复合功能树脂NXD-2对水中邻苯二甲酸单丁酯的去除性能

doi:10.3969/j.issn.0438-1157.2014.04.042

化工学报 ›› 2014, Vol. 65 ›› Issue (4): 1462-1469.DOI: 10.3969/j.issn.0438-1157.2014.04.042

复合功能树脂NXD-2对水中邻苯二甲酸单丁酯的去除性能

许正文^1,2, 赵云龙^1,2, 史静³, 陆建刚^1,2, 承玲^1,2, 李赛超^1,2, 刘聪^1,2

1 南京信息工程大学江苏省大气环境监测与污染控制高技术研究重点实验室, 江苏南京 210044;
2 南京信息工程大学环境科学与工程学院, 江苏南京 210044;
3 中国药科大学理学院, 江苏南京 211198

收稿日期:2013-07-15 修回日期:2013-08-25 出版日期:2014-04-05 发布日期:2013-09-09
通讯作者: 许正文（1980—），男，博士，讲师。
作者简介:许正文（1980—），男，博士，讲师。
基金资助:
国家自然科学基金项目（21107050）；江苏高校优势学科建设工程资助项目。

Removal of mono-n-butyl phthalate in aqueous phase by bifunctional polymeric adsorbent NXD-2

XU Zhengwen^1,2, ZHAO Yunlong^1,2, SHI Jing³, LU Jiangang^1,2, CHENG Ling^1,2, LI Saichao^1,2, LIU Cong^1,2

1 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science & Technology, Nanjing 210044, Jiangsu, China;
2 School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, Jiangsu, China;
3 School of Sciences, China Pharmaceutical University, Nanjing 211198, Jiangsu, China

Received:2013-07-15 Revised:2013-08-25 Online:2014-04-05 Published:2013-09-09
Supported by:
supported by the National Natural Science Foundation of China(21107050) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

摘要/Abstract

摘要： 酞酸单酯是水体环境中一类新型的环境激素污染物。以含叔胺基的复合功能树脂NXD-2为吸附剂，以邻苯二甲酸单丁酯（MBP）为目标污染物，通过吸附等温线、热力学、动力学和柱吸附脱附实验，考察了NXD-2对MBP的吸附性能。研究结果表明，NXD-2对MBP的吸附以氢键作用为主，在288～313 K的温度范围内，平衡吸附量随温度的升高而升高；升高温度有利于加快NXD-2对MBP的去除速率。柱吸附脱附研究表明，在进水浓度为300 mg·L^-1的高浓度条件下，吸附出水的前100 BV中，溶液中MBP的浓度低于检测限（10 mg·L^-1），说明NXD-2对MBP具有较高的处理深度；同时NXD-2具有较好的脱附效果，脱附体积达到20 BV时，脱附率接近100%。因此，复合功能树脂NXD-2作为一种吸附剂，在水体中酞酸单酯的去除方面具有良好的应用前景。

关键词: 复合功能树脂, 酞酸单酯, 环境激素, 吸附, 脱附, 吸附剂

Abstract: A new emerging hormone pollutants in aquatic environment, phthalic acid monoesters can lead to potential human health and ecological risks. In the present study, the adsorption performance of NXD-2（a hydrophilic bifunctional polymeric resin with tertiary amine groups）for mono-n-butyl phthalate (MBP) was studied by means of isotherms, thermodynamics, kinetics and dynamic column adsorption-desorption experiments. An analysis for sorption isotherms and thermodynamics showed that the adsorption of NXD-2 for MBP relied mainly on contribution of hydrogen bonding. The equilibrium adsorption capacities and adsorption rates increased with the increasing temperature in the range of 288—313 K. The results of continuous column adsorption demonstrated that at the condition of inflow with high concentration of MBP 300 mg·L^-1，the removal efficiency of NXD-2 could make the MBP content in effluent lower the detection limit (10 mg·L^-1) for first 100BV of effluent. Furthermore, NXD-2 was of good desorption performance, adsorbed MBP could be completely desorbed when adsorption volume reached 20BV. These results showed that NXD-2 could be an effective sorbent for the removal of phthalic acid monoesters in aqueous solution.

Key words: bifunctional polymeric adsorbent, phthalic acid monoesters, environmental hormone, adsorption, desorption, adsorbents

中图分类号:

O647.33

许正文, 赵云龙, 史静, 陆建刚, 承玲, 李赛超, 刘聪. 复合功能树脂NXD-2对水中邻苯二甲酸单丁酯的去除性能[J]. 化工学报, 2014, 65(4): 1462-1469.

XU Zhengwen, ZHAO Yunlong, SHI Jing, LU Jiangang, CHENG Ling, LI Saichao, LIU Cong. Removal of mono-n-butyl phthalate in aqueous phase by bifunctional polymeric adsorbent NXD-2[J]. CIESC Journal, 2014, 65(4): 1462-1469.

参考文献

[1] Lim C K, Kim S K, Ko D S. Differential cytotoxic effects of mono-(2-ethylhexyl)phthalate on blastomere-derived embryonic stem cells and differentiating neurons[J]. Toxicology, 2009, 264: 145-154
[2] Hong D, Li X W, Liang Q Q. Mono-(2-ethylhexyl)phthalate(MEHP) regulates glucocorticoid metabolism through 11b-hydroxysteroid dehydrogenase 2 in murine gonadotrope cells[J]. Biochemical and Biophysical Research Communications, 2009, 389: 305-309
[3] Knorr D. Biotechnology of marine polysaccharids[J]. Food Technology, 1985, 85: 313
[4] Blair J D, Ikonomou M G, Kelly B C. Ultra-trace determination of phthalate ester metabolites in seawater, sediments, and biota from an urbanized marine inlet by LC/ESI-MS/MS[J]. Environmental Science and Technology, 2009, 43: 6262-6268
[5] Calafat A M, Slakman A R, Silva M J. Automated solid phase extraction and quantitative analysis of human milk for 13 phthalate metabolites[J]. Journal of Chromatography B: Biomedical Sciences and Applications, 2004, 805: 49-56
[6] Jonsson S, Ejlertsson J, Ledin A. Mono-and diesters from o-phthalic acid in leachates from different European landfills[J]. Water Research, 2003 ,37: 609-617
[7] Jonsson S, Ejlertsson J, Svensson B H. Behaviour of mono- and diesters of o-phthalic acid in leachates released during digestion of municipal solid waste under landfill conditions[J]. Advances in Environmental Research, 2003, 7: 429-440
[8] Salim C J, Liu H, Kennedy J F. Comparative study of the adsorption on chitosan beads of phthalate esters and their degradation products[J]. Carbohydrate Polymers, 2010, 81: 640-644
[9] Subhankar C, Tapan K D. Metabolism of benzyl phthalate by Gordonia sp. stain MTCC 4818[J]. Biochemical and Biophysical Research Communications, 2003, 309: 36-43
[10] Saito T, Hong P, Tanabe R. Enzymatic hydrolysis of structurally diverse phthalic acid esters by porcine and bovine pancreatic cholesterol esterases[J]. Chemosphere, 2010, 81: 1544-1548
[11] Wang Xuejiang(王学江), Zhao Jianfu(赵建夫), Xia Siqing(夏四清). Adsorption of sulfosalicylic acid on amino modified polystyrene[J]. Environmental Chemistry(环境化学), 2004, 3(5): 269-273
[12] Pan Bingcai(潘丙才), Zhang Quanxing(张全兴). Sorption enhancement of aromatic sulfonates onto an aminated hyer-cross- linked polymer[J]. Environmental Science and Technology(环境科学与技术), 2005, 39: 3308-3313
[13] Pan B C, Xiong Y. Role of amination of a polymeric adsorbent on phenol adsorption from aqueous solution[J]. Chemosphere, 2003, 51: 953-962
[14] GB 5760—86
[15] GB 8144—87
[16] Salim C J, Liu H, Kennedy J F. Comparative study of the adsorption on chitosan beads of phthalate esters and their degradation products[J]. Carbohydrate Polymers, 2010, 81: 640-644
[17] Wang J L, Chen L J, Shi H C. Microbial degradation of phthalic acid esters under anaerobic digestion of sludge[J]. Chemosphere, 2000, 41: 1245-1248
[18] Zhao Ping(赵平), Zhang Yueping(张月萍), Ren Peng(任鹏). Adsorption process of proanthocyanidins in AB-8 macroporous resin[J]. CIESC Journal (化工学报), 2013, 64(3): 980-985
[19] Zhang Yanhao(章燕豪). Adsorption(吸附作用)[M]. Shanghai: Shanghai Scientific and Technical Literature Publishing House, 1988
[20] Song Yinghua(宋应华), Zhu Jiawen(朱家文), Chen Kui(陈葵), Wu Bin(武斌). Adsorption of erythromycin on macroporous resins and thermodynamic analysis[J]. Journal of Chemical Industry and Engineering(China)(化工学报), 2006, 57(4): 715-718
[21] Huang Jiangou(黄贱苟), Xu Mancai(徐满才), Li Haitao(李海涛), Shi Zuoqing(史作清), Shi Rongfu(施荣富), He Binglin(何炳林). A thermodynamic study on adsorption of phenols onto D301 resin[J]. Ion Exchange and Adsorption(离子交换与吸附), 2003, 19(1): 37-42
[22] Sun Yue(孙越), Chen Jinlong(陈金龙). Adsorption of resorcinol from aqueous solution on hypercrosslinked polymeric adsorbents with tertiary amino croups[J]. Acta Polymerica Sinica(高分子学报), 2005, 12(6): 803-806
[23] Dang Xifeng(党西峰), Sun Aiju(孙爱菊), Wei Jianyi(魏建毅). Determination of free aliphatic alcohol in alkyl sulphate by IR spectroscopy[J]. Guangzhou Chemicals(广州化工), 1991(2): 58
[24] Sun Yue(孙越), Tong Jian(童建), Li Aimin(李爱民). Study on adsorption behaviors of tannin from aqueous solution on three polymeric resins[J]. Ion Exchange and Adsorption(离子交换与吸附), 2007, 23(6): 512-518
[25] Fan Jun, Yang Weiben, Li Aimin. Adsorption of phenol bisphenol A and nonylphenol ethoxylates onto hypercrosslinked and aminated adsorbents[J]. Reactive and Functional Polymers, 2011, 71: 994-1000
[26] Wang Jinnan, Zhou Yang, Li Aimin, Xu Li. Adsorption of humic acid by bi-functional resin JN-10 and the effect of alkali-earth metal ions on the adsorption[J]. Journal of Hazardous Materials, 2010, 176: 1018-1026
[27] Qiu Yuping, Chen Jinlong, Li Aimin, Zhang Quanxing, Huang Minsheng. Adsorption of 2,4-D on modified hypercrosslinked polystyrene (NDA-99) and XAD-4 resin[J]. Chinese Journal of Polymer Science, 2005, 23(4): 435-440
[28] Zhang Qingjian(张庆建), Xu Zhengwen(许正文), Wang Hailing(王海玲). Adsorption behavior of p-nitroaniline on macroporous polymer and its application[J]. Ion Exchange and Adsorption(离子交换与吸附), 2006, 22(6): 503-511
[29] Li Jiazheng(李家政), Ou Lailiang(欧来良), Shi Zuoqing(史作清), Yao Kangde(姚康德). Adsorption from aqueous solution based on the synergism between hydrogen bonding and hydrophobic interactions [J]. Ion Exchange and Adsorption(离子交换与吸附), 2005, 21(2): 97-102
[30] Zhou Wei(周玮), Sun Yue(孙越), Wang Mujun(王穆君), Zhang Quanxing(张全兴). Study on adsorption behaviors of acid 4B on two adsorption resins[J]. Ion Exchange and Adsorption (离子交换与吸附), 2004, 20(6): 526-532

复合功能树脂NXD-2对水中邻苯二甲酸单丁酯的去除性能

Removal of mono-n-butyl phthalate in aqueous phase by bifunctional polymeric adsorbent NXD-2

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