Surface reaction controlled preparation of hierarchical structure nanomaterials and their electrochemical performances

doi:10.11949/j.issn.0438-1157.20150643

Abstract

Abstract:

The development of supercapacitors, lithium-ion batteries (LIBs) and other energy storage devices are getting increasing concern. For energy storage devices such as supercapacitors and LIBs whose electrochemical performance depends mainly on the electrode material, the preparation of efficient energy storage materials becomes the key to the development of efficient energy storage devices. This article aims to introduce the preparation and properties of hierarchical transition metal oxide-based electrode materials, specifically summarizing the related work on the study and development of high-performance supercapacitors and LIBs by our group over the past years: surface chemical reaction controlled preparation of hierarchical metal oxides, metal oxides incorporated into carbon matrixes nanohybrids and various three-dimensional (3D) multi-component composites, demonstrating excellent electrochemical properties.

Key words: transition metal oxides, hierarchical structure, composites, chemical reaction, electrochemical performance

摘要：

超级电容器和锂离子电池等储能设备的研究和开发日益受到人们的关注。对于超级电容器和锂离子电池等储能设备,其电化学性能主要取决于电极材料,因此高效储能材料的制备成为开发高效储能设备的关键。本文主要介绍了多级结构过渡金属氧化物基电极材料的制备及性能,重点阐述了本实验室近年来在研制高性能超级电容器和锂离子电池方面的相关工作:基于表面化学反应控制制备多级结构金属氧化物、金属氢氧化物/碳嵌入式纳米杂化物以及多种三维结构的多元复合电极材料,表现出优异的电化学性能。

关键词: 过渡金属氧化物, 多级结构, 复合材料, 化学反应, 电化学性能

CLC Number:

O646
TB34

JIANG Hao, LI Chunzhong. Surface reaction controlled preparation of hierarchical structure nanomaterials and their electrochemical performances[J]. CIESC Journal, 2015, 66(8): 2872-2877.

江浩, 李春忠. 表面化学反应控制制备多级结构电极材料及性能[J]. 化工学报, 2015, 66(8): 2872-2877.

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