碱催化裂解甘蔗渣制备2,3-二氢苯并呋喃和苯

doi:10.3969/j.issn.0438-1157.2014.05.016

化工学报 ›› 2014, Vol. 65 ›› Issue (5): 1667-1672.DOI: 10.3969/j.issn.0438-1157.2014.05.016

• 催化、动力学与反应器 • 上一篇下一篇

碱催化裂解甘蔗渣制备2,3-二氢苯并呋喃和苯

王新德¹, 冷帅¹, 邱会哲¹, 王磊¹, 刘景梅², 马凤云², 王建国¹

1 浙江工业大学化学工程与材料学院, 浙江杭州 310032;
2 新疆大学化学化工学院, 新疆乌鲁木齐 830046

收稿日期:2013-12-30 修回日期:2014-04-08 出版日期:2014-05-05 发布日期:2014-05-05
通讯作者: 王建国
基金资助:
国家重点基础研究发展计划项目（2013CB733501）。

Production of 2, 3-dihydrobenzofuran and benzene by catalytic pyrolysis of bagasse over base catalysts

WANG Xinde¹, LENG Shuai¹, QIU Huizhe¹, WANG Lei¹, LIU Jingmei², MA Fengyun², WANG Jianguo¹

1 School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China;
2 School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, Xinjiang, China

Received:2013-12-30 Revised:2014-04-08 Online:2014-05-05 Published:2014-05-05
Supported by:
supported by the National Basic Research Program of China (2013CB733501).

摘要/Abstract

摘要： 通过管式炉热裂解实验装置考察了氧化物、复合氧化物、盐和负载型Na₂CO₃作为催化剂对甘蔗渣热裂解产物（二氢苯并呋喃和苯）选择性的影响。结果表明，氧化物、复合氧化物和盐催化剂对高附加值的2，3-二氢苯并呋喃有非常好的选择性，在复合氧化物上产率可达14.15%；而Na₂CO₃负载型热裂解催化剂对苯的选择性较高，其中，在Na₂CO₃/TiO₂催化剂上产率可达到22.42%。

关键词: 热解, 甘蔗渣, 化学品, 催化剂, 选择性

Abstract: The influence of different pyrolysis catalysts (oxide, composite oxide, salts and supported Na₂CO₃) for bagasse on product (2, 3-dihydrobenzofuran and benzene) yield was investigated by pyrolysis experiment. Oxide, composite oxide and salt catalysts had high selectivity for high value 2, 3-dihydrobenzofuran (2, 3-DHB), with the highest yield (14.15%) over composite oxide. Supported Na₂CO₃ catalysts had high selectivity for benzene and the yield was as high as 22.4% over Na₂CO₃/TiO₂.

Key words: pyrolysis, bagasse, chemical, catalyst, selectivity

中图分类号:

S216.2

王新德, 冷帅, 邱会哲, 王磊, 刘景梅, 马凤云, 王建国. 碱催化裂解甘蔗渣制备2,3-二氢苯并呋喃和苯[J]. 化工学报, 2014, 65(5): 1667-1672.

WANG Xinde, LENG Shuai, QIU Huizhe, WANG Lei, LIU Jingmei, MA Fengyun, WANG Jianguo. Production of 2, 3-dihydrobenzofuran and benzene by catalytic pyrolysis of bagasse over base catalysts[J]. CIESC Journal, 2014, 65(5): 1667-1672.

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碱催化裂解甘蔗渣制备2,3-二氢苯并呋喃和苯

Production of 2, 3-dihydrobenzofuran and benzene by catalytic pyrolysis of bagasse over base catalysts

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