化工学报 ›› 2023, Vol. 74 ›› Issue (9): 3708-3715.DOI: 10.11949/0438-1157.20230255

• 离子液体与绿色过程专栏 • 上一篇    下一篇

离子液体催化合成2-氰基呋喃反应动力学研究

郑佳丽1(), 李志会1,2(), 赵新强1, 王延吉1()   

  1. 1.河北工业大学化工学院,河北省绿色化工与高效节能重点实验室,天津 300130
    2.河北工业大学能源与环境工程学院,天津 300130
  • 收稿日期:2023-03-17 修回日期:2023-07-24 出版日期:2023-09-25 发布日期:2023-11-20
  • 通讯作者: 李志会,王延吉
  • 作者简介:郑佳丽(1998—),女,博士研究生,2547124405@qq.com
  • 基金资助:
    国家自然科学基金项目(U20A20152)

Kinetics of ionic liquid catalyzed synthesis of 2-cyanofuran

Jiali ZHENG1(), Zhihui LI1,2(), Xinqiang ZHAO1, Yanji WANG1()   

  1. 1.Hebei Provincial Key Laboratory of Green Chemical Technology and High Efficient Energy Saving, Hebei University of Technology, Tianjin 300130, China
    2.School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300130, China
  • Received:2023-03-17 Revised:2023-07-24 Online:2023-09-25 Published:2023-11-20
  • Contact: Zhihui LI, Yanji WANG

摘要:

2-氰基呋喃(CF)是一种具有广泛潜在应用的重要生物基衍生物,是合成糠胺、糠酸等产品的关键原料,但目前对于合成2-氰基呋喃的研究甚少。本研究采用离子液体为催化剂,探究了糠醛与离子液体型羟胺盐反应制备2-氰基呋喃的动力学过程。考察了反应温度和反应时间对产物收率的影响,建立了反应动力学模型,对动力学参数进行了有效性验证。实验结果显示:当反应温度为120℃,反应时间为2 h时,糠醛转化率和2-氰基呋喃收率均为100%。通过计算得到了活化能、指前因子及动力学方程,对比了计算值和实验值,发现平均误差为0.34%,从而验证了该反应动力学方程的准确性,为2-氰基呋喃的后续应用提供了理论指导。

关键词: 生物质, 2-氰基呋喃, 糠醛, 离子液体, 动力学

Abstract:

2-Cyanofuran (CF) is an important bio-based derivative with a wide range of potential applications. It is a key raw material for the synthesis of furfurylamine, furoic acid and other products, but there are few studies on the synthesis of 2-cyanofuran. In this study, ionic liquid was used as catalyst to explore the kinetic process of preparing 2-cyanofuran by reaction of furfural and hydroxylamine ionic liquid salt. The effect of reaction temperature and reaction time on the product yield was investigated. The kinetic model was established, and the kinetic parameters were validated. The experimental results showed that the furfural conversion and 2-cyanofuran yield were 100% when the reaction temperature is 120℃ and the reaction time was 2 h. The activation energy, pre-exponential factor and kinetic equation were obtained by calculation. By comparing the calculated and experimental values, it was found that the average error was 0.34%, which verified the accuracy of the kinetic equation and provided theoretical guidance for the subsequent application of 2-cyanofuran.

Key words: biomass, 2-cyanofuran, furfural, ionic liquid, dynamics

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