化工学报 ›› 2025, Vol. 76 ›› Issue (5): 2101-2118.DOI: 10.11949/0438-1157.20241215

• 综述与专论 • 上一篇    下一篇

基于新型有机多孔聚合物的智能响应膜研究进展

陆艳秋(), 狄扬, 石文博, 殷聪聪, 汪勇()   

  1. 东南大学能源与环境学院,江苏 南京 210096
  • 收稿日期:2024-10-31 修回日期:2025-01-17 出版日期:2025-05-25 发布日期:2025-06-13
  • 通讯作者: 汪勇
  • 作者简介:陆艳秋(1991—),女,博士,副研究员,yanqiulu@seu.edu.cn
  • 基金资助:
    国家自然科学基金项目(U24A2083);江苏省基础研究计划(自然科学基金)青年基金项目(BK20241331)

Research progress of smart responsive membranes based on novel porous organic polymers

Yanqiu LU(), Yang DI, Wenbo SHI, Congcong YIN, Yong WANG()   

  1. School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu, China
  • Received:2024-10-31 Revised:2025-01-17 Online:2025-05-25 Published:2025-06-13
  • Contact: Yong WANG

摘要:

膜分离技术因其高效与环境友好的特性,在多个领域得到了广泛应用。然而,传统膜在复杂环境中的适应性有限,难以满足不断提升的分离需求。智能响应膜能够响应光、温度、pH、电场等外界刺激,实现膜结构与性能的动态调控,展现出应对多变应用需求的优势。随着共价有机框架、金属有机框架和共轭微孔聚合物等新型有机多孔聚合物的发展,智能响应膜的设计和优化迎来了新的机遇。该综述总结了新型有机多孔聚合物智能响应膜的研究进展,分析了不同外界刺激对膜结构和性能的调控,梳理了制膜方法及响应基团的引入策略,并探讨了未来的发展方向与挑战。

关键词: 膜, 分离, 智能响应, 新型有机多孔聚合物, 纳滤

Abstract:

Membrane separation technology has been widely used in many fields due to its high efficiency and environmental friendliness. However, traditional membranes have limited adaptability in complex environments and are difficult to meet the ever-increasing separation needs. In contrast, smart responsive membranes can dynamically modify their structure and properties in response to external stimuli, such as light, temperature, pH, or electric fields, offering greater flexibility and improved performance across a wide range of applications. The development of novel porous organic polymers, such as covalent organic frameworks, metal organic frameworks, and conjugated microporous polymers, has paved the way for new possibilities in the design and optimization of these membranes. This review presents recent advancements in smart responsive membranes based on porous organic polymers, with a focus on how different external stimuli influence their structure and performance. Additionally, it explores various fabrication methods, strategies for integrating responsive groups, and addresses potential challenges along with future research directions in the field.

Key words: membrane, separation, smart response, novel organic porous polymers, nanofiltration

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