黄腐酸基Cd2+离子印迹聚合物的吸附性能测试

doi:10.11949/j.issn.0438-1157.20161156

摘要/Abstract

摘要：

以改性黄腐酸为功能单体，反相悬浮聚合法制备了Cd²⁺离子印迹聚合物，并研究其吸附性能。动力学模型表明，黄腐酸基Cd²⁺离子印迹聚合物对Cd²⁺的吸附符合准二级动力学吸附模型，相关系数达到0.9977；热力学研究发现，黄腐酸基Cd²⁺离子印迹聚合物吸附重金属离子的形式为单分子层表面吸附，与Langmuir等温吸附模型相符；竞争吸附实验显示，竞争离子Pb²⁺、Cr³⁺存在时，Cd²⁺/Pb²⁺、Cd²⁺/Cr³⁺的相对选择性系数分别为4.32、13.47，说明MFA-IIP对模板离子拥有较强的选择识别性能，竞争离子化合价不同，选择识别性更加显著。

关键词: 离子印迹, 改性黄腐酸, 吸附剂, 动力学, 热力学

Abstract:

Cd²⁺ ion imprinted polymer (MFA-IIP) was synthesized by inverse suspension copolymerization of modified fulvic acid monomer. Adsorption study showed that adsorption kinetics of MFA-IIP to Cd²⁺ is in accordance with pseudo-second-order kinetic model with correlation coefficient of 0.9977. The adsorption of heavy metal ions on MFA-IIP polymer thermodynamically follows single-molecule surface Langmuir adsorption model. In presence of competitive Pb²⁺and Cr³⁺ ions, the polymer exhibited strong selection and recognition to template ion with relative selectivity coefficient of Cd²⁺/Pb²⁺ and Cd²⁺/Cr³⁺ at 4.32 and 13.47, respectively. When other metal ions with different valences existed in aqueous solution, selective recognition of MFA-IIP polymer to Cd²⁺ would be much more obvious.

Key words: ion imprinted, modified fulvic acid, adsorbents, kinetics, thermodynamics

中图分类号:

TQ424.3

尚宏周, 赵敬东, 何俊男, 孙晓然. 黄腐酸基Cd²⁺离子印迹聚合物的吸附性能测试[J]. 化工学报, 2017, 68(5): 1940-1945.

SHANG Hongzhou, ZHAO Jingdong, HE Junnan, SUN Xiaoran. Absorption properties of Cd²⁺ ion imprinted poly(fulvic acid)[J]. CIESC Journal, 2017, 68(5): 1940-1945.

参考文献 33

[1]	KRYSTYNA P, ANNA K, IRENA W. Application of solid phase extraction procedures for rare earth elements determination in environmental samples[J]. Talanta, 2016, 154: 15-22.
[2]	ELHAM M, HOMAYON A P, KHALEDEH A, et al. Selective solid-phase extraction of zinc(Ⅱ) from environmental water samples using ion imprinted activated carbon[J]. Journal of AOAC INTERMATIONAL, 2015, 98(1): 206-212.
[3]	MARCO R C, VINICIUS R Z, MARIANA P, et al. Molds and resists studies for nanoimprint lithography of electrodes in low-voltage polymer thin-film transistors[J]. Journal of Electronic Materials, 2014, 43(5): 1317-1325.
[4]	FAYAZI M, TAHER M A, AFZALI D, et al. Synthesis and application of novel ion-imprinted polymer coated magnetic multi-walled carbon nanotubes for selective solid phase extraction of lead(Ⅱ) ions[J]. Materials Science and Engineering: C, 2016, 60: 365-373.
[5]	丁兰岚, 龙素群, 辉永庆, 等. 锌离子印迹聚合物的合成及固相萃取特性研究[J]. 环境科学与技术, 2013, 36(5): 28-32. DING L L, LONG S Q, HUI Y Q, et al. Zinc-ion imprinted polymer for solid-phase extraction: its synthesis and characteristics[J]. Environmental Science & Technology, 2013, 36(5): 28-32.
[6]	GÜNEY S, GÜNEY O. A novel electrochemical sensor for selective determination of uranyl ion based on imprinted polymer sol-gel modified carbon paste electrode[J]. Sensors and Actuators B: Chemical, 2016, 231: 45-53.
[7]	RAHELE Z, MASOUD G M, IMAN R. Selective voltammetric sensor for nanomolar detection of silver ions using carbon paste electrode modified with novel nanosized Ag(I)-imprinted polymer[J]. Journal of Molecular Liquids, 2016, 219: 554-560.
[8]	TAHER A, GANJALI M R, NOROUZI P, et al. A carbon paste electrode impregnated with Cd(Ⅱ) imprinted polymer as a new and high selective electrochemical sensor for determination of ultra-trace Cd(Ⅱ) in water samples[J]. Journal of Electroanalytical Chemistry, 2011, 657(1/2): 98-106.
[9]	付坤, 高云玲, 姚克俭. 离子印迹传感器选择性检测甲基汞离子[J]. 分析测试学报, 2012, 31(8): 1001-1004. FU K, GAO Y L, YAO K J. Selective determination of methylmercury ion in aqueous media with molecularly imprinted polymer fluorescent sensor[J]. Journal of Instrumental Analysis, 2012, 31(8): 1001-1004.
[10]	MOHY ELDIN M S, ABU-SAIED M A, TAMER T M, et al. Development of polystyrene based nanoparticles ions exchange resin for water purification applications[J]. Desalination and Water Treatment, 2016, 57(32): 14810-14823.
[11]	NETSANET S T, OLGA G, KIRTHI D S, et al. Application of stimuli responsive polymers for sustainable ion exchange chromatography[J]. Food and Bioproducts Processing, 2014, 92(C2): 208-225.
[12]	刘耀驰, 张晓文, 刘慧君, 等. 硫酸铀酰印迹离子交换树脂的合成及识别特性研究[J]. 高校化学工程学报, 2006, 20(4): 510-514. LIU Y C, ZHANG X W, LIU H J, et al. Synthesis of uranyl sulphate imprinted ion exchange resin and its recognition characteristics[J]. Journal of Chemical Engineering of Chinese Universities, 2006, 20(4): 510-514.
[13]	LEE D S, SONG H W, CHOI C G, et al. Pore-size reduction protocol for SiN membrane nanopore using the thermal reflow in nanoimprinting for nanobio-based sensing[J]. Journal of Biomedical Optics, 2014, 19(5): 051211.
[14]	范荣玉, 郑细鸣, 林兴. 铜(Ⅱ)离子印迹复合膜的静电组装法制备及其吸附特性[J]. 化工学报, 2014, 65(8): 3039-3047. FAN R Y, ZHENG X M, LIN X. Preparation and adsorption behavior of Cu(Ⅱ) ion-imprinted composite membranes via electrostatic assembly[J]. CIESC Journal, 2014, 65(8): 3039-3047.
[15]	肖艳春, 黄婧, 林香信, 等. 去除猪场沼液重金属Pb(Ⅱ)的离子印迹膜制备及其应用[J]. 福建农业学报, 2016, 31(1): 57-62. XIAO Y C, HUANG J, LIN X X, et al. Preparation and application of ion-imprinted membrane for Pb(Ⅱ) removal from pig farm biogas slurry[J]. Fujian Journal of Agricultural Science, 2016, 31(1): 57-62.
[16]	SUMI V S, KALA R, SAROJAM P R, et al. Imprinted polymers as drug delivery vehicles for metal-based anti-inflammatory drug[J]. International Journal of Pharmaceutics, 2008, 349(1): 30-37.
[17]	BERRIN G, SABRIYE P Ö, ESENGUL K. Voltammetric behavior and determination of doxycycline in pharmaceuticals at molecularly imprinted and non-imprinted overoxidized polypyrrole electrodes[J]. Journal of Pharmaceutical and Biomedical Analysis, 2013, 84: 263-268.
[18]	傅骏青, 王晓艳, 李金花, 等. 重金属离子印迹技术[J]. 化学进展, 2016, 28(1): 83-90. FU J Q, WANG X Y, LI J H, et al. Ion imprinting technology for heavy metal ions[J]. Progress in Chemistry, 2016, 28(1): 83-90.
[19]	MAFU L D, MSAGATI T A M, MAMBA B B. Ion-imprinted polymers for environmental monitoring of inorganic pollutants: synthesis, characterization, and applications[J]. Environmental Science and Pollution Research, 2013, 20(2): 790-802.
[20]	RAO T P, KALA R, DANIEL S. Metal ion-imprinted polymers - novel materials for selective recognition of inorganics[J]. Analytica Chimica Acta, 2006, 578(2): 105-116.
[21]	张明磊, 张朝晖, 罗丽娟, 等. 磁性Fe3O4@SiO2@CS镉离子印迹聚合物的制备及吸附性能[J]. 高等学校化学学报, 2011, 32(12): 2763-2768. ZHANG M L, ZHANG Z H, LUO L J, et al. Preparation and adsorption properties of magnetic Fe3O4@SiO2@CS cadmium ion-imprinted polymer[J]. Chemical Journal of Chinese Universities, 2011, 32(12): 2763-2768.
[22]	MONIER M, ABDEL-LATIF D A, ABOU EI-REASH Y G. Ion-imprinted modified chitosan resin for selective removal of Pd(II) ions[J]. Journal of Colloid and Interface Science, 2016, 469: 344-354.
[23]	周尊隆, 卢媛, 孙红文. 菲在不同性质黑炭上的吸附动力学和等温线研究[J]. 农业环境科学学报, 2010, 29(3): 476-480. ZHOU Z L, LU Y, SUN H W. Sorption kinetics and isotherms of phenanthrene in charcoals with different properties[J]. Journal of Agro-Environment Science, 2010, 29(3): 476-480.
[24]	孙小莉, 曾庆轩, 冯长根. 多胺型阴离子交换纤维吸附铬(Ⅵ)的动力学[J]. 物理化学学报, 2009, 25(10): 1951-1957. SUN X L, ZENG Q X, FENG C G. Adsorption kinetics of chromium (Ⅵ) onto an anion exchange fiber containing polyamine[J]. Acta Phys. -Chim. Sin. , 2009, 25(10): 1951-1957.
[25]	KALAVATHY M H, KARTHIKEYAN T, RAJGOPAL S, et al. Kinetic and isotherm studies of Cu(Ⅱ) adsorption onto H3PO4-activated rubber wood sawdust[J]. Journal of Colloid and Interface Science, 2005, 292: 354-362.
[26]	郝汉, 冯建国, 马超, 等. 三种阴离子聚合物分散剂在吡虫啉颗粒表面的吸附热力学和动力学[J]. 化工学报, 2013, 64(10): 3838-3850. HAO H, FENG J G, MA C, et al. Adsorption thermodynamics and kinethcs of three anionic polymeric dispersants onto imidacloprid particle surface[J]. CIESC Journal, 2013, 64(10): 3838-3850.
[27]	GEORGE Z K, DIMITRIOS N B. Characterization of binding properties of silver ion-imprinted polymers with equilibrium and kinetic models[J]. Journal of Molecular Liquids, 2015, 212: 133-141.
[28]	LIU F F, LIU Y, XU Y, et al. Efficient static and dynamic removal of Sr(II) from aqueous solution using chitosan ion-imprinted polymer functionalized with dithiocarbamate[J]. Journal of Environmental Chemical Engineering, 2015, 3(2): 1061-1071.
[29]	郑跃国, 谢继铃, 李燕峰, 等. 脱硫渣吸附剂对Cu2+的吸附动力学和热力学[J]. 硅酸盐学报, 2013, 41(3): 396-401. ZHENG Y G, XIE J L, LI Y F, et al. Adsorption kinetics and thermodynamics of desulfurization slag adsorbent for copper(Ⅱ)[J]. Journal of the Chinese Ceramic Society, 2013, 41(3): 396-401.
[30]	龙宇, 羊依金, 李春涛, 等. 新型污泥吸附材料制备及其对镉、铬吸附行为研究[J]. 四川化工, 2014, 17(1): 4-8. LONG Y, YANG Y J, LI C T, et al. Study on the adsorption behavior of new sludge-based adsorption material for Cd(Ⅱ) and Cr(Ⅲ)[J]. Sichuan Chemical Industry, 2014, 17(1): 4-8.
[31]	张慧敏, 阮弦, 胡勇有, 等. 静电纺壳聚糖/聚乙烯醇纳米纤维膜对Cu2+、Ni2+及Cd2+的吸附特性[J]. 环境科学学报, 2015, 35(1): 184-193. ZHANG H M, RUAN X, HU Y Y, et al. Adsorptive characteristics of Cu2+, Ni2+ and Cd2+ on chitosan/poly (vinyl alcohol) nanofiber[J]. Acta Scientiae Circumstantiae, 2015, 35(1): 184-193.
[32]	田犀卓, 金兰淑, 应博, 等. 钢渣-蒙脱石复合吸附剂对水中Cd2+的吸附去除[J]. 环境科学学报, 2015, 35(1): 207-214. TIAN X Z, JIN L S, YING B, et al. Adsorption of Cd2+ from aqueous solution by steel slag-montmorillonite composite adsorbent[J]. Acta Scientiae Circumstantiae, 2015, 35(1): 207-214.
[33]	刘敬勇, 黄桂虹, 邓俊强, 等. 改性柚子皮吸附剂对模拟废水中Pb2+的吸附性能[J]. 生态与农村环境学报, 2012, 28(2): 187-191. LIU J Y, HUANG G H, DENG J Q, et al. Adsorbent prepared from waste pomelo peel and its adsorption of Pb2+ in wastewater[J]. Journal of Ecology and Rural Environment, 2012, 28(2): 187-191.

黄腐酸基Cd²⁺离子印迹聚合物的吸附性能测试

Absorption properties of Cd²⁺ ion imprinted poly(fulvic acid)

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