固态金属锂电池研究进展：外部压力和内部应力的影响

doi:10.11949/0438-1157.20201201

化工学报 ›› 2021, Vol. 72 ›› Issue (1): 61-70.DOI: 10.11949/0438-1157.20201201

固态金属锂电池研究进展：外部压力和内部应力的影响

南皓雄^1,²(),赵辰孜¹,袁洪³(),卢洋¹,沈馨¹,朱高龙^1,⁴,刘全兵²(),黄佳琦³,张强¹()

^1.清华大学化学工程系，绿色反应工程与工艺北京市重点实验室，北京 100084
^2.广东工业大学轻工化工学院，广东广州 510006
^3.北京理工大学前沿交叉科学研究院，北京 100081
^4.深圳大学化学与化工学院功能高分子深圳市重点实验室，广东深圳 518000

收稿日期:2020-08-21 修回日期:2020-11-06 出版日期:2021-01-05 发布日期:2021-01-05
通讯作者: 袁洪,刘全兵,张强
作者简介:南皓雄（1986—），男，博士，讲师，nanhaoxiong@163.com
基金资助:
国家自然科学基金项目(21905056);国家重点研发计划项目(2016YFA0202500);北京市自然科学基金项目(Z200011)

Recent advances in solid-state lithium metal batteries: the role of external pressure and internal stress

NAN Haoxiong^1,²(),ZHAO Chenzi¹,YUAN Hong³(),LU Yang¹,SHEN Xin¹,ZHU Gaolong^1,⁴,LIU Quanbing²(),HUANG Jiaqi³,ZHANG Qiang¹()

^1.Beijing Key Laboratory of Green Chemical Reaction Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
^2.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
^3.Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
^4.Shenzhen Key Laboratory of Functional Polymer, College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518000, Guangdong, China

Received:2020-08-21 Revised:2020-11-06 Online:2021-01-05 Published:2021-01-05
Contact: YUAN Hong,LIU Quanbing,ZHANG Qiang

摘要/Abstract

摘要：

固态锂金属电池具有理论能量密度高、安全性高等优势，是极有前景的下一代储能系统。然而，固体电极与固体电解质之间有限的固–固接触严重阻碍了界面离子的传输。因此，增加外部压力是增加固–固接触及延长电池循环寿命的重要途径。同时，在充放电过程中，电极体积变化产生的内应力也将影响电池界面特性。通过介绍两种基本物理接触模型，结合硫化物、氧化物、聚合物电解质以及金属锂的物理性质，综述了外压和内部应力对电解质、电极及电池的影响。最后，对外压力与内应力在全固态金属锂电池中的作用进行了总结和展望。

关键词: 全固态电池, 锂金属负极, 固态电解质界面膜, 力学, 电化学

Abstract:

The solid-state lithium metal battery has the advantages of high theoretical energy density and high safety, and is a very promising next-generation energy storage system. However, the limited solid–solid contact retards the migration of Li ions between solid electrolytes and electrodes. Consequently, applying external pressure is an effective route to enhance interfacial contacts and extend battery cycle life. At the same time, the internal stresses generated with the volume changes of electrodes during cycling will also hugely influence the interfacial contacts. In this paper, the mechanisms of external pressure and internal stresses on electrodes and electrolytes are reviewed by introducing two basic physical contact models and analyzing the physical properties of sulfide, oxide, polymer electrolytes and lithium metal anodes. Finally, the roles of external pressure and internal stresses in all-solid-state Li metal batteries are summarized and prospected.

Key words: all-solid-state battery, Li metal anode, solid electrolyte interphase, mechanics, electrochemistry

中图分类号:

O 646

南皓雄, 赵辰孜, 袁洪, 卢洋, 沈馨, 朱高龙, 刘全兵, 黄佳琦, 张强. 固态金属锂电池研究进展：外部压力和内部应力的影响[J]. 化工学报, 2021, 72(1): 61-70.

NAN Haoxiong, ZHAO Chenzi, YUAN Hong, LU Yang, SHEN Xin, ZHU Gaolong, LIU Quanbing, HUANG Jiaqi, ZHANG Qiang. Recent advances in solid-state lithium metal batteries: the role of external pressure and internal stress[J]. CIESC Journal, 2021, 72(1): 61-70.

图/表 1

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固态金属锂电池研究进展：外部压力和内部应力的影响

Recent advances in solid-state lithium metal batteries: the role of external pressure and internal stress

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