PAA-g-ZrO2复合膜过滤牛血清蛋白过程的污染阻力分析

doi:10.3969/j.issn.0438-1157.2014.03.027

化工学报 ›› 2014, Vol. 65 ›› Issue (3): 954-959.DOI: 10.3969/j.issn.0438-1157.2014.03.027

PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析

周守勇¹, 张艳¹, 薛爱莲¹, 王辉^1,2, 李梅生¹, 赵宜江¹, 邢卫红²

1 淮阴师范学院化学化工学院, 淮安市新型环境功能材料重点实验室, 江苏淮安 223300;
2 南京工业大学化学化工学院, 材料化学工程国家重点实验室, 江苏南京 210009

收稿日期:2013-06-23 修回日期:2013-11-16 出版日期:2014-03-05 发布日期:2014-03-05
通讯作者: 赵宜江
作者简介:周守勇（1973—），男，博士，副教授。
基金资助:
国家自然科学基金项目（20976067）；江苏省高校自然科学研究项目（12KJD530001）；江苏省科技支撑计划（工业）项目（BE2013080）；江苏省低维材料化学重点建设实验室开放课题（JSKC12115）；江苏省高校“青蓝工程”资助项目；江苏省六大人才高峰项目；江苏省政府留学基金项目。

Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution

ZHOU Shouyong¹, ZHANG Yan¹, XUE Ailian¹, WANG Hui^1,2, LI Meisheng¹, ZHAO Yijiang¹, XING Weihong²

1 Huai'an Key Laboratory of Advanced Environment Functional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an 223300, Jiangsu, China;
2 State Key Laboratory of Materials-Oriented Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China

Received:2013-06-23 Revised:2013-11-16 Online:2014-03-05 Published:2014-03-05
Supported by:
supported by the National Natural Science Foundation of China (20976067), the Natural Science Foundation of Jiangsu Education Department (12KJD530001), the Jiangsu Province Science and Technology Support Program (BE2013080), the Open Project Program of Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials (JSKC12115), the Jiangsu Qing Lan Project, the Six Projects Sponsoring Talent Summits of Jiangsu Province and the Jiangsu Government Scholarship for Overseas Studies.

摘要/Abstract

摘要： 通过对PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力及其分布分析揭示接枝聚丙烯酸（PAA）对ZrO₂膜抗污染性能的影响规律。结果表明：PAA-g-ZrO₂复合膜和ZrO₂膜的总阻力均随着过滤时间的延长而增加，但是PAA-g-ZrO₂复合膜总阻力的增加趋势明显低于原ZrO₂膜，同时，PAA-g-ZrO₂复合膜的内部污染阻力R_if所占比例下降为原ZrO₂膜的一半，这表明PAA接枝到ZrO₂膜表面明显降低了膜孔内堵塞的内部污染，提高了膜的抗污染和易清洗性能。此外，溶液的pH值对PAA-g-ZrO₂复合膜的污染阻力及其分布有着明显影响，当溶液pH值为8.0时，PAA-g-ZrO₂复合膜几乎不存在膜孔堵塞污染。

关键词: 膜, 过滤, 膜污染, 蛋白质, 丙烯酸, pH敏感, 膜阻力

Abstract: Fouling of PAA-g-ZrO₂ composite membrane by BSA solution was investigated in conjunction with analysis of membrane total resistances and resistances distribution. The total resistances of the PAA-g-ZrO₂ composite membrane and ZrO₂ membrane increased with increasing filtration time, but the growth trend of the PAA-g-ZrO₂ composite membrane total resistances was lower than that of the ZrO₂ membrane. The fouling resistance of the ZrO₂ membrane was R_cp(concentration polarization resistance)-dominant, while R_cp and R_m (membrane resistance) controlled the PAA-g-ZrO₂ composite membrane separation process. The internal plugging resistance (R_if) of the PAA-g-ZrO₂ composite membrane was just half of that of the ZrO₂ membrane. The membrane resistance of PAA-g-ZrO₂ composite membrane increased with increasing pH. The densely packed brush-shaped structure of the PAA chains was considered to be responsible for reducing the protein adsorption on the membrane surface. Furthermore, the PAA-g-ZrO₂ composite membrane displayed high pH-sensitivity for BSA solutions, and could resist protein fouling in high pH applications.

Key words: membranes, filtration, fouling, protein, acrylic acid, pH-sensitivity, membrane resistance

中图分类号:

TQ028.8

周守勇, 张艳, 薛爱莲, 王辉, 李梅生, 赵宜江, 邢卫红. PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析[J]. 化工学报, 2014, 65(3): 954-959.

ZHOU Shouyong, ZHANG Yan, XUE Ailian, WANG Hui, LI Meisheng, ZHAO Yijiang, XING Weihong. Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution[J]. CIESC Journal, 2014, 65(3): 954-959.

参考文献 24

[1]	Xing Weihong(邢卫红), Fan Yiqun(范益群), Zhong Zhaoxiang(仲兆祥), Xu Nanping(徐南平). Recent advances in process-engineering oriented preparation and application of ceramic membranes[J]. CIESC Journal(化工学报), 2009,60(11): 2679-2688
[2]	Fan Yiqun(范益群), Qi Hong(漆红), Xu Nanping(徐南平). Advances in preparation techniques of porous ceramic membranes[J]. CIESC Journal(化工学报), 2013, 64(1): 107-115
[3]	Guo W S, Ngo H H, Li J X. A mini-review on membrane fouling[J]. Bioresour. Technol., 2012, 122: 27-34
[4]	Li M S, Zhao Y J, Zhou S Y, Xing M H, Wong F S. Resistance analysis for ceramic membrane microfiltration of raw soy sauce[J]. J. Membr. Sci., 2007, 299: 122-129
[5]	Clark W M, Bansal A, Sontakke M, Ma Y H. Protein adsorption and fouling in ceramic ultrafiltration membranes[J]. J. Membr. Sci., 1991, 55: 21-38
[6]	Zhong Z X, Li D Y, Liu X, Xing W H, Xu N P. The fouling mechanism of ceramic membranes used for recovering TS-1 catalysts[J]. Chin. J. Chem. Eng., 2009,17 (1): 53-57
[7]	Liu Y F, He G H, Ding L H, Dou H, Ju J, Li B J. Experimental and CFD studies on the performance of microfiltration enhanced by a turbulence promoter[J]. Chin. J. Chem. Eng., 2012, 20 (4): 617-624
[8]	Sur H W, Cui Z F. Enhancement of microfiltration of yeast suspensions using gas sparging-effect of feed conditions[J]. Sep. Sci. Technol., 2005,41: 313-319
[9]	Gönder Z B, Arayici S, Barlas H. Advanced treatment of pulp and paper mill wastewater by nanofiltration process: effects of operating conditions on membrane fouling[J]. Sep. Purif. Technol., 2011, 76: 292-302
[10]	Li W, Xing W, Jin W, Xu N. Effect of pH on microfiltration of Chinese herb aqueous extract by zirconia membrane [J]. Sep. Purif. Technol., 2006, 50:92-96
[11]	Xing Weihong(邢卫红), Zhong Zhaoxiang(仲兆祥), Jing Wenhen(景文珩), Fan Yiqun(范益群). Controlling of membrane fouling bases on membrane interface interactions[J]. CIESC Journal(化工学报), 2013, 64(1): 173-181
[12]	Zhao X T, Su Y L, Chen W J, Peng J M, Jiang Z Y. Grafting perfluoroalkyl groups onto polyacrylonitrile membrane surface for improved fouling release property[J]. J. Membr. Sci., 2012, 415/416: 824-834
[13]	He H T, Jing W H, Xing W H, Fan Y Q. Improving protein resistance of α-Al2O3 membranes by modification with POEGMA brushes[J]. Appl. Surf. Sci., 2011, 258: 1038-1044
[14]	Randon J, Blanc P, Paterson R. Modification of ceramic membrane surfaces using phosphoric acid and alkyl phosphonic acids and its effects on ultrafiltration of BSA protein[J]. J. Membr. Sci., 1995, 98: 119-129
[15]	Chang Q B, Zhou J, Wang Y Q, Wang J M, Meng G Y. Hydrophilic modification of Al2O3 microfiltration membrane with nano-sized γ-Al2O3 coating[J]. Desalination, 2010, 262: 110-114
[16]	Thérien-Aubin H, Chen L, Ober C K. Fouling-resistant polymer brush coatings[J]. Polymer, 2011, 52: 5419-5425
[17]	Zhou S Y, Xue A L, Zhao Y J, Li M S, Wang H, Xing W H. Grafting polyacrylic acid brushes onto zirconia membranes: fouling reduction and easy-cleaning properties[J]. Sep. Purif. Technol., 2013, 114: 53-63
[18]	Zhao Y J, Zhou S Y, Li M S, Xue A L, Zhang Y, Wang J G, Xing W H. Humic acid removal and easy-cleanability using temperature-responsive ZrO2 tubular membranes grafted with poly(N-isopropylacrylamide) brush chains[J]. Water Res., 2013, 47:2375-2386
[19]	Yang L L, Zhao Y J, Zhou S Y, Li M S, Chen Y, Xing W H. Preparation of pH-responsive ceramic composite membranes by grafting acrylic acid onto α-alumina membranes[J]. Chin. Sci. Bull., 2009,54: 2147-2149
[20]	Zhou S Y, Xue A L, Zhang Y, Li M S, Wang J G, Zhao Y J, Xing W H. Fabrication of temperature-responsive ZrO2 tubular membranes, grafted with poly (N-isopropylacrylamide) brush chains, for protein removal and easy cleaning[J]. J. Membr. Sci., 2014, 450: 351-361
[21]	Ousrnan M, Bennasar M. Determination of various hydraulic resistances during crossflow filtration of a starch grain suspension through inorganic membranes[J]. J. Membr. Sci., 1995, 105: 1-21
[22]	Hendri J, Hiroki A, Maekawa Y, Yoshida M, Katakai R. Permeability control of metal ions using temperature-and pH-sensitive gel membranes[J]. Radiat. Phys. Chem., 2001, 60: 617-624
[23]	Hu K, Dickson J M. Development and characterization of poly(vinylidene fluoride)-poly(acrylic acid) pore-filled pH-sensitive membranes[J]. J. Membr. Sci., 2007, 301: 19-28
[24]	Qian B, Li J, Wei Q, Bai P, Fang B, Zhao C. Preparation and characterization of pH-sensitive polyethersulfone hollow fiber membrane for flux control[J]．J. Membr. Sci., 2009, 34: 297-303

PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析

Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献 24

相关文章 15

编辑推荐

Metrics

本文评价

[1]	邵苛苛, 宋孟杰, 江正勇, 张旋, 张龙, 高润淼, 甄泽康. 水平方向上冰中受陷气泡形成和分布实验研究[J]. 化工学报, 2023, 74(S1): 161-164.
[2]	吴延鹏, 李晓宇, 钟乔洋. 静电纺丝纳米纤维双疏膜油性细颗粒物过滤性能实验分析[J]. 化工学报, 2023, 74(S1): 259-264.
[3]	胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765.
[4]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[5]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[6]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.
[7]	张佳怡, 何佳莉, 谢江鹏, 王健, 赵鹬, 张栋强. 渗透汽化技术用于锂电池生产中N-甲基吡咯烷酮回收的研究进展[J]. 化工学报, 2023, 74(8): 3203-3215.
[8]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[9]	陈雅鑫, 袁航, 刘冠章, 毛磊, 杨纯, 张瑞芳, 张光亚. 蛋白质纳米笼介导的酶自固定化研究进展[J]. 化工学报, 2023, 74(7): 2773-2782.
[10]	张贲, 王松柏, 魏子亚, 郝婷婷, 马学虎, 温荣福. 超亲水多孔金属结构驱动的毛细液膜冷凝及传热强化[J]. 化工学报, 2023, 74(7): 2824-2835.
[11]	韩奎奎, 谭湘龙, 李金芝, 杨婷, 张春, 张永汾, 刘洪全, 于中伟, 顾学红. 四通道中空纤维MFI分子筛膜用于二甲苯异构体分离[J]. 化工学报, 2023, 74(6): 2468-2476.
[12]	蔡斌, 张效林, 罗倩, 党江涛, 左栗源, 刘欣梅. 导电薄膜材料的研究进展[J]. 化工学报, 2023, 74(6): 2308-2321.
[13]	陈朝光, 贾玉香, 汪锰. 以低浓度废酸驱动中和渗析脱盐的模拟与验证[J]. 化工学报, 2023, 74(6): 2486-2494.
[14]	王蕾, 王磊, 白云龙, 何柳柳. SA膜状锂离子筛的制备及其锂吸附性能[J]. 化工学报, 2023, 74(5): 2046-2056.
[15]	张建华, 陈萌萌, 孙雅雯, 彭永臻. 部分短程硝化同步除磷耦合Anammox实现生活污水高效脱氮除磷[J]. 化工学报, 2023, 74(5): 2147-2156.