Cu2+参考浓度/ (mol/L) | 1 | — | |
操作温度/K | T | 298.15 | 测量 |
阳极电解质电导率/ (S/m) | 6.3 | 测量 | |
阴极电解质电导率/ (S/m) | 7.8 | 测量 | |
阳极反应速度常量/ (m/s) | 7 ×10-7 | 文献[ | |
阴极反应速度常量/(m/s) | 5 ×10-6 | 文献[ | |
Cu2+初始浓度/ (mol/L) | 0.1 | — | |
0.5 | — | ||
0.1 | — | ||
NH3?H2O初始浓度/ (mol/L) | 0.6 | — | |
反应(9)阴极传递系数 | 0.36 | — | |
反应(10)阴极传递系数 | 0.64 | — | |
0.5 | — | ||
0.5 | — |
源/汇 | 阳极 | 阴极 |
---|---|---|
S1( | 0 | |
S2( | 0 | |
S3( | 0 |
Table 3 Source items of the mass conservation equation
源/汇 | 阳极 | 阴极 |
---|---|---|
S1( | 0 | |
S2( | 0 | |
S3( | 0 |
硫酸铵浓度/(mol/L) | 阴极电解液电导率 | 阳极电解液电导率 |
---|---|---|
0.5 | 7.8 | 6.3 |
1 | 13.3 | 11.3 |
1.5 | 22 | 19.9 |
2 | 25.6 | 23.5 |
2.5 | 28.9 | 26.7 |
Table 4 Conductivity of the electrolyte with different concentration of (NH4)2SO4
硫酸铵浓度/(mol/L) | 阴极电解液电导率 | 阳极电解液电导率 |
---|---|---|
0.5 | 7.8 | 6.3 |
1 | 13.3 | 11.3 |
1.5 | 22 | 19.9 |
2 | 25.6 | 23.5 |
2.5 | 28.9 | 26.7 |
1 | Lu H Y, Price L, Zhang Q. Capturing the invisible resource: analysis of waste heat potential in Chinese industry[J]. Applied Energy, 2016, 161: 497-511. |
2 | Jouhara H, Khordehgah N, Almahmoud S, et al. Waste heat recovery technologies and applications[J]. Thermal Science and Engineering Progress, 2018, 6: 268-289. |
3 | Woolley E, Luo Y, Simeone A. Industrial waste heat recovery: a systematic approach[J]. Sustainable Energy Technologies and Assessments, 2018, 29: 50-59. |
4 | 陈昕, 王如竹. 一种低温余热高效利用的氨水动力循环[J]. 化工学报, 2016, 67(9): 3536-3544. |
Chen X, Wang R Z. An efficient ammonia-water power cycle in low temperature waste heat application[J]. CIESC Journal, 2016, 67(9): 3536-3544. | |
5 | 刘超, 徐进良. 一种新型天然气锅炉烟气余热回收系统[J]. 化工学报, 2013, 64(11): 4223-4230. |
Liu C, Xu J L. A novel heat recovery system for flue gas from natural gas boiler[J]. CIESC Journal, 2013, 64(11): 4223-4230. | |
6 | 路会同, 江龙, 王丽伟, 等. 低温余热驱动的无泵有机朗肯循环瞬时稳态发电性能[J]. 化工学报, 2017, 68(12): 4709-4716. |
Lu H T, Jiang L, Wang L W, et al. Instantaneous steady state of pumpless organic Rankine cycle driven by low temperature heat source[J]. CIESC Journal, 2017, 68(12): 4709-4716. | |
7 | 谢飞博, 朱彤, 高乃平. 冷源温度对小型ORC低温余热发电系统的影响[J]. 化工学报, 2016, 67(10): 4111-4117. |
Xie F B, Zhu T, Gao N P. Effect of cold source temperature on power generation of small organic Rankine cycle system with low-grade waste heat[J]. CIESC Journal, 2016, 67(10): 4111-4117. | |
8 | Bell L E. Cooling, heating, generating power, and recovering waste heat with thermoelectric systems[J]. Science, 2008, 321(5895): 1457-1461. |
9 | Abraham T J, Macfarlane D R, Baughman R H, et al. Towards ionic liquid-based thermoelectrochemical cells for the harvesting of thermal energy[J]. Electrochimica Acta, 2013, 113: 87-93. |
10 | Rahimi M, Straub A P, Zhang F, et al. Emerging electrochemical and membrane-based systems to convert low-grade heat to electricity[J]. Energy & Environmental Science, 2018, 11(2): 276-285. |
11 | Straub A P, Deshmukh A, Elimelech M. Pressure-retarded osmosis for power generation from salinity gradients: is it viable?[J]. Energy & Environmental Science, 2016, 9(1): 31-48. |
12 | Kim T, Rahimi M, Logan B E, et al. Harvesting energy from salinity differences using battery electrodes in a concentration flow cell[J]. Environmental Science & Technology, 2016, 50(17): 9791-9797. |
13 | Al-Masri D, Dupont M, Yunis R, et al. The electrochemistry and performance of cobalt-based redox couples for thermoelectrochemical cells[J]. Electrochimica Acta, 2018, 269: 714-723. |
14 | Anari E H B, Romano M, Teh W X, et al. Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids[J]. Chemical Communications, 2016, 52(4): 745-748. |
15 | Marino M, Misuri L, Carati A, et al. Boosting the voltage of a salinity-gradient-power electrochemical cell by means of complex-forming solutions[J]. Applied Physics Letters, 2014, 105: 0339013. |
16 | Zhang F, Liu J, Yang W L, et al. A thermally regenerative ammonia-based battery for efficient harvesting of low-grade thermal energy as electrical power[J]. Energy & Environmental Science, 2015, 8(1): 343-349. |
17 | Zhu X P, Rahimi M, Gorski C A, et al. A thermally-regenerative ammonia-based flow battery for electrical energy recovery from waste heat[J]. ChemSusChem, 2016, 9(8): 873-879. |
18 | Zhang F, Labarge N, Yang W L, et al. Enhancing low-grade thermal energy recovery in a thermally regenerative ammonia battery using elevated temperatures[J]. ChemSusChem, 2015, 8(6): 1043-1048. |
19 | Rahimi M, Zhu L, Kowalski K L, et al. Improved electrical power production of thermally regenerative batteries using a poly(phenylene oxide) based anion exchange membrane[J]. Journal of Power Sources, 2017, 342: 956-963. |
20 | Rahimi M, D􀆳Angelo A, Gorski C A,et al. Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery[J]. Journal of Power Sources, 2017, 351: 45-50. |
21 | Rahimi M, Kim T, Gorski C A, et al. A thermally regenerative ammonia battery with carbon-silver electrodes for converting low-grade waste heat to electricity[J]. Journal of Power Sources, 2018, 373: 95-102. |
22 | Wang W G, Shu G Q, Tian H, et al. A bimetallic thermally-regenerative ammonia-based flow battery for low-grade waste heat recovery[J]. Journal of Power Sources, 2019, 424: 184-192. |
23 | 王福添, 张绍志, 陈光明. 热再生氨化学电池的实验研究及热力学分析[J]. 热能动力工程, 2018, 33(9): 132-137. |
Wang F T, Zhang S Z, Chen G M. Experimental study and thermodynamic analysis on thermally regenerative ammonia battery[J]. Journal of Engineering for Thermal Energy and Power, 2018, 33(9): 132-137. | |
24 | Rahimi M, Schoener Z, Zhu X P, et al. Removal of copper from water using a thermally regenerative electrodeposition battery[J]. Journal of Hazardous Materials, 2017, 322(B): 551-556. |
25 | 唐志强, 张亮, 朱恂, 等. 不同Cu2+浓度下热再生氨电池产电及Cu2+去除特性[J]. 化工学报, 2019, 70(12): 4804-4810. |
Tang Z Q, Zhang L, Zhu X, et al. Effect of Cu2+ concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery[J]. CIESC Journal, 2019, 70(12): 4804-4810. | |
26 | 张绍志, 王福添, 陈光明, 等. 一种输出电能的第二类吸收式热泵: 2016105464590[P]. 2016-07-13. |
Zhang S Z, Wang F T, Chen G M, et al. A second kind of absorption heat pump for energy output: 2016105464590[P]. 2016-07-13. | |
27 | 张绍志, 王福添, 陈光明, 等. 一种低品位热驱动的冷电联供系统及其应用方法: 2016109965536[P]. 2016-11-13. |
Zhang S Z, Wang F T, Chen G M, et al. A low-grade thermal driven cold electricity cogeneration system and its application method: 2016109965536[P]. 2016-11-13. | |
28 | Vicari F, D􀆳Angelo A, Kouko Y,et al. On the regeneration of thermally regenerative ammonia batteries[J]. Journal of Applied Electrochemistry,2018, 48(12SI): 1381-1388. |
29 | 王福添. 热再生氨化学电池的电极反应及基本循环研究[D]. 杭州: 浙江大学, 2018. |
Wang F T. Study on the electrode reaction and basic cycle of the thermally regenerative ammonia battery[D]. Hangzhou: Zhejiang University, 2018. | |
30 | Zhang L, Li Y X, Zhu X, et al. Copper foam electrodes for increased power generation in thermally regenerative ammonia-based batteries for low-grade waste heat recovery[J]. Industrial & Engineering Chemistry Research, 2019, 58(17): 7408-7415. |
31 | 李彦翔, 张亮, 朱恂, 等. 传质对热可再生氨电池性能的影响[J]. 工程热物理学报, 2019, (3): 668-671. |
Li Y X, Zhang L, Zhu X, et al. Effect of mass transfer on the performance of thermally regenerative ammonia-based battery[J]. Journal of Engineering Thermophysics, 2019, (3): 668-671. | |
32 | Zhang Y S, Zhang L, Li J, et al. Performance of a thermally regenerative ammonia-based flow battery with 3D porous electrodes: effect of reactor and electrode design[J]. Electrochimica Acta, 2020, 331: 135442. |
33 | Wang W, Shu G, Tian H, et al. A numerical model for a thermally-regenerative ammonia-based flow battery using for low grade waste heat recovery[J]. Journal of Power Sources, 2018, 388: 32-44. |
34 | 高明峰. 钒微流控燃料电池的数值模拟研究[D]. 长春: 吉林大学, 2012. |
Gao M F. Numerical simulation study on vanadium microfluidic fuel cell[D]. Changchun: Jilin University, 2012. | |
35 | Wang R, Li Y, He Y. Achieving gradient-pore-oriented graphite felt for vanadium redox flow batteries: meeting improved electrochemical activity and enhanced mass transport from nano-to micro-scale[J]. Journal of Materials Chemistry A, 2019, 7(18): 10962-10970. |
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