CIESC Journal ›› 2023, Vol. 74 ›› Issue (4): 1419-1432.DOI: 10.11949/0438-1157.20221553
• Reviews and monographs • Previous Articles Next Articles
Can YANG1,2,3(), Xueqi SUN2, Minghua SHANG4, Jian ZHANG4, Xiangping ZHANG2,3, Shaojuan ZENG2,3()
Received:
2022-11-30
Revised:
2023-03-08
Online:
2023-06-02
Published:
2023-04-05
Contact:
Shaojuan ZENG
杨灿1,2,3(), 孙雪琦2, 尚明华4, 张建4, 张香平2,3, 曾少娟2,3()
通讯作者:
曾少娟
作者简介:
杨灿(1998—),女,硕士研究生,yangcan2021@ipe.ac.cn
基金资助:
CLC Number:
Can YANG, Xueqi SUN, Minghua SHANG, Jian ZHANG, Xiangping ZHANG, Shaojuan ZENG. Research status and prospect of CO2 absorption and separation by phase-change ionic liquid systems[J]. CIESC Journal, 2023, 74(4): 1419-1432.
杨灿, 孙雪琦, 尚明华, 张建, 张香平, 曾少娟. 相变离子液体体系吸收分离CO2的研究现状及展望[J]. 化工学报, 2023, 74(4): 1419-1432.
液-液相变离子液体体系 | 主吸收剂 | 相分离促进剂 | CO2吸收量 | 文献 |
---|---|---|---|---|
[BMIM][NTf2]-MEA-环丁砜 | MEA | [BMIM][NTf2]-环丁砜 | 2.86 mol/kg absorbent | [ |
[BMIM][BF4]-MEA-H2O | MEA | [BMIM][BF4] | 0.53 mol/mol MEA | [ |
[TETAH][Lys]-乙醇-H2O | [TETAH][Lys] | 乙醇 | 2.35 mol/mol IL | [ |
[DETAH][Triz]-1-丙醇-H2O | [DETAH][Triz] | 1-丙醇 | 1.71 mol/mol IL | [ |
[TETA][Br]-DEEA-H2O | [TETA][Br] | DEEA | — | [ |
[TETA][Br]-PMDETA-H2O | [TETA][Br] | PMDETA | 2.19 mol/mol IL | [ |
[TETA][BF4]-PMDETA-H2O | [TETA][BF4] | PMDETA | — | [ |
Table 1 Representative liquid-liquid phase-change ionic liquid systems for CO2 capture
液-液相变离子液体体系 | 主吸收剂 | 相分离促进剂 | CO2吸收量 | 文献 |
---|---|---|---|---|
[BMIM][NTf2]-MEA-环丁砜 | MEA | [BMIM][NTf2]-环丁砜 | 2.86 mol/kg absorbent | [ |
[BMIM][BF4]-MEA-H2O | MEA | [BMIM][BF4] | 0.53 mol/mol MEA | [ |
[TETAH][Lys]-乙醇-H2O | [TETAH][Lys] | 乙醇 | 2.35 mol/mol IL | [ |
[DETAH][Triz]-1-丙醇-H2O | [DETAH][Triz] | 1-丙醇 | 1.71 mol/mol IL | [ |
[TETA][Br]-DEEA-H2O | [TETA][Br] | DEEA | — | [ |
[TETA][Br]-PMDETA-H2O | [TETA][Br] | PMDETA | 2.19 mol/mol IL | [ |
[TETA][BF4]-PMDETA-H2O | [TETA][BF4] | PMDETA | — | [ |
液-固相变离子液体体系 | 主吸收剂 | 相分离促进剂 | CO2吸收量 | 文献 |
---|---|---|---|---|
[HMIM][NTf2]-MEA | MEA | [HMIM][NTf2] | 0.5 mol/mol MEA | [ |
[EOHMIM][NTf2]-MEA | MEA | [EOHMIM][NTf2] | 0.5 mol/mol MEA | [ |
[C n MIM][NTf2]-DEA | DEA | [C n MIM][NTf2] | 0.5 mol/mol DEA | [ |
[HMIM][NTf2]-AMP | AMP | [HMIM][NTf2] | — | [ |
[EMIM][TfO]-MEA | MEA | [EMIM][TfO] | — | [ |
[EMIM][BF4]-MEA | MEA | [EMIM][BF4] | 0.51 mol/mol MEA | [ |
[BMIM][BF4]-MEA | MEA | [BMIM][BF4] | 0.52 mol/mol MEA | [ |
[TETA][BF4]-乙醇 | [TETA][BF4] | 乙醇 | — | [ |
[N1111][Gly]-乙醇 | [N1111][Gly] | 乙醇 | 0.85 mol/mol IL | [ |
[N1111][Gly]-1-丙醇 | [N1111][Gly] | 1-丙醇 | 0.90 mol/mol IL | [ |
[N1111][Gly]-DMEE | [N1111][Gly] | DMEE | 1.2 mol/mol IL | [ |
[DETAH][Br]-PEG200 | [DETAH][Br] | PEG200 | 1.18 mol/mol IL | [ |
[TETA][Br]-PEG200 | [TETA][Br] | PEG200 | — | [ |
Table 2 Representative liquid-solid phase-change ionic liquid systems for CO2 capture
液-固相变离子液体体系 | 主吸收剂 | 相分离促进剂 | CO2吸收量 | 文献 |
---|---|---|---|---|
[HMIM][NTf2]-MEA | MEA | [HMIM][NTf2] | 0.5 mol/mol MEA | [ |
[EOHMIM][NTf2]-MEA | MEA | [EOHMIM][NTf2] | 0.5 mol/mol MEA | [ |
[C n MIM][NTf2]-DEA | DEA | [C n MIM][NTf2] | 0.5 mol/mol DEA | [ |
[HMIM][NTf2]-AMP | AMP | [HMIM][NTf2] | — | [ |
[EMIM][TfO]-MEA | MEA | [EMIM][TfO] | — | [ |
[EMIM][BF4]-MEA | MEA | [EMIM][BF4] | 0.51 mol/mol MEA | [ |
[BMIM][BF4]-MEA | MEA | [BMIM][BF4] | 0.52 mol/mol MEA | [ |
[TETA][BF4]-乙醇 | [TETA][BF4] | 乙醇 | — | [ |
[N1111][Gly]-乙醇 | [N1111][Gly] | 乙醇 | 0.85 mol/mol IL | [ |
[N1111][Gly]-1-丙醇 | [N1111][Gly] | 1-丙醇 | 0.90 mol/mol IL | [ |
[N1111][Gly]-DMEE | [N1111][Gly] | DMEE | 1.2 mol/mol IL | [ |
[DETAH][Br]-PEG200 | [DETAH][Br] | PEG200 | 1.18 mol/mol IL | [ |
[TETA][Br]-PEG200 | [TETA][Br] | PEG200 | — | [ |
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