二氧化硅纳米颗粒对冰浆中冰晶粒径分布及存储演化特性的影响

doi:10.11949/j.issn.0438-1157.20160937

化工学报 ›› 2017, Vol. 68 ›› Issue (3): 870-878.DOI: 10.11949/j.issn.0438-1157.20160937

二氧化硅纳米颗粒对冰浆中冰晶粒径分布及存储演化特性的影响

刘曦, 林淑娴, 李岁, 李学来

福州大学石油化工学院, 福建福州 350116

收稿日期:2016-07-06 修回日期:2016-11-24 出版日期:2017-03-05 发布日期:2017-03-05
通讯作者: 李学来,lxl6632@sina.com
基金资助:
国家自然科学基金国家基础科学人才培养基金项目（J1103303）；福建省中青年教师教育科研项目（JA14053）。

Effect of nanosilica on size distribution and evolution of ice crystal particles during storage of ice slurry

LIU Xi, LIN Shuxian, LI Sui, LI Xuelai

School of Chemical Engineering, Fuzhou University, Fuzhou 350116, Fujian, China

Received:2016-07-06 Revised:2016-11-24 Online:2017-03-05 Published:2017-03-05
Contact: 10.11949/j.issn.0438-1157.20160937
Supported by:
supported by the National Science Foundation for Fostering Talents in Basic Research of the National Natural Science Foundation of China (J1103303) and the Program of Young Teacher Education and Research of Fujian Province (JA14053).

摘要/Abstract

摘要：

分别以乙二醇水溶液和氯化钠水溶液为基液配制不同浓度的二氧化硅纳米流体并以此制备冰浆，通过显微装置获得冰晶图像，将实验得到的粒径分布与正态分布、对数正态分布、Gamma分布和Weibull分布进行对比，探讨纳米二氧化硅对冰晶平均粒径与分布特性的影响，同时观测储存过程中冰晶粒径演化规律。结果表明：加入纳米二氧化硅前后冰晶粒径分布均可用Gamma分布描述；纳米二氧化硅可起到细化晶粒的作用，而且添加浓度越高冰晶颗粒越小；当基液为乙二醇水溶液时，加入纳米二氧化硅可较好地抑制储存过程中的冰晶粒径增长，但基液为氯化钠水溶液时，纳米二氧化硅浓度需达到0.75%，才可抑制冰晶增大。研究结果证明，一定浓度的纳米二氧化硅流体可作为制冰溶液，起到减小冰晶粒径并控制冰晶生长的作用，这对冰浆流动和传热性能的改善具有重要的应用价值。

关键词: 冰浆, 粒度分布, 粒径演化, 纳米粒子, 二氧化硅

Abstract:

Ice slurries of nanosilica fluid at different concentrations were prepared by dispersing silica nanoparticles in aqueous solutions of either ethylene glycol or sodium chloride. Images of ice crystal particles in ice slurries were obtained by a microscopic observation system. The resulting size distributions of ice crystals were compared to normal, log-normal, Gamma, and Weibull distributions so as to investigate nanosilica effect on average diameter and size distribution of ice particles and to study dimensional change of ice particles during storage of ice slurries. The experimental results indicated that ice particle sizes were fitted well with Gamma distribution before and after addition of nanosilica. Nanosilica played an important role in grain refinement such that sizes of ice particles decreased linearly with increasing concentrations of nanosilica. When ethylene glycol aqueous solution was base fluid, nanosilica addition effectively inhibited growth of ice particles during slurry storage. When sodium chloride aqueous solution was base fluid, concentration of nanosilica had to be increased from 0.25% to 0.75% for similar inhibition effect. Therefore, nanosilica could be used to reduce particle size and to control growth of ice crystals, which has an important application for flow and heat transfer improvement of ice slurry.

Key words: ice slurry, particle size distribution, particle size evolution, nanoparticles, silica

中图分类号:

TK02

刘曦, 林淑娴, 李岁, 李学来. 二氧化硅纳米颗粒对冰浆中冰晶粒径分布及存储演化特性的影响[J]. 化工学报, 2017, 68(3): 870-878.

LIU Xi, LIN Shuxian, LI Sui, LI Xuelai. Effect of nanosilica on size distribution and evolution of ice crystal particles during storage of ice slurry[J]. CIESC Journal, 2017, 68(3): 870-878.

参考文献 30

[1]	SAITO A. Recent advances in research on cold thermal energy storage[J]. International Journal of Refrigeration, 2002, 25(2):177-189.
[2]	BELLAS I, TASSOU S A. Present and future applications of ice slurries[J]. International Journal of Refrigeration, 2005, 28(1):115-121.
[3]	FANG G Y, TANG F, CAO L. Dynamic characteristics of cool thermal energy storage systems-a review[J]. International Journal of Green Energy, 2016, 13(1):1-13.
[4]	EGOLF P W, KAUFFELD M. From physical properties of ice slurries to industrial ice slurry applications[J]. International Journal of Refrigeration, 2005, 28(1):4-12.
[5]	LI G, HWANG Y, RADERMACHER R. Review of cold storage materials for air conditioning application[J]. International Journal of Refrigeration, 2012, 35(8):2053-2077.
[6]	KAUFFELD M, WANG M J, GOLDSTEIN V, et al. Ice slurry applications[J]. International Journal of Refrigeration, 2010, 33(8):1491-1505.
[7]	WANG M J, KUSUMOTO N. Ice based storage in multifunctional buildings[J]. Heat Mass Transfer, 2001, 37(6):594-604.
[8]	QUARINI J. Ice-pigging to reduce and remove fouling and to achieve clean-in-place[J]. Applied Thermal Engineering, 2002, 22(7):747-753.
[9]	YOUSSEF Z, DELAHAYE A, HUANG L, et al. State of the art on phase change material slurries[J]. Energy Conversion and Management, 2013, 65(1):120-132.
[10]	AYEL V, LOTTIN O, PEERHOSSAINI H. Rheology, flow behavior and heat transfer of ice slurries:a review of the state of the art[J]. International Journal of Refrigeration, 2003, 26(1):51-59.
[11]	DORON P, GRANICA D, BARNEA D. Slurry flow in horizontal pipes-experimental and modeling[J]. Multiphase Flow, 1987, 13(4):535-547.
[12]	DORON P, BARNEA D. A three-layer model for solid-liquid flow in horizontal pipes[J]. Multiphase Flow, 1993, 19(6):1029-1043.
[13]	EGOLF P W, KITANOVSKI A, ATA-CAESAR D, et al. Thermodynamics and heat transfer of ice slurries[J]. International Journal of Refrigeration, 2005, 28(1):51-59.
[14]	MIKA L. Ice slurry flow in a poppet-type flow control valve[J]. Experimental Thermal and Fluid Science, 2013, 45(1):128-135.
[15]	DELAHAYE A, FOURNAISON L, GUILPART J. Characterisation of ice and THF hydrate slurry crystal size distribution by microscopic observation method[J]. International Journal of Refrigeration, 2010, 33(8):1639-1647.
[16]	刘志强, 王肖肖, 王小倩, 等. 冰浆存储过程中冰晶粒径演化的影响因素研究[J]. 热科学与技术, 2013, 12(4):307-312. LIU Z Q, WANG X X, WANG X Q, et al. Analysis of influence factors of ice slurry in storage[J]. Journal of Thermal Science and Technology, 2013, 12(4):307-312.
[17]	赵腾磊, 刘志强, 徐爱祥, 等. 冰浆存储过程中冰晶粒径演化数值模拟[J]. 中南大学学报, 2014, 45(10):3651-3656. ZHAO T L, LIU Z Q, XU A X, et al. Numerical simulation of evolution of ice crystal size distribution during storage[J]. Journal of Central South University, 2014, 45(10):3651-3656.
[18]	徐爱祥, 刘志强, 赵腾磊, 等. 冰浆存储过程中冰晶粒径动力学演化影响因素[J]. 中南大学学报, 2015, 46(8):3138-3144. XU A X, LIU Z Q, ZHAO T L, et al. Factors influencing dynamics evolution of ice crystals during ice slurry storage[J]. Journal of Central South University, 2015, 46(8):3138-3144.
[19]	PENG Z B, YUAN Z L, LIANG K F, et al. Ice slurry formation in a cocurrent liquid-liquid flow[J]. Chinese Journal of Chemical Engineering, 2008, 16(4):552-557.
[20]	PRONK P, INFANTE FERREIRA C A, WITKAMP G J. A dynamic model of Ostwald ripening in ice suspensions[J]. Journal of Crystal Growth, 2005, 275(1/2):1355-1361.
[21]	PRONK P, HANSEN T M, INFANTE FERREIRA C A, et al. Time-dependent behavior of different ice slurries during storage[J]. International Journal of Refrigeration, 2005, 28(1):27-36.
[22]	INADA T, MODAK P R. Growth control of ice crystals by poly(vinyl alcohol) and antifreeze protein in ice slurries[J]. Chemical Engineering Science, 2006, 61(10):3149-3158.
[23]	YOSHI K T, AKIO S, SEIJI O. A study of supercooling-phenomenon and freezing probability of water inside horizontal cylinders[J]. International Journal of Refrigeration, 2004, 27(3):242-247.
[24]	FARID M M, KHUDHAIR A M, RAZACK S A K, et al. A review on phase change energy storage:materials and applications[J]. Energy Conversion and Management, 2004, 45(9):1597-1615.
[25]	HE Q B, WANG S F, TONG M W, et al. Experimental study on thermophysical properties of nanofluids as phase-change material (PCM) in low temperature cool storage[J]. Energy Conversion and Management, 2012, 64:199-205.
[26]	LEE J H, LEE S H, CHOI C J, et al. A review of thermal conductivity data, mechanisms and models for nanofluids[J]. International Journal of Micro-Nano Scale Transport, 2010, 1(4):269-322.
[27]	XIE H Q. Thermal conductivity enhancements of suspensions containing nanosized alumina particles[J]. Journal of Applied Physics, 2002, 91(7):4568-4572.
[28]	WANG X, XU X F, CHOI S U S. Thermal conductivity of nanoparticle-fluid mixture[J]. Journal of Thermophysics and Heat Transfer, 1999, 13(4):474-480.
[29]	CLAIN P, NDOYE F T, DELAHAYE A, et al. Particle size distribution of TBPB hydrates by focused beam reflectance measurement (FBRM) for secondary refrigeration application[J]. International Journal of Refrigeration, 2015, 50:19-31.
[30]	刘海红, 李玉星, 王武昌, 等. 四氢呋喃水合物和一氟二氯乙烷水合物颗粒聚结特性[J]. 化工学报, 2014, 65(6):2049-2055. LIU H H, LI Y X, WANG W C, et al. Agglomeration characterization of THF and HCFC-141b hydrate particle[J]. CIESC Journal, 2014, 65(6):2049-2055.

二氧化硅纳米颗粒对冰浆中冰晶粒径分布及存储演化特性的影响

Effect of nanosilica on size distribution and evolution of ice crystal particles during storage of ice slurry

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 30

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈美思, 陈威达, 李鑫垚, 李尚予, 吴有庭, 张锋, 张志炳. 硅基离子液体微颗粒强化气体捕集与转化的研究进展[J]. 化工学报, 2023, 74(9): 3628-3639.
[2]	仪显亨, 周骛, 蔡小舒, 蔡天意. 光纤后向动态光散射测量纳米颗粒的浓度适用范围研究[J]. 化工学报, 2023, 74(8): 3320-3328.
[3]	李勇, 高佳琦, 杜超, 赵亚丽, 李伯琼, 申倩倩, 贾虎生, 薛晋波. Ni@C@TiO₂核壳双重异质结的构筑及光热催化分解水产氢[J]. 化工学报, 2023, 74(6): 2458-2467.
[4]	葛运通, 王玮, 李楷, 肖帆, 于志鹏, 宫敬. 多相分散体系中微油滴与改性二氧化硅表面间作用力的AFM研究[J]. 化工学报, 2023, 74(4): 1651-1659.
[5]	王瑞恒, 何品晶, 吕凡, 章骅. 垃圾焚烧飞灰水洗后三种固液分离方法参数比较及优化[J]. 化工学报, 2023, 74(4): 1712-1723.
[6]	任金胜, 刘克润, 焦志伟, 刘家祥, 于源. 涡流空气分级机近导叶处团聚体解团机理研究[J]. 化工学报, 2023, 74(4): 1528-1538.
[7]	曲国娟, 江涛, 刘涛, 马骧. 超分子策略调控金纳米团簇的发光行为[J]. 化工学报, 2023, 74(1): 397-407.
[8]	黄心童, 耿宇昊, 刘恒源, 陈卓, 徐建鸿. 微流控制备新型功能纳米粒子研究进展[J]. 化工学报, 2023, 74(1): 355-364.
[9]	张炜, 李昊阳, 徐纯刚, 李小森. 气体水合物生成微观机理及分析方法研究进展[J]. 化工学报, 2022, 73(9): 3815-3827.
[10]	鲁统鹏, 潘晓林, 吴鸿飞, 李煜, 于海燕. 有机絮凝剂对铁矿相沉降性能影响及其吸附机理[J]. 化工学报, 2022, 73(9): 4122-4132.
[11]	张鑫, 许蕊, 路馨语, 牛永安. SiO₂@BiOCl-Bi₂₄O₃₁Cl₁₀核壳微球的合成及光催化[J]. 化工学报, 2022, 73(8): 3636-3646.
[12]	顾仁杰, 张加威, 靳雪阳, 文利雄. 微撞击流反应器制备镍钴复合氢氧化物超级电容器材料及其性能研究[J]. 化工学报, 2022, 73(8): 3749-3757.
[13]	戴文华, 辛忠. Si掺杂对Cu/ZrO₂催化CO₂加氢制甲醇性能的影响[J]. 化工学报, 2022, 73(8): 3586-3596.
[14]	张苗, 杨洪海, 尹勇, 徐悦, 沈俊杰, 卢心诚, 施伟刚, 王军. 氧化石墨烯/水脉动热管的启动及传热特性[J]. 化工学报, 2022, 73(3): 1136-1146.
[15]	白浩隆, 付亮亮, 许光文, 白丁荣. 流化床煤燃烧过程不同气氛下的气态氮释放特征[J]. 化工学报, 2022, 73(2): 876-886.