顶空气相色谱法研究柠檬醛+α-紫罗兰酮+β-紫罗兰酮体系的汽液平衡

doi:10.11949/0438-1157.20191515

摘要/Abstract

摘要：

采用顶空气相色谱法测定了柠檬醛(1)+ α-紫罗兰酮(2)、柠檬醛(1)+ β-紫罗兰酮(2)和α-紫罗兰酮(1)+ β-紫罗兰酮(2)体系在333.15、368.15和403.15 K温度下的等温汽液相平衡数据；采用Redlich-Kister面积检验法和van Ness点检验法进行热力学一致性检验；采用Aspen plus V10.0软件、Britt-Luecke算法回归NRTL和 UNIQUAC活度系数模型参数；采用NRTL活度系数模型计算体系的超额自由焓(G^E)。结果表明，所测体系的p-T-x-y数据均符合热力学一致性；柠檬醛(1)+ α-紫罗兰酮(2)、柠檬醛(1)+ β-紫罗兰酮(2)和α-紫罗兰酮(1)+ β-紫罗兰酮(2)体系的气相组成(y₁)的计算值与实验值的最大平均绝对偏差(AAD)分别为0.0044、0.0060和0.0032；三组二元体系 G^E的正、负偏差最大值分别为0.4002、0.2315和 –0.7143 kJ·mol^-1。

关键词: 柠檬醛, α-紫罗兰酮, β-紫罗兰酮, 色谱, 汽液平衡, 活度系数

Abstract:

Isothermal vapor-liquid equilibrium (VLE) data for citral (1) +α-ionone (2), citral (1) +β-ionone (2) and α-ionone (1) +β-ionone (2) were measured at 333.15, 368.15 and 403.15 K using headspace gas chromatography method. Redlich-Kister area test method and van Ness point test method were used to check the thermodynamic consistency. Aspen plus V10.0 software and Britt-Luecke algorithm were used to return the NRTL and UNIQUAC activity coefficient model parameters. Furthermore，the excess Gibbs energy (G^E) for all systems were calculated using the NRTL model. The results showed all experimental p-T-x-y data satisfied the requirements of thermodynamic consistency. The maximum absolute average deviation (AAD) of vapor compositions between calculated and experimental data for citral (1) +α-ionone (2), citral (1) +β-ionone (2) and α-ionone (1) +β-ionone (2) systems at the measured temperatures were 0.0044,0.0060 and 0.0032, respectively. The maximum G^E for three systems were 0.4002, 0.2315 and–0.7143 kJ·mol^-1, respectively.

Key words: citral, α-ionone, β-ionone, chromatography, vapor-liquid equilibrium, activity coefficient

中图分类号:

TQ 013.1

郑佩, 王琳琳, 梁杰珍, 陈小鹏, 童张法, 韦小杰, 唐锐. 顶空气相色谱法研究柠檬醛+α-紫罗兰酮+β-紫罗兰酮体系的汽液平衡[J]. 化工学报, 2020, 71(7): 2983-2992.

Pei ZHENG, Linlin WANG, Jiezhen LIANG, Xiaopeng CHEN, Zhangfa TONG, Xiaojie WEI, Rui TANG. Vapor-liquid equilibrium for citral + α-ionone + β-ionone systems using headspace gas chromatography method[J]. CIESC Journal, 2020, 71(7): 2983-2992.

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