化工学报 ›› 2014, Vol. 65 ›› Issue (2): 576-582.DOI: 10.3969/j.issn.0438-1157.2014.02.030

• 催化、动力学与反应器 • 上一篇    下一篇

热重分析法研究氢氧化镁纳米粉体的非等温分解动力学

李歌1, 李增和1, 马鸿文2, 陈登利3   

  1. 1 北京化工大学理学院, 北京 100029;
    2 中国地质大学矿物材料国家专业实验室, 北京 100083;
    3 中国石油辽阳石化亿方工业公司, 辽宁 辽阳 111003
  • 收稿日期:2013-04-14 修回日期:2013-09-18 出版日期:2014-02-05 发布日期:2014-02-05
  • 通讯作者: 李增和
  • 基金资助:

    中央高校基本科研业务费项目(ZY1348)。

Non-isothermal decomposition kinetics of nano-Mg(OH)2 using thermal gravimetric analysis

LI Ge1, LI Zenghe1, MA Hongwen2, CHEN Dengli3   

  1. 1 College of Science, Beijing University of Chemical Technology, Beijing 100029, China;
    2 National Laboratory of Mineral Materials, China University of Geosciences, Beijing 100083, China;
    3 Liaoyang Petrochemical Yifang Industries Corp., China National Petroleum Corporation, Liaoyang 111003, Liaoning, China
  • Received:2013-04-14 Revised:2013-09-18 Online:2014-02-05 Published:2014-02-05
  • Supported by:

    supported by the Fundamental Research Funds for the China Central Universities (ZY1348).

摘要: 以白云石为原料,盐酸酸溶后得到CaCl2-MgCl2滤液,采用氨水直接沉淀法制备出符合HG/T 3607—2000Ⅰ型标准的六方片状的纳米氢氧化镁。六方片厚度为25~30 nm,直径为0.3~0.4 mm。利用热重分析法对纳米氢氧化镁在不同升温速率下的热分解动力学进行研究,以期深入了解纳米氢氧化镁热分解制备纳米氧化镁粉体过程的物理化学本质。采用Kissinger法和Ozawa法计算出氢氧化镁热分解反应活化能分别为115.47 kJ·mol-1和126.04 kJ·mol-1。对热重分析数据进行处理和拟合,判断纳米氢氧化镁粉体热分解反应机理函数为Avrami-Erofeev(n=1.5)的随机成核和随后生长机理。指前因子为3.077×1010 s-1。纳米氢氧化镁经煅烧制备得到的氧化镁纳米球的直径为80~100 nm。

关键词: 纳米氢氧化镁, 热重分析, 热分解, 动力学, 纳米氧化镁

Abstract: Hexagonal nano-magnesium hydroxide with thickness of 25—30 nm and diameter of 0.3—0.4 μm was synthesized via acid immersion and ammonia precipitation from dolomites. Its quality met the standards of typeⅠ in HG/ T 3607—2000. The thermal decomposition kinetics of Mg(OH)2 was investigated by using thermal gravimetric analysis at different heating rates for deep understanding of physical chemistry in this process. The activation energies of decomposition estimated by the Kissinger and Ozawa methods were 115.47 kJ·mol-1 and 126.04 kJ·mol-1 respectively. Decomposition reaction of magnesium hydroxide was controlled by Avrami-Erofeev function (n=1.5). Pre-exponential was 3.077×1010 s-1. Nano-magnesium oxide with average diameter of 80—100 nm was prepared after calcination of magnesium hydroxide.

Key words: nano-magnesium hydroxide, thermal gravimetric analysis, thermal decomposition, kinetics, nano- magnesium oxide

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