生物质快速热解制油试验及流程模拟

doi:10.3969/j.issn.0438-1157.2014.02.044

化工学报 ›› 2014, Vol. 65 ›› Issue (2): 679-683.DOI: 10.3969/j.issn.0438-1157.2014.02.044

生物质快速热解制油试验及流程模拟

王超^1,2, 陈冠益¹, 兰维娟¹, 马文超¹

1 天津大学环境科学与工程学院, 天津 300072;
2 中国石化工程建设有限公司, 北京 100101

收稿日期:2013-05-01 修回日期:2013-06-03 出版日期:2014-02-05 发布日期:2014-02-05
通讯作者: 陈冠益
基金资助:
国家自然科学基金项目（51036006，51076158）。

Experimental research and process simulation on biomass fast pyrolysis for production of bio-oil

WANG Chao^1,2, CHEN Guanyi¹, LAN Weijuan¹, MA Wenchao¹

1 Faculty of Environment Science and Engineering, Tianjin University, Tianjin 300072, China;
2 Sinopec Engineering Incorporation, Beijing 100101, China

Received:2013-05-01 Revised:2013-06-03 Online:2014-02-05 Published:2014-02-05
Supported by:
supported by the National Natural Science Foundation of China (51036006, 51076158).

摘要/Abstract

摘要： 使用自主研发的流化床热解反应器对生物质热解制油进行实验研究，通过对不同实验温度450、500、525、550、580、610℃下得到的目标产物进行分析，得到了反应温度对生物油产率的影响规律。实验表明：550℃时，最大液体产率为42.5%（质量）；实验得到的不可冷凝气体的组分以CO、CO₂、CH₄和H₂为主，气相产物产率约为37.7%（质量）。在实验基础上，利用Aspen Plus流程模拟软件，建立了生物质热解制油工艺模拟流程，模拟分析了热解温度对生物油产率的影响，结果表明该模型能准确模拟实际热解过程，具有较好的适用性和可靠性。

关键词: 生物质, 热解, 生物油, 流程模拟

Abstract: The experimental research of biomass pyrolysis for production of bio-oil is performed with a fluidized bed reactor designed by ourselves. By analysis of desired products collected at different temperature 450, 500, 525, 550, 580, 610℃, influence of reaction temperature on the yield of bio-oil is investigated in this paper. The results show that the highest yield of bio-oil is 42.5%(mass) received around 550℃, while gas yield is 37.7%(mass), gas components are mainly CO, CO₂, CH₄, H₂. On the basis of the experiment, using Aspen Plus software for process simulation a biomass fast pyrolysis model for production of bio-oil is set up, the effects of temperature on bio-oil yield is simulatedly analyzed. The results show that the pyrolysis process is simulated exactly, the model is proved applicable and reliable.

Key words: biomass, pyrolysis, bio-oil, process simulation

中图分类号:

王超, 陈冠益, 兰维娟, 马文超. 生物质快速热解制油试验及流程模拟[J]. 化工学报, 2014, 65(2): 679-683.

WANG Chao, CHEN Guanyi, LAN Weijuan, MA Wenchao. Experimental research and process simulation on biomass fast pyrolysis for production of bio-oil[J]. CIESC Journal, 2014, 65(2): 679-683.

参考文献 14

[1]	Mao Yuru, Fang Mengxiang, Luo Zhongyang, Wang Shurong, Zhou Jinsong, Cen Kefa. Practice on conversion and utilization of biomass in fluidized bed technology[J]. Acta Energiae Solaris Sinica, 2001, 22(2): 124-130
[2]	Ren Zhenghui, Xu Qing, Chen Mingqiang, Zhang Suping, Yan Yongjie, Li Tingchen. Fast pyrolysis of biomass in fluid bed to produce liquid fuel[J]. Acta Energiae Solaris Sinica, 2002, 23(4): 463-470
[3]	Diebold J, Scahill J. Ablative pyrolysis of biomass in solid-convective heat transfer environments//Estes Park[C]. 1985: 539-555
[4]	Scott D S, Piskorz J, Radlein D. Liquid products from the continuous flash pyrolysis of biomass[J]. Industrial & Engineering Chemistry Research, 1985, 24: 581-588
[5]	Zhu Xifeng(朱锡锋). Principle and Technology of Biomasss Pyrolysis(生物质热解原理与技术)[M]. Heifei: Press of University of Science and Technology of China, 2004
[6]	Dai Xianwen, Wu Chuangzhi, Zhou Zhaoqiu, Chen Yong. Biomass pyrolysis for liquid in circulating fluidized bed(CFB) reactor[J]. Acta Energiae Solaris Sinica, 2001, 22(2): 124-130
[7]	Bridgwater A V. Renewable fuels and chemicals by thermal processing of biomass[J]. Chemical Engineering Journal, 2003, 91: 87-102
[8]	Wang Qi, Wang Shurong, Wang Le, Tan Hong, Luo Zhongyang, Cen Kefa. Experimental study of biomass flash pyrolysis for bio-oil production[J]. Journal of Engineering Thermophysics, 2007, 28(1): 173-176
[9]	Yang Qiaoli, Liu Yizhen, Zhang Ruiqin. Analysis of biomass-based bio-oil by GC-MS[J]. J. Zhengzhou Univ.:Nat.Sci.Ed., 2007, 39(3): 140-144
[10]	Miller R S, Bellan J A. A generalized biomass pyrolysis model based on superimposed cellulose, hemicelluloses and lignin kinetics [J]. Combust. Sci. and Tech., 1997, 126: 97-137
[11]	Janse A M C, Westerhout R W J, Prins W. Modeling of flash pyrolysis of a single wood particle[J]. Chemical Engineering and Processing, 2000, 39: 239-252
[12]	Jiang Jianchun, Shen Zhaobang. Study on reaction kinetics of biomass pyrolysis[J]. Chemistry and Industry of Forest Products, 2003, 23(4): 1-6
[13]	Fu Aiqing, Chen Lunjian, Yang Jie, Zhu Zhenzhong. Pyrolysis process and kinetics analysis of corn stalk and wheat straw[J]. Chemical Industry and Engineering, 2009, 26(4): 350-353
[14]	Wang Xinyun, Chen Mingqiang, Wang Jun, Wan Xinjun. Study on kinetic modeling of biomass pyrolysis[J]. Chemistry & Bioengineering, 2009, 26(7): 61-63

[1]	郑佳丽, 李志会, 赵新强, 王延吉. 离子液体催化合成2-氰基呋喃反应动力学研究[J]. 化工学报, 2023, 74(9): 3708-3715.
[2]	吴雷, 刘姣, 李长聪, 周军, 叶干, 刘田田, 朱瑞玉, 张秋利, 宋永辉. 低阶粉煤催化微波热解制备含碳纳米管的高附加值改性兰炭末[J]. 化工学报, 2023, 74(9): 3956-3967.
[3]	陈佳起, 赵万玉, 姚睿充, 侯道林, 董社英. 开心果壳基碳点的合成及其对Q235碳钢的缓蚀行为研究[J]. 化工学报, 2023, 74(8): 3446-3456.
[4]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[5]	吴文涛, 褚良永, 张玲洁, 谭伟民, 沈丽明, 暴宁钟. 腰果酚生物基自愈合微胶囊的高效制备工艺研究[J]. 化工学报, 2023, 74(7): 3103-3115.
[6]	董茂林, 陈李栋, 黄六莲, 吴伟兵, 戴红旗, 卞辉洋. 酸性助水溶剂制备木质纳米纤维素及功能应用研究进展[J]. 化工学报, 2023, 74(6): 2281-2295.
[7]	杨峥豪, 何臻, 常玉龙, 靳紫恒, 江霞. 生物质快速热解下行式流化床反应器研究进展[J]. 化工学报, 2023, 74(6): 2249-2263.
[8]	葛泽峰, 吴雨青, 曾名迅, 查振婷, 马宇娜, 侯增辉, 张会岩. 灰化学成分对生物质气化特性的影响规律[J]. 化工学报, 2023, 74(5): 2136-2146.
[9]	衣思敏, 马亚丽, 刘伟强, 张金帅, 岳岩, 郑强, 贾松岩, 李雪. 微晶菱镁矿蒸氨及水化动力学研究[J]. 化工学报, 2023, 74(4): 1578-1586.
[10]	包嘉靖, 别洪飞, 王子威, 肖睿, 刘冬, 吴石亮. 正庚烷对冲扩散火焰中添加长链醚类对碳烟前体生成特性的影响[J]. 化工学报, 2023, 74(4): 1680-1692.
[11]	刘海芹, 李博文, 凌喆, 刘亮, 俞娟, 范一民, 勇强. 羟基-炔点击化学改性半乳甘露聚糖薄膜的制备及性能研究[J]. 化工学报, 2023, 74(3): 1370-1378.
[12]	顾学荣, 刘硕士, 杨思宇. 基于并行EGO和代理模型辅助的多参数优化方法研究[J]. 化工学报, 2023, 74(3): 1205-1215.
[13]	祖凌鑫, 胡荣庭, 李鑫, 陈余道, 陈广林. 木质生物质化学组分的碳释放产物特征和反硝化利用程度[J]. 化工学报, 2023, 74(3): 1332-1342.
[14]	陈瑞哲, 程磊磊, 顾菁, 袁浩然, 陈勇. 纤维增强树脂复合材料化学回收技术研究进展[J]. 化工学报, 2023, 74(3): 981-994.
[15]	张娜, 潘鹤林, 牛波, 张亚运, 龙东辉. 酚醛树脂热裂解反应机理的密度泛函理论研究[J]. 化工学报, 2023, 74(2): 843-860.

生物质快速热解制油试验及流程模拟

Experimental research and process simulation on biomass fast pyrolysis for production of bio-oil

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 14

相关文章 15

编辑推荐

Metrics

本文评价