高抗冲聚丙烯结构与性能分析的最新进展

doi:10.11949/j.issn.0438-1157.20151269

化工学报 ›› 2016, Vol. 67 ›› Issue (2): 397-403.DOI: 10.11949/j.issn.0438-1157.20151269

高抗冲聚丙烯结构与性能分析的最新进展

笪文忠¹, 屠宇侠², 徐宏彬¹, 梅利¹, 姚臻², 曹堃²

1 中国石化扬子石油化工有限公司南京研究院, 江苏南京 210047;
2 浙江大学化学工程与生物工程学院, 化学工程联合国家重点实验室, 浙江杭州 310027

收稿日期:2015-08-05 修回日期:2015-12-01 出版日期:2016-02-05 发布日期:2016-02-05
通讯作者: 曹堃
基金资助:
国家高技术研究发展计划项目(2012AA040306)。

Progress in analysis of structure and properties of hiPP

DA Wenzhong¹, TU Yuxia², XU Hongbin¹, MEI Li¹, YAO Zhen², CAO Kun²

1 Nanjing Research Institute of SINOPEC Yangzi Petrochemical Co. Ltd., Nanjing 210047, Jiangsu, China;
2 State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China

Received:2015-08-05 Revised:2015-12-01 Online:2016-02-05 Published:2016-02-05
Supported by:
supported by the National High Technology Research and Development Program of China (2012AA040306).

摘要/Abstract

摘要：

高抗冲聚丙烯(hiPP)以其优异的力学性能成为当前聚丙烯行业中的一类代表性产品,具有广阔的应用前景,关于其结构与性能的分析和关联一直都是研究的热点之一。综述了近年来关于高抗冲聚丙烯结构与性能分析的最新进展,一方面从体系相形态入手,分析提高hiPP 抗冲性能的分散相形态及其分布;另一方面从分子链结构出发,将hiPP 中各组分归纳为乙丙橡胶、乙丙短嵌段共聚物、乙丙嵌段共聚物和等规聚丙烯等,并阐述了各自的作用及影响因素。

关键词: 高抗冲聚丙烯, 结构, 性能, 分子链, 相形态

Abstract:

The high impact polypropylene (hiPP) with excellent impact resistance has become a representative product of PP in industry. Study on the relationship between structure and property is always the one of the focuses in this field. The latest research progress of structure-property correlation in recent years is reviewed. Based on the analysis on morphology, the dispersed phase distribution to achieve high impact resistance has been presented. More generally at microscopic structure, the compositions of hiPP are classified as ethylene-propylene rubber, ethylene-propylene segmented copolymer, ethylene-propylene block copolymer and isotactic polypropylene, and their respective role has been described as well as effect factors.

Key words: high impact polypropylene, structure, property, molecule chain, phase morphology

中图分类号:

TQ325.1

笪文忠, 屠宇侠, 徐宏彬, 梅利, 姚臻, 曹堃. 高抗冲聚丙烯结构与性能分析的最新进展[J]. 化工学报, 2016, 67(2): 397-403.

DA Wenzhong, TU Yuxia, XU Hongbin, MEI Li, YAO Zhen, CAO Kun. Progress in analysis of structure and properties of hiPP[J]. CIESC Journal, 2016, 67(2): 397-403.

参考文献 32

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高抗冲聚丙烯结构与性能分析的最新进展

Progress in analysis of structure and properties of hiPP

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