MnCl2-CaCl2-NH3再吸附温度提升系统储能特性

doi:10.11949/j.issn.0438-1157.20151212

化工学报 ›› 2016, Vol. 67 ›› Issue (4): 1453-1458.DOI: 10.11949/j.issn.0438-1157.20151212

MnCl₂-CaCl₂-NH₃再吸附温度提升系统储能特性

朱芳啟, 江龙, 王丽伟, 王如竹

上海交通大学机械与动力工程学院, 上海 200240

收稿日期:2015-07-29 修回日期:2015-11-20 出版日期:2016-04-05 发布日期:2016-04-05
通讯作者: 王丽伟
基金资助:
国家优秀青年科学基金项目(51222601)。

Energy storage properties of MnCl₂-CaCl₂-NH₃ resorption temperature-lifting system

ZHU Fangqi, JIANG Long, WANG Liwei, WANG Ruzhu

School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Received:2015-07-29 Revised:2015-11-20 Online:2016-04-05 Published:2016-04-05
Supported by:
supported by the National Science Foundation of China for Excellent Young Scholars (51222601).

摘要/Abstract

摘要：

吸附储热因其储热密度高、储热周期长、工作模式灵活而备受关注。基于热化学变温再吸附原理,构建了低品位热能温度提升实验系统,并采用吸附工质对MnCl₂-CaCl₂-NH₃对其升温储能特性进行了理论分析和实验研究。结果表明在储热、释热温度分别为135℃和140℃的条件下,最大储热密度和最大潜热显热比分别为614 kJ·kg^-1、0.418。在储热、释热温度分别为125℃和130℃的条件下,最大储热效率为28.57%。实验验证了热化学温度提升系统的可行性。

关键词: 吸附剂, 吸附, 热力学, 能量密度, 温度提升

Abstract:

The sorption thermal energy storage has drawn burgeoning attention due to the high energy storage density, long-term heat storage capability and flexible operating modes. A novel thermochemical temperature-lifting system is established for the integrated energy storage and energy upgrade of low-grade thermal energy based on thermochemical temperature-lifting resorption technology. The resorption working pair MnCl₂-CaCl₂-NH₃ is selected to investigate the performance of the energy storage cycle theoretically and experimentally. Results indicate that the highest thermal storage density and latent/sensible heat ratio are 614 kJ·kg^-1 and 0.418 when the heat charging and discharging temperature are 135℃ and 140℃,respectively. The highest heat storage efficiency is 28.57% when the heat charging and discharging temperature are 125℃ and 130℃. The experiments verify the feasibility of the system for utilizing the low-grade thermal energy.

Key words: adsorbents, adsorption, thermodynamics, energy density, energy upgrade

中图分类号:

TK172

朱芳啟, 江龙, 王丽伟, 王如竹. MnCl₂-CaCl₂-NH₃再吸附温度提升系统储能特性[J]. 化工学报, 2016, 67(4): 1453-1458.

ZHU Fangqi, JIANG Long, WANG Liwei, WANG Ruzhu. Energy storage properties of MnCl₂-CaCl₂-NH₃ resorption temperature-lifting system[J]. CIESC Journal, 2016, 67(4): 1453-1458.

参考文献 22

[1]	MURADOV D, SHADIEV O. Experimental investigation of the operation of an intermittent solar refrigerator[C]//Proc. All. Union Conf. on Utilization of Solar Energy. Moscow, 1969: 347-354.
[2]	闫霆, 李卉, 马良, 等. 基于热化学再吸附变温原理的低品位热能升温储能特性[J]. 上海交通大学学报, 2013, 47 (11): 1717-1722. YAN T, LI H, MA L, et al. Integrated energy storage and energy upgrade of low-grade thermal energy based on thermochemical resorption heat transformer[J]. Journal of Shanghai Jiao Tong University, 2013, 47 (11): 1717-1722.
[3]	白立光, 朱吉钦, 陈标华, 等. 离子液体在传热及相变储热中的应用研究进展[J]. 化工学报, 2010, 61 (12): 3037-3043. BAI L G, ZHU J Q, CHEN B H, et al. Applications of ionic liquids in heat transfer and heat storage process[J].CIESC Journal, 2010, 61 (12): 3037-3043.
[4]	张寅平, 胡汉平, 孔祥冬.相变贮能: 理论和应用[M]. 合肥: 中国科技大学出版社, 1996. ZHANG Y P, HU H P, KONG X D. Phase Change Energy Storage: Theory and Application[M]. Hefei: University of Science and Technology of China Press, 1996.
[5]	FARID M M, KHUDHAIR A M, RAZACK S A K, et al. A review on phase change energy storage: materials and applications[J]. Energy Conversion and Management, 2004, 45: 1597-1615.
[6]	谢望平, 汪南, 朱冬生, 等. 相变材料强化传热研究进展[J]. 化工进展, 2008, 27 (2): 190-195. XIE W P, WANG N, ZHU D S, et al. Review of heat transfer enhancement of the PCMs[J]. Chemical Industry and Engineering Process, 2008, 27 (2): 190-195.
[7]	李廷贤, 李卉, 闫霆. 大容量热化学吸附储热原理及性能分析[J]. 储能科学与技术, 2014, 3 (3): 236-243. LI T X, LI H, YAN T. Performance analysis of high-capacity thermal energy storage using solid-gas thermochemical sorption principle[J]. Energy Storage Science and Technology, 2014, 3 (3): 236-243.
[8]	韩瑞端, 王沣浩, 郝吉波. 高温蓄热技术的研究现状及展望[J]. 建筑节能, 2011, 39 (247): 32-38. HAN R D, WANG F H, HAO J B. Research progress and prospect of high temperature thermal storage[J]. Building Energy Efficiency, 2011, 39 (247): 32-38.
[9]	YAN T, WANG R Z, WANG L W, et al. A review of promising candidate reactions for chemical heat storage[J]. Renewable and Sustainable Energy Reviews, 2015, 43: 13-31.
[10]	FREDERIC K, KEVYN J. A review on chemisorption heat storage in low-energy buildings[J]. Energy Procedia, 2014, 57: 2333-2341.
[11]	LI T X, WANG R Z, KIPLAGAT J K. Performance analysis of an integrated energy storage and energy upgrade thermochemical solid-gas sorption system for seasonal storage of solar thermal energy[J]. Energy, 2013, 50: 454-67.
[12]	ZONDAG H, KIKKERT B, SMEDING S, et al. Prototype thermochemical heat storage with open reactor system[J]. Appl. Energy, 2013, 109: 360-5.
[13]	HAIJE W G, VEDHUIS J B, SMEDING S F, et al. Solid/vapour sorption heat transformer: design and performance[J]. Applied Thermal Energy, 2007, 27 (8): 1371-6.
[14]	BAO H, WANG R, OLIVEIRA R, et al. Resorption system for cold storage and long-distance refrigeration[J]. Appl. Energy, 2012, 93: 479-87.
[15]	王如竹, 王丽伟, 吴静怡. 吸附式制冷理论与应用[M]. 北京: 科学出版社, 2007. WANG R Z, WANG L W, WU J Y. Theory and Application of Adsorption Refrigeration[M]. Beijing: Science Press, 2007.
[16]	WANG L W, METCALF S J, CRITOPH R E, et al. Development of thermal conductive consolidated activated carbon for adsorption refrigeration[J]. Carbon, 2012, 50 (3): 977-86.
[17]	马良. 基于低品位热能能量品位提升的热化学吸附变温器储能特性研究[D]. 上海: 上海交通大学, 2012. MA L. Study on the energy storage character of thermo-chemical sorption transformer based on the energy grade lift of low-grade thermal energy[D]. Shanghai: Shanghai Jiao Tong University, 2012.
[18]	陈恒. 低温位驱动的固-气热化学吸附制冷工质对及变压解吸特性研究[D]. 上海:上海交通大学, 2011. CHEN H. Study on the characteristics of decreasing-pressure desorption and working pairs of the solid-gas thermochemical sorption refrigeration driven by low-temperature thermal energy[D]. Shanghai: Shanghai Jiao Tong University, 2011.
[19]	LI T X, WANG R Z, WANG L W, et al. Experimental investigation of an innovative Dual-mode chemisorption refrigeration system based on multifunction heat pipes[J]. International Journal of Refrigeration, 2008, 31: 1104-1112.
[20]	SORIN M, SPINNER B, STITOU D. Thermodymic techniques for the conceptual design of thermochemical refrigerators using two salt materials[J]. Chemical Engineering Science, 2002, 57: 4243-4251.
[21]	HUANG H J, WU G B, YANG J, et al. Modeling of gas-solid chemisorption in chemical heat pumps[J]. Separation and Purification Technology, 2004, 34: 191-200.
[22]	闫霆, 王如竹, 李卉,等. 耦合变压解析-变温吸附技术的热化学变温器储能特性研究[J]. 工程热物理学报, 2014, 35 (8): 1470-1474. YAN T, WANG R Z, LI H, et al. Study on the energy storage performance of thermochemical heat transformer coupled with pressure-reducing desorption and temperature-lift adsorption[J]. Journal of Engineering Thermophysics, 2014, 35 (8): 1470-1474.

MnCl₂-CaCl₂-NH₃再吸附温度提升系统储能特性

Energy storage properties of MnCl₂-CaCl₂-NH₃ resorption temperature-lifting system

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