无机调理剂与表面活性剂联合调理对污泥脱水性能的影响

doi:10.3969/j.issn.0438-1157.2014.03.042

CIESC Journal ›› 2014, Vol. 65 ›› Issue (3): 1068-1075.DOI: 10.3969/j.issn.0438-1157.2014.03.042

无机调理剂与表面活性剂联合调理对污泥脱水性能的影响

洪晨, 邢奕, 王志强, 张坤, 司艳晓

北京科技大学土木与环境工程学院, 北京 100083

收稿日期:2013-06-21 修回日期:2013-11-11 出版日期:2014-03-05 发布日期:2014-03-05
通讯作者: 邢奕
作者简介:洪晨（1984—），男，博士研究生。
基金资助:
国家自然科学基金项目（51104009）；北京市科技新星计划项目（Z111106054511043）；北京市优秀人才培养资助项目（2012D009006000003）；中央高校基本科研业务费专项资金资助项目（FRF-TP-12-011B）；昆明市科技计划项目（2012-02-09-A-G-02-0001）；广东省教育部产学研结合项目（2011B090400629）。

Dewatering performance of sludge modified by inorganic conditioner combined with surfactant

HONG Chen, XING Yi, WANG Zhiqiang, ZHANG Kun, SI Yanxiao

School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China

Received:2013-06-21 Revised:2013-11-11 Online:2014-03-05 Published:2014-03-05
Supported by:
supported by the National Natural Science Foundation of China (51104009), Beijing Nova Program (Z111106054511043), Beijing Outstanding Talent Nurture and Funding Scheme (2012D009006000003), the Fundamental Research Funds for the Central Universities (FRF-TP-12-011B) and the Kunming Science and Technology Program (2012-02-09-A-G-02-0001).

摘要/Abstract

摘要： 研究了CaO、PAFC联合表面活性剂预处理对污泥脱水性能的影响。以污泥滤饼含水率和比阻（SRF）作为评价污泥脱水性能的指标，通过测定污泥调理过程中胞外聚合物（EPS）含量、Zeta电位的变化来阐明污泥脱水性能的变化。实验结果表明，十二烷基二甲基苄基氯化铵（1227）的加入导致上清液中EPS含量发生变化，有效降低了SRF和滤饼含水率，提高污泥脱水性能。CaO、PAFC和表面活性剂的联合调理污泥比单独使用表面活性剂的效果更好，CaO、PAFC的投加不仅改善污泥脱水性能，并有助于减少表面活性剂的用量。污泥上清液中EPS及其各组分含量与污泥滤饼含水率、SRF均有较高的相关性，对污泥的脱水性能有重要贡献。实验中确定的最佳污泥调理条件是CaO投加量为66.67 mg·（g DS）^-1、PAFC投加量为33.33 mg·（gDS）^-1和表面活性剂投加量为56.25 mg·（g DS）^-1，污泥滤饼含水率和SRF分别降至69.41%、0.294×10¹³ m·kg^-1。

关键词: 废物处理, 混凝, 表面活性剂, 污泥, 胞外聚合物, 脱水性能

Abstract: Dewatering performance of sludge modified by CaO and PAFC combined with surfactant is investigated in this study. Water content of dewatered sludge and specific resistance of filtration (SRF) are used to evaluate the sludge dewaterability, and the change of sludge dewaterability is explained by measuring variation of extracellular polymeric substance (EPS) content and Zeta potential in the conditioning process. The results show that adding surfactant can change EPS content in the filtrate, and reduce SRF and water content of dewatered sludge, and improve dewatering performance of sludge. The effect of CaO and PAFC combined with surfactant is better than individual surfactant. The addition of CaO and PAFC can both improve sludge dewaterability and contribute to reduce the addition of surfactant. The content of EPS and its components in sludge filtrate has a high correlation with the water content of dewatered sludge and SRF, and an important effect on the detwatering performance of sludge. The optimal conditions determined by experiment is that the addition amount of CaO, PAFC, surfactant is 66.67 mg·g^-1, 33.33 mg·g^-1, 56.25 mg·g^-1, and the water content in dewatered sludge and SRF are 69.41%、0.294×10¹³ m·kg^-1, respectively.

Key words: waste treatment, coagulation, surfactant, sludge, extracellular polymeric substance, dewaterability

中图分类号:

X705

洪晨, 邢奕, 王志强, 张坤, 司艳晓. 无机调理剂与表面活性剂联合调理对污泥脱水性能的影响[J]. CIESC Journal, 2014, 65(3): 1068-1075.

HONG Chen, XING Yi, WANG Zhiqiang, ZHANG Kun, SI Yanxiao. Dewatering performance of sludge modified by inorganic conditioner combined with surfactant[J]. , 2014, 65(3): 1068-1075.

参考文献 29

[1]	Neyens E, Baeyens J, Dewil R, De heyder B. Advanced sludge treatment affects extracellular polymeric substances to improve activated sludge dewatering[J]. Journal of Hazardous Materials, 2004, 106(2/3): 83-92
[2]	Yi Saili(易赛莉), Lu Lei(卢磊). Selection of sustainable development crafts and preliminary exploration of technological improvements on urban sewage treatment[J]. Environmental Science and Technology (环境科学与技术), 2007,30(8):60-63
[3]	Liu Haibo(柳海波), Zhang Huiling(张惠灵), Fan Liangjuan(范凉娟), et al. Effect of joint action of inorganic conditioner and surfactant on dewaterability of sludge[J]. China Water and Wastewater(中国给水排水),2012,28(3):10-14
[4]	Ma W, Zhao Y Q, Kearney P. A study of dual polymer conditioning of aluminum-based drinking water treatment residual[J]. Journal of Environmental Science and Health,2007, 42(7): 961-968
[5]	Li Kai(李恺), Ye Zhiping(叶志平), Li Huanwen(李焕文), et al. Study of surfactants CTAC on activated sludge's dewaterability and mechanism[J]. Journal of South China Normal University: Natural Science Edition (华南师范大学学报:自然科学版),2010(2):76-81
[6]	Jiang Bo(蒋波). Research on the effect and mechanism of cationic surfactants on the dewaterability of activated sludge[D].Shanghai: Shanghai Jiao Tong University,2007
[7]	Lu Wen(鹿雯), Zhang Dengfeng(张登峰), Wang Panpan(王盼盼), et al. Effect of cationic surfactants on sludge dewaterability[J]. Environmental Science and Technology(环境科学与技术),2008, 27(4):444-448
[8]	Huang C, Pan J R, Fu C G, Wu C C. Effects of surfactant addition on dewatering of alum sludges[J]. Journal of Environmental Engineering, 2002, 128(12): 1121-1127
[9]	Feng Kai(冯凯), Huang Ou(黄鸥). Application of lime conditioning and lime drying craft on sludge dewatering[J]. Urban Water Supply and Drainage (城镇给排水), 2011,37(5): 7
[10]	Thapa K B, Qi Y, Clayton S A, Hoadle A F A. Lignite aided dewatering of digested sewage sludge[J]. Water Research, 2009, 43(3): 623-634
[11]	Yang Guoyou(杨国友),Shi Lin(石林),Chai Ni(柴妮). The effect of calcium oxide combined with microwave on sludge dewatering[J]. Environmental Chemistry(环境化学),2011,30(3):698-702
[12]	Chen Y G, Chen Y S, Gu G W. Influence of pretreating activated sludge with acid and surfactant prior to conventional conditioning on filtration dewatering[J]. Chemical Engineering Journal, 2004, 99(2): 137-143
[13]	Yuan Haiping, Zhu Nanwen, Song Fangyong. Dewaterability characteristics of sludge conditioned with surfactants pretreatment by electrolysis[J]. Bioresource Technology, 2011, 102(3): 2308-2315
[14]	Zhou Zhenying(周贞英). Researches on the sludge dewaterability co-conditioned by electrolysis and surfactants[D]. Taiyuan: Taiyuan University of Technology, 2011
[15]	Higgins M J, Novak J T. Dewatering and settling of activated sludge: the case for using cation analysis[J].Water Environment Research, 1997, 69(2):225-232
[16]	Mikkelsen L H, Keiding K. Physico-chemical characteristics of full scale sewage sludges with implications to dewatering[J].Water Research, 2002, 36(10): 2451-2462
[17]	Lowry O H, Rosebrough N J, Farr A L, Randall R J. Protein measurement with the Folin phenol reagent[J]. The Journal of Biological Chemistry, 1951, 193(1): 265-275
[18]	Gaudy A F. Colorimetric determination of protein and carbohydrate[J]. Industrial Water Wastes, 1962, 7(1): 17-27
[19]	Burton K. Determination of DNA concentration with diphenylamine[J]. Methods in Enzymology, 1968, 12: 163-166
[20]	Bhuyan A K. On the mechanism of SDS-induced protein denaturation[J]. Biopolymers, 2010, 93(2): 186-199
[21]	Chu C P, Lee D J, Huang C. The role of ionic surfactants in compression dewatering of alum sludge[J]. Journal of Colloid and Interface Science, 1998,206(1):181-188
[22]	Wang Wanxia(王万霞), He Yunfei(何云飞), Shang Yazhuo(尚亚卓), et al. Interaction between the Gemini Surfactant (12-6-12) and DNA[J]. Acta Physico-Chimica Sinica(物理化学学报), 2011,27(1): 156-162
[23]	Li Laisheng(李来生), Huang Weidong(黄伟东), Wang Liping(王丽苹), et al. Study on the conformational change of DNA in surfactant[J]. Acta Chimica Sinica(化学学报),2002,60(1): 98-104
[24]	Biswas S C, Chattoraj D K. Polysaccharide-surfactant interaction(Ⅰ): Adsorption of cationic surfactants at the cellulose-water interface[J]. Langmuir, 1997, 13(17): 4505-4511
[25]	Lu Diannan(卢滇楠), Yan Ming(闫明), Zhang Minlian(张敏莲), et al. Molecular simulation of protein-surfactant assembly in a aqueous solution[J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2006, 57(8): 1949-1956
[26]	Hu Mengyao(胡梦瑶),Peng Mao(彭毛),Wu Hui (吴辉), et al. Spectroscopic investigation of the interaction between CTAB and protein[J].Chinese Journal Colloid and Polymer(胶体与聚合物), 2009, 27(3): 33-36, 44
[27]	Liu Y, Fang H H P. Influences of extracellular polymeric substances (EPS) on flocculation, settling, and dewatering of activated sludge[J]. Environmental Science and Engineering, 2003,33(3): 237-273
[28]	Chen Y, Yang H, Gu G. Effect of acid and surfactant treatment on activated sludge dewatering and settling[J]. Water Research, 2001, 35(11): 2615-2620
[29]	Yuan H, Zhu N, Song F. Dewaterability characteristics of sludge conditioned with surfactants pretreatment by electrolysis[J]. Bioresource Technology, 2011,102(3):2308-2315

无机调理剂与表面活性剂联合调理对污泥脱水性能的影响

Dewatering performance of sludge modified by inorganic conditioner combined with surfactant

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