胍基聚合物接枝改性制备抗菌抗污染超滤膜

doi:10.11949/j.issn.0438-1157.20180551

化工学报 ›› 2018, Vol. 69 ›› Issue (11): 4869-4878.DOI: 10.11949/j.issn.0438-1157.20180551

• 材料化学工程与纳米技术 • 上一篇下一篇

胍基聚合物接枝改性制备抗菌抗污染超滤膜

孙雪飞¹, 高勇强¹, 赵颂¹, 张文¹, 王志¹, 王晓琳²

1. 化学工程联合国家重点实验室, 天津大学化工学院化学工程研究所, 天津市膜科学与海水淡化技术重点实验室, 天津 300072;
2. 化学工程联合国家重点实验室, 清华大学化学工程系, 北京 100084

收稿日期:2018-05-24 修回日期:2018-07-20 出版日期:2018-11-05 发布日期:2018-11-05
通讯作者: 赵颂
基金资助:
国家自然科学基金项目（21776205）；天津市应用基础与前沿技术研究计划项目（15JCQNJC43400）。

Ultrafiltration membrane with antibacterial and antifouling properties by grafting guanidine based polymer

SUN Xuefei¹, GAO Yongqiang¹, ZHAO Song¹, ZHANG Wen¹, WANG Zhi¹, WANG Xiaolin²

1. State Key Laboratory of Chemical Engineering, Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300072, China;
2. State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2018-05-24 Revised:2018-07-20 Online:2018-11-05 Published:2018-11-05
Supported by:
supported by the National Natural Science Foundation of China (21776205) and the Tianjin Research Program of Basic Research and Frontier Technology (15JCQNJC43400).

摘要/Abstract

摘要：

表面接枝杀菌材料是提高膜抗菌和抗污染性能的常用手段。胍基化合物具有杀菌广谱、易制备、低毒等优点，已受到研究者的广泛关注。通过聚乙烯亚胺和盐酸胍的熔融聚合反应制备胍基聚合物（聚乙烯亚胺胍盐酸盐，PEIGH），并利用聚多巴胺中间层将其接枝到聚砜超滤膜表面。结果表明，PEIGH具有良好的抗菌性能，经其改性后的超滤膜润湿性能提高，纯水通量提高了11%~98%，牛血清蛋白截留率由96.6%提高到98.3%以上。抗菌性能、抗有机物污染和抗生物污染性能均得到明显改善。

关键词: 膜, 超滤, 聚乙烯亚胺胍盐酸盐, 表面改性, 选择性, 抗生物污染

Abstract:

Surface grafting bactericidal materials are commonly used methods to improve the antibacterial and anti-pollution properties of membranes. Guanidine compounds have received a lot of attentions due to their efficient and broad-spectrum antibacterial properties, easy preparation and low toxicity to the mammalian cell. Herein, a guanidine based polymer, namely PEIGH, was prepared through melt phase polycondensation of polyethyleneimine and guanidine hydrochloride, then used for ultrafiltration membrane surface modification with the assist of polydopamine. The results show that the synthesized PEIGH possesses good antibacterial property. Compared to the unmodified membranes, the membranes modified by PEIGH have better wettability. The permeation flux increases by 11%-98% and rejection for bovine serum albumin raises from 96.6% to 98.3% above. Antibacterial, anti-organic and anti-biobial properties have been significantly improved.

Key words: membranes, ultrafiltration, PEIGH, surface modification, selectivity, antibiofouling

中图分类号:

TQ028.8

孙雪飞, 高勇强, 赵颂, 张文, 王志, 王晓琳. 胍基聚合物接枝改性制备抗菌抗污染超滤膜[J]. 化工学报, 2018, 69(11): 4869-4878.

SUN Xuefei, GAO Yongqiang, ZHAO Song, ZHANG Wen, WANG Zhi, WANG Xiaolin. Ultrafiltration membrane with antibacterial and antifouling properties by grafting guanidine based polymer[J]. CIESC Journal, 2018, 69(11): 4869-4878.

参考文献 38

[1]	DAN W, MICHAEL R B. The fouling and cleaning of ultrafiltration membranes during the filtration of model tea component solutions[J]. Journal of Food Process Engineering, 2010, 30(3):293-323.
[2]	ZHU L J, SONG H M, WANG J R, et al. Polysulfone hemodiafiltration membranes with enhanced anti-fouling and hemocompatibility modified by poly(vinyl pyrrolidone) via in situ cross-linked polymerization[J]. Materials Science and Engineering C, 2017, 74:159-166.
[3]	SUN H Z, TANG B B, WU P Y. Development of hybrid ultrafiltration membranes with improved water separation properties using modified superhydrophilic metal-organic framework nanoparticles[J]. ACS Applied Materials & Interfaces, 2017, 9(25):21473-21484.
[4]	WANG H D, LU X F, WANG Z H, et al. Improved surface hydrophilicity and antifouling property of polysulfone ultrafiltration membrane with poly(ethylene glycol) methyl ether methacrylate grafted graphene oxide nanofillers[J]. Applied Surface Science, 2017, 425:603-613.
[5]	REZAEE R, NASSERI S, MAHVI A H, et al. Fabrication and characterization of a polysulfone-graphene oxide nanocomposite membrane for arsenate rejection from water[J]. Journal of Environmental Health Science Engineering, 2015, 13:61-72.
[6]	PARK M S, PARK B J, KIM N U, et al. Ultrafiltration membranes based on hybrids of an amphiphilic graft copolymer and titanium isopropoxide[J]. Journal of Applied Polymer Science, 2018, 135(12):45932-45942.
[7]	ZHANG J J, XU Y N, CHEN S W, et al. Enhanced antifouling and antibacterial properties of poly(ether sulfone) membrane modified through blending with sulfonated poly(aryl ether sulfone) and copper nanoparticles[J]. Applied Surface Science, 2018, 434:806-815.
[8]	ABIDIN M N Z, GOH P S, ISMAIL A F, et al. Antifouling polyethersulfone hemodialysis membranes incorporated with poly(citric acid) polymerized multi-walled carbon nanotubes[J]. Materials Science and Engineering C, 2016, 68:540-550.
[9]	KO K, YU Y J, KIM M J, et al. Improvement in fouling resistance of silver-graphene oxide coated polyvinylidene fluoride membrane prepared by pressurized filtration[J]. Separation and Purification Technology, 2018, 194:161-169.
[10]	WANG H Y, ZHAO X Z, HE C J. Innovative permeation and antifouling properties of PVDF ultrafiltration membrane with stepped hollow SiO2 microspheres in membrane matrix[J]. Materials Letters, 2016, 182:376-379.
[11]	EREN E, SARIHAN A, EREN B, et al. Preparation, characterization and performance enhancement of polysulfone ultrafiltration membrane using PBI as hydrophilic modifier[J]. Journal of Membrane Science, 2015, 475:1-8.
[12]	LIU Z X, MI Z M, CHEN C H, et al. Preparation of hydrophilic and antifouling polysulfone ultrafiltration membrane derived from phenolphthalin by copolymerization method[J]. Applied Surface Science, 2017, 401:69-78.
[13]	ZHANG Q H, JIANG J X, GAO F, et al. Engineering high-effective antifouling polyether sulfone membrane with P(PEG-PDMS-KH570)@SiO2 nanocomposite via in-situ sol-gel process[J]. Chemical Engineering Journal, 2017, 321:412-423.
[14]	ALSOHAIMI I H, KUMAR M, ALGAMDI M S, et al. Antifouling hybrid ultrafiltration membranes with high selectivity fabricated from polysulfone and sulfonic acid functionalized TiO2 nanotubes[J]. Chemical Engineering Journal, 2017, 316:573-583.
[15]	GAO H W, SUN X H, GAO C L. Antifouling polysulfone ultrafiltration membranes with sulfobetaine polyimides as novel additive for the enhancement of both water flux and protein rejection[J]. Journal of Membrane Science, 2017, 542:81-90.
[16]	LI R J, WANG X N, CAI X, et al. A facile strategy to prepare superhydrophilic polyvinylidene fluoride (PVDF) based membranes and the thermodynamic mechanisms underlying the improved performance[J]. Separation and Purification Technology, 2018, 197:271-280.
[17]	YU S P, ZHANG X, LI F Z, et al. Poly(vinyl pyrrolidone) modified poly(vinylidene fluoride) ultrafiltration membrane via a two-step surface grafting for radioactive wastewater treatment[J]. Separation and Purification Technology, 2018, 194:404-409.
[18]	HOMAYOONFAL M, AKBARI A, MEHRNIA M R. Preparation of polysulfone nanofiltration membranes by UV-assisted grafting polymerization for water softening[J]. Desalination, 2010, 263(1/2/3):217-225.
[19]	LIU F, HASHIM N A, LIU Y T, et al. Progress in the production and modification of PVDF membranes[J]. Journal of Membrane Science, 2011, 375(1/2):1-27.
[20]	MILLER D J, DREYER D R, BIELAWSKI C W, et al. Surface modification of water purification membranes[J]. Angew. Chem. Int. Ed., 2017, 56(17):4662-4711.
[21]	ZHANG D Y, XIONG S, SHI Y S, et al. Antifouling enhancement of polyimide membrane by grafting DEDA-PS zwitterions[J]. Chemosphere, 2018, 198:30-39.
[22]	LIN Z, WU X D, ZHONG W Z, et al. Towards improved antifouling ability and separation performance of polyethersulfone ultrafiltration membranes through poly(ethylenimine) grafting[J]. Journal of Membrane Science, 2018, 554:125-133.
[23]	WAN P, BERNARDS M, DENG B L. Modification of polysulfone (PSF) hollow fiber membrane (HFM) with zwitterionic or charged polymers[J]. Industrial & Engineering Chemistry Research, 2017, 56(26):7576-7584.
[24]	WU C R, WANG Z Y, LIU S H, et al. Simultaneous permeability, selectivity and antibacterial property improvement of PVC ultrafiltration membranes via in-situ quaternization[J]. Journal of Membrane Science, 2018, 548:50-58.
[25]	RAMANAN S N, SHAHKARAMIPOUR N, TRAN T, et al. Self-cleaning membranes for water purification by co-deposition of photo-mobile 4,4'-azodianiline and bio-adhesive polydopamine[J]. Journal of Membrane Science, 2018, 554:164-174.
[26]	SHAHKARAMIPOUR N, RAMANAN S N, FISTER D. Facile grafting of zwitterions onto the membrane surface to enhance antifouling properties for wastewater reuse[J]. Industrial & Engineering Chemistry Research, 2017, 56(32):9202-9212.
[27]	SOYEKWO F, ZHANG Q G, ZHEN L, et al. Borate crosslinking of polydopamine grafted carbon nanotubes membranes for protein separation[J]. Chemical Engineering Journal, 2018, 337:110-121.
[28]	KIRSCHNER A Y, CHANG C C, KASEMSET S, et al. Fouling-resistant ultrafiltration membranes prepared via co-deposition of dopamine/zwitterion composite coatings[J]. Journal of Membrane Science, 2017, 541:300-311.
[29]	彭开美, 丁伟, 涂伟萍, 等. 胍基聚合物的构建及应用[J]. 化学学报, 2016, 74(9):713-725. PENG K M, DING W, TU W P, et al. Construction of guanidinium-rich polymers and their applications[J]. Acta Chimica Sinica, 2016, 74(9):713-725.
[30]	周艺璇, 王志, 董晨曦, 等. 双胍基化聚乙烯胺改性制备抗生物污染反渗透膜[J]. 化工学报, 2018, 69(2):858-865. ZHOU Y X, WANG Z, DONG C X, et al. Biguanidine functionalized polyvinylamine modified reverse osmosis membrane with improved anti-bacterial property[J]. CIESC Journal, 2018, 69(2):858-865.
[31]	LI X, CAO Y M, YU H J, et al. A novel composite nanofiltration membrane prepared with PHGH and TMC by interfacial polymerization[J]. Journal of Membrane Science, 2014, 466:82-91.
[32]	NIKKOLA J, LIU X, LI Y, et al. Surface modification of thin film composite RO membrane for enhanced anti-biofouling performance[J]. Journal of Membrane Science, 2013, 444:192-200.
[33]	GUAN Y, XIAO H N, SULLIVAN H, et al. Antimicrobial-modified sulfite pulps prepared by in situ copolymerization[J]. Carbohydrate Polymers, 2007, 69(4):688-696.
[34]	ZHANG Y M, JIANG J M, CHEN Y M. Synthesis and antimicrobial activity of polymericguanidine and biguanidine salts[J]. Polymer, 1999, (40):6189-6198.
[35]	AHANI E, MONTAZER M, TOLIYAT T, et al. A novel biocompatible antibacterial product:nanoliposomes loaded with poly(hexamethylene biguanide chloride)[J]. Journal of Bioactive and Compatible Polymers, 2016, 32(3):242-262.
[36]	王冬梅, 曹金丽, 张怡, 等. 红外光谱法研究聚乙烯亚胺的结构[J]. 光谱学与光谱分析, 2016, 36(10):199-200. WANG D M, CAO J L, ZHANG Y, et al. The structure characterization of polyethylenimine via FTIR[J]. Spectroscopy and Spectral Analysis, 2016, 36(10):199-200.
[37]	ZANGMEISTER R A, MORRIS T A, TARLOV M J. Characterization of polydopamine thin films deposited at short times by autoxidation of dopamine[J]. Langmuir, 2013, 29(27):8619-8628.
[38]	HUANG L C, ZHAO S, WANG Z, et al. In situ immobilization of silver nanoparticles for improving permeability, antifouling and anti-bacterial properties of ultrafiltration membrane[J]. Journal of Membrane Science, 2016, 499:269-281.

胍基聚合物接枝改性制备抗菌抗污染超滤膜

Ultrafiltration membrane with antibacterial and antifouling properties by grafting guanidine based polymer

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 38

相关文章 15

编辑推荐

Metrics

本文评价

[1]	邵苛苛, 宋孟杰, 江正勇, 张旋, 张龙, 高润淼, 甄泽康. 水平方向上冰中受陷气泡形成和分布实验研究[J]. 化工学报, 2023, 74(S1): 161-164.
[2]	吴延鹏, 李晓宇, 钟乔洋. 静电纺丝纳米纤维双疏膜油性细颗粒物过滤性能实验分析[J]. 化工学报, 2023, 74(S1): 259-264.
[3]	范孝雄, 郝丽芳, 范垂钢, 李松庚. LaMnO₃/生物炭催化剂低温NH₃-SCR催化脱硝性能研究[J]. 化工学报, 2023, 74(9): 3821-3830.
[4]	胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765.
[5]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[6]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.
[7]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[8]	张佳怡, 何佳莉, 谢江鹏, 王健, 赵鹬, 张栋强. 渗透汽化技术用于锂电池生产中N-甲基吡咯烷酮回收的研究进展[J]. 化工学报, 2023, 74(8): 3203-3215.
[9]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[10]	张贲, 王松柏, 魏子亚, 郝婷婷, 马学虎, 温荣福. 超亲水多孔金属结构驱动的毛细液膜冷凝及传热强化[J]. 化工学报, 2023, 74(7): 2824-2835.
[11]	李盼, 马俊洋, 陈志豪, 王丽, 郭耘. Ru/α-MnO₂催化剂形貌对NH₃-SCO反应性能的影响[J]. 化工学报, 2023, 74(7): 2908-2918.
[12]	韩奎奎, 谭湘龙, 李金芝, 杨婷, 张春, 张永汾, 刘洪全, 于中伟, 顾学红. 四通道中空纤维MFI分子筛膜用于二甲苯异构体分离[J]. 化工学报, 2023, 74(6): 2468-2476.
[13]	蔡斌, 张效林, 罗倩, 党江涛, 左栗源, 刘欣梅. 导电薄膜材料的研究进展[J]. 化工学报, 2023, 74(6): 2308-2321.
[14]	朱兴驰, 郭志远, 纪志永, 汪婧, 张盼盼, 刘杰, 赵颖颖, 袁俊生. 选择性电渗析镁锂分离过程模拟优化[J]. 化工学报, 2023, 74(6): 2477-2485.
[15]	陈朝光, 贾玉香, 汪锰. 以低浓度废酸驱动中和渗析脱盐的模拟与验证[J]. 化工学报, 2023, 74(6): 2486-2494.