氨水沉淀法由含钛滤液提取二氧化钛

doi:10.3969/j.issn.0438-1157.2012.10.048

化工学报 ›› 2012, Vol. 63 ›› Issue (10): 3345-3349.DOI: 10.3969/j.issn.0438-1157.2012.10.048

• 材料化学工程与纳米技术 • 上一篇下一篇

氨水沉淀法由含钛滤液提取二氧化钛

张悦^1,2, 王思佳¹, 薛向欣¹

1. 东北大学材料与冶金学院, 辽宁沈阳 110819;
2. 沈阳化工研究院有限公司农药研究所, 辽宁沈阳 110021

收稿日期:2012-02-08 修回日期:2012-06-26 出版日期:2012-10-05 发布日期:2012-10-05
通讯作者: 张悦
作者简介:张悦(1982- ),男,博士,工程师。

Recovery of titanium dioxide from titanium-bearing solution by using ammonium as precipitant

ZHANG Yue^1,2, WANG Sijia¹, XUE Xiangxin¹

1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China;
2. Pesticide Research Institute, Shenyang Research Institute of Chemical Industry, Shenyang 110021, Liaoning, China

Received:2012-02-08 Revised:2012-06-26 Online:2012-10-05 Published:2012-10-05

摘要/Abstract

摘要： 以含钛高炉渣为原料,经硫酸铵熔融法得到含钛滤液,然后以氨水为沉淀剂,控制pH值使钛水解,水解产物经600℃煅烧2 h得到二氧化钛。考察了螯合剂的加入量、溶液pH值和反应时间对钛沉淀率的影响,实验结果表明:反应过程中铁与钛发生共沉淀,造成二氧化钛产物中的铁含量过高。EDTA几乎完全抑制了铁的沉淀,明显降低了二氧化钛产物的全铁含量;2-羟基丙烷-1,2,3-三羧酸的加入降低了产物中二氧化硅的含量,提高了产物中二氧化钛的含量。当2-羟基丙烷-1,2,3-三羧酸与硅的摩尔比为1,EDTA与铁的摩尔比为3,pH值为2.0,反应时间为90 min时产物中二氧化钛的含量为96.35%。

关键词: 含钛高炉渣, 二氧化钛, 水解, 沉淀

Abstract: Extraction of titanium dioxide from titanium-bearing blast furnace slag was studied.Firstly,the titanium-bearing blast furnace slag reacted with ammonium sulfate to obtain NH₃ and TiOSO₄ solution,and then titanium dioxide was precipitated from TiOSO₄ solution by using ammonium as precipitant. Finally,the filtered precipitate was calcined in a muffle furnace at 600℃ for 2 h.The effects of quantities of chelate reagent added,pH and holding time on the precipitation rate of titanium were investigated.The results showed that the precipitation rate of titanium,aluminum and iron increased with increasing solution pH since NH₃ was used as precipitant and during this stage iron ion hydrolyzed to form Fe(OH)₃.The hydrolysis of Fe³⁺ was restrained by EDTA addition into the solution.At the same time,the content of iron in production decreased and the content of TiO₂ increased.The precipitation of silicon was restrained by citric acid(a novel additive)addition into the solution.At the same time,the content of silicon dioxide in production decreased and the content of TiO₂ increased.The TiO₂ content of the production increased with increasing EDTA/Fe³⁺ molar ratio.TiO₂ with purity 96.35% was obtained when EDTA/Fe³⁺ molar ratio increased to 3,citric acid /Si molar ratio was 1,solution pH was 2.0 and holding time was 90 min.

Key words: titanium-bearing blast furnace slag, titanium dioxide, hydrolysis, precipitation

中图分类号:

TF111.3

张悦, 王思佳, 薛向欣. 氨水沉淀法由含钛滤液提取二氧化钛[J]. 化工学报, 2012, 63(10): 3345-3349.

ZHANG Yue, WANG Sijia, XUE Xiangxin. Recovery of titanium dioxide from titanium-bearing solution by using ammonium as precipitant[J]. CIESC Journal, 2012, 63(10): 3345-3349.

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氨水沉淀法由含钛滤液提取二氧化钛

Recovery of titanium dioxide from titanium-bearing solution by using ammonium as precipitant

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