CIESC Journal ›› 2021, Vol. 72 ›› Issue (4): 2317-2327.DOI: 10.11949/0438-1157.20201182
• Material science and engineering, nanotechnology • Previous Articles Next Articles
ZHANG Rui(),SHAO Qi,ZHANG Huayu,JIN Zelong,ZHANG Xiaoliang()
Received:
2020-08-19
Revised:
2020-09-18
Online:
2021-04-05
Published:
2021-04-05
Contact:
ZHANG Xiaoliang
通讯作者:
张小亮
作者简介:
张锐(1996—),男,硕士研究生,基金资助:
CLC Number:
ZHANG Rui, SHAO Qi, ZHANG Huayu, JIN Zelong, ZHANG Xiaoliang. Fabrication of boron-doped hybrid silica membranes for pervaporation desalination[J]. CIESC Journal, 2021, 72(4): 2317-2327.
张锐, 邵琦, 张华宇, 金泽龙, 张小亮. 硼掺杂二氧化硅杂化膜的制备及渗透汽化脱盐性能[J]. 化工学报, 2021, 72(4): 2317-2327.
Fig.10 Arrhenius plots of temperature dependent water permeation flux [(a), (b)] and permeance [(c), (d)] of B-BTESE- SiO2 hybrid membranes towards pure water and 3.5%(mass) NaCl solutions
Membrane | Ej/(kJ·mol-1) | Ep/(kJ·mol-1) | (Ej-Ep)/(kJ·mol-1) | |||
---|---|---|---|---|---|---|
pure H2O | 3.5%(质量) NaCl | pure H2O | 3.5%(质量) NaCl | pure H2O | 3.5%(质量) NaCl | |
BTESE | 16.57±2.18 | 18.23±1.85 | -26.64±2.10 | -24.99±1.86 | 43.21 | 43.22 |
B-BTESE-0.05 | 13.80±1.57 | 17.40±1.74 | -29.42±1.58 | -25.82±1.77 | 43.22 | 43.22 |
B-BTESE-0.13 | 12.83±1.61 | 17.04±1.90 | -30.39±1.38 | -26.18±1.41 | 43.22 | 43.22 |
B-BTESE-0.25 | 10.71±1.54 | 14.27±1.40 | -32.50±1.38 | -28.95±1.41 | 43.21 | 43.22 |
B-BTESE-0.50 | 19.44±0.64 | 19.00±1.10 | -23.73±0.35 | -24.22±1.39 | 43.17 | 43.22 |
B-BTESE-1.00 | 19.98±2.80 | 20.02±1.80 | -23.24±2.75 | -23.20±1.74 | 43.22 | 43.22 |
Table 1 Activation energy of B-BTESE-SiO2 hybrid membranes for PV desalination processes
Membrane | Ej/(kJ·mol-1) | Ep/(kJ·mol-1) | (Ej-Ep)/(kJ·mol-1) | |||
---|---|---|---|---|---|---|
pure H2O | 3.5%(质量) NaCl | pure H2O | 3.5%(质量) NaCl | pure H2O | 3.5%(质量) NaCl | |
BTESE | 16.57±2.18 | 18.23±1.85 | -26.64±2.10 | -24.99±1.86 | 43.21 | 43.22 |
B-BTESE-0.05 | 13.80±1.57 | 17.40±1.74 | -29.42±1.58 | -25.82±1.77 | 43.22 | 43.22 |
B-BTESE-0.13 | 12.83±1.61 | 17.04±1.90 | -30.39±1.38 | -26.18±1.41 | 43.22 | 43.22 |
B-BTESE-0.25 | 10.71±1.54 | 14.27±1.40 | -32.50±1.38 | -28.95±1.41 | 43.21 | 43.22 |
B-BTESE-0.50 | 19.44±0.64 | 19.00±1.10 | -23.73±0.35 | -24.22±1.39 | 43.17 | 43.22 |
B-BTESE-1.00 | 19.98±2.80 | 20.02±1.80 | -23.24±2.75 | -23.20±1.74 | 43.22 | 43.22 |
Fig.11 N2 adsorption-desorption isotherms (close symbols for adsorption, open symbols for desorption) and pore size distribution (inset) of B-BTESE-0.25 gel powder
Membrane | c(NaCl)/%(mass) | T/℃ | J/(kg·m-2·h-1) | P/(mol·m-2·s-1·Pa-1) | Rej/% | Ref. |
---|---|---|---|---|---|---|
PVA/SiO2 | 0.2 | 60 | 20.6 | 16×10-6 | 99 | [ |
BTESEthy-SiO2 | 0.2 | 70 | 14.2 | 7×10-6 | 99.6 | [ |
PVA/SiO2 | 3.5 | 60 | 12.3 | 9.7×10-6 | 99.9 | [ |
ES40-SiO2 | 3.5 | 60 | 17.8 | 14.1×10-6 | 99 | [ |
Co-TEOS-SiO2 | 3.5 | 60 | 11.3 | 9.7×10-6 | 99.9 | [ |
Ni/TEOS-SiO2 | 3.5 | 25 | 2.5 | 23.9×10-6 | 97 | [ |
La25Y75-BTESE-SiO2 | 3.5 | 60 | 15.6 | 12.4×10-6 | 99.9 | [ |
P123/TEOS-SiO2 | 3.5 | 60 | 8 | 6.9×10-6 | 99.9 | [ |
CTAB/SiO2 | 4 | 25 | 2.6 | 12.9×10-6 | 99.9 | [ |
P123/TEOS-TEVS-SiO2 | 15 | 60 | 9.2 | 8.7×10-6 | 98.6 | [ |
B-BTESE-SiO2 | 0.3 | 60 | 24.5 | 19×10-6 | 100 | 本工作 |
B-BTESE-SiO2 | 3.5 | 60 | 16.5 | 13.1×10-6 | 100 | 本工作 |
B-BTESE-SiO2 | 15 | 60 | 9.6 | 8.4×10-6 | 99.9 | 本工作 |
Table 2 Comparison of PV desalination performance of SiO2 membranes
Membrane | c(NaCl)/%(mass) | T/℃ | J/(kg·m-2·h-1) | P/(mol·m-2·s-1·Pa-1) | Rej/% | Ref. |
---|---|---|---|---|---|---|
PVA/SiO2 | 0.2 | 60 | 20.6 | 16×10-6 | 99 | [ |
BTESEthy-SiO2 | 0.2 | 70 | 14.2 | 7×10-6 | 99.6 | [ |
PVA/SiO2 | 3.5 | 60 | 12.3 | 9.7×10-6 | 99.9 | [ |
ES40-SiO2 | 3.5 | 60 | 17.8 | 14.1×10-6 | 99 | [ |
Co-TEOS-SiO2 | 3.5 | 60 | 11.3 | 9.7×10-6 | 99.9 | [ |
Ni/TEOS-SiO2 | 3.5 | 25 | 2.5 | 23.9×10-6 | 97 | [ |
La25Y75-BTESE-SiO2 | 3.5 | 60 | 15.6 | 12.4×10-6 | 99.9 | [ |
P123/TEOS-SiO2 | 3.5 | 60 | 8 | 6.9×10-6 | 99.9 | [ |
CTAB/SiO2 | 4 | 25 | 2.6 | 12.9×10-6 | 99.9 | [ |
P123/TEOS-TEVS-SiO2 | 15 | 60 | 9.2 | 8.7×10-6 | 98.6 | [ |
B-BTESE-SiO2 | 0.3 | 60 | 24.5 | 19×10-6 | 100 | 本工作 |
B-BTESE-SiO2 | 3.5 | 60 | 16.5 | 13.1×10-6 | 100 | 本工作 |
B-BTESE-SiO2 | 15 | 60 | 9.6 | 8.4×10-6 | 99.9 | 本工作 |
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