CIESC Journal ›› 2020, Vol. 71 ›› Issue (1): 409-416.DOI: 10.11949/0438-1157.20191271

• Material science and engineering, nanotechnology • Previous Articles     Next Articles

Synthesis of carbides supported on ordered mesoporous carbon by molten salt method

Minshan MENG(),Jiahua ZHAO,Pengfei ZHANG()   

  1. College of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2019-09-24 Revised:2019-10-24 Online:2020-01-05 Published:2020-01-05
  • Contact: Pengfei ZHANG

熔盐法合成有序介孔碳负载的金属碳化物

孟敏珊(),赵佳华,张鹏飞()   

  1. 上海交通大学化学化工学院,上海 200240
  • 通讯作者: 张鹏飞
  • 作者简介:孟敏珊(1996—),女,硕士研究生,msmeng_1123@qq.com
  • 基金资助:
    国家自然科学基金面上项目(21776174);国家千人计划青年项目;海洋工程国家重点实验室开发课题(1809);中船重工委托项目;浙江新安化工集团委托项目

Abstract:

Ordered mesoporous carbon is a kind of nanostructured material with regular pore structure, high specific surface area and large pore volume. It is also a very good carrier material. Meanwhile, transition metal carbides have a series of properties that are similar to precious metals because of their structural characteristics. They can be used as catalysts with high activity in theory for heterogeneous catalytic processes to replace precious metals. However, transition metal carbides greatly affect the catalytic activity due to their low specific surface area and large particle size. Therefore, a variety of ordered mesoporous carbon-supported transition metal carbides were synthesized by molten salt method, and the samples were characterized by SEM, TEM, XRD and BET. The results show that the method can form carbon-supported metal carbides such as TiC and Mo2C with small particle size and high specific surface area, which has better prospects for catalytic application.

Key words: ordered mesoporous carbon, metal carbides, molten salt method, porous carbon

摘要:

有序介孔碳是一种具有宽孔径、规则孔道结构、高比表面积和大孔容的纳米结构材料,具有很高的导电性及化学稳定性,是一种非常优良的载体材料。过渡金属碳化物因其结构相似性,具有一系列类似贵金属的性质,可作为贵金属替代材料,用于多相催化过程。但过渡金属碳化物多数粒径大、比表面积低,不利于催化活性,因此,采用熔盐法合成了多种有序介孔碳负载的过渡金属碳化物,并通过SEM、TEM、XRD、BET等方法对样品进行了一系列表征。结果表明,该方法能有效制备碳负载的TiC、Mo2C等金属碳化物,且具有较小的颗粒尺寸和较高的比表面积,将有较好的催化应用前景。

关键词: 有序介孔碳, 金属碳化物, 熔盐法, 多孔碳

CLC Number: