微通道内CO2吸收与传质及资源化利用的研究进展

doi:10.11949/0438-1157.20210881

摘要/Abstract

摘要：

由于在流体流动、传质、传热及反应等方面良好的调控能力，微化工技术成为化工学科重要的发展领域。综述了近年来以CO₂应用为背景的微化工系统中的多相流与传质的研究进展。从流体流动和传质机理出发，分别介绍了物理吸收和化学吸收过程的传质规律。总结了二氧化碳资源化利用的应用进展。展望了微化工技术在二氧化碳吸收与传质方面的发展前景。

关键词: 微通道, 质量传递, 二氧化碳, 多相流

Abstract:

Due to the good control ability in fluid flow, mass transfer, heat transfer and reaction, microchemical technology has become an important development area of chemical engineering. The research progress of multiphase flow and mass transfer in microchannel system based on the application of CO₂ is reviewed. Based on the fluid flow and mass transfer mechanism, the kinetic and results of mass transfer in microchannels by physical absorption and chemical absorption are introduced respectively. The application progress of resource utilization of CO₂ is summarized. The development of microchemical engineering technology towards carbon dioxide absorption and mass transfer are prospected.

Key words: microchannel, mass transfer, carbon dioxide, multiphase flow

中图分类号:

TQ 021.1

庞子凡, 蒋斌, 朱春英, 马友光, 付涛涛. 微通道内CO₂吸收与传质及资源化利用的研究进展[J]. 化工学报, 2022, 73(1): 122-133.

Zifan PANG, Bin JIANG, Chunying ZHU, Youguang MA, Taotao FU. Progress of absorption, mass transfer and resource utilization of CO₂ in microchannels[J]. CIESC Journal, 2022, 73(1): 122-133.

图/表 6

参考文献 60

61	Aghel B, Sahraie S, Heidaryan E. Comparison of aqueous and non-aqueous alkanolamines solutions for carbon dioxide desorption in a microreactor[J]. Energy, 2020, 201: 117618.
62	Aghel B, Sahraie S, Heidaryan E. Carbon dioxide desorption from aqueous solutions of monoethanolamine and diethanolamine in a microchannel reactor[J]. Separation and Purification Technology, 2020, 237: 116390.
63	Endrődi B, Bencsik G, Darvas F, et al. Continuous-flow electroreduction of carbon dioxide[J]. Progress in Energy and Combustion Science, 2017, 62: 133-154.
64	Adamo A, Beingessner R L, Behnam M, et al. On-demand continuous-flow production of pharmaceuticals in a compact, reconfigurable system[J]. Science, 2016, 352(6281): 61-67.
65	Nguyen D T, Esser-Kahn A P. A microvascular system for chemical reactions using surface waste heat[J]. Angewandte Chemie International Edition, 2013, 52(51): 13731-13734.
66	Lai W H, Wang Y X, Wang Y, et al. Morphology tuning of inorganic nanomaterials grown by precipitation through control of electrolytic dissociation and supersaturation[J]. Nature Chemistry, 2019, 11(8): 695-701.
67	Li S W, Xu J H, Wang Y J, et al. Liquid-liquid two-phase flow in pore array microstructured devices for scaling-up of nanoparticle preparation[J]. AIChE Journal, 2009, 55(12): 3041-3051.
68	Wu K J, de Varine Bohan G M, Torrente-Murciano L. Synthesis of narrow sized silver nanoparticles in the absence of capping ligands in helical microreactors[J]. Reaction Chemistry & Engineering, 2017, 2(2): 116-128.
69	Duraiswamy S, Khan S A. Droplet-based microfluidic synthesis of anisotropic metal nanocrystals[J]. Small, 2009, 5(24): 2828-2834.
70	Han C L, Hu Y P, Wang K, et al. Preparation and in situ surface modification of CaCO₃ nanoparticles with calcium stearate in a microreaction system[J]. Powder Technology, 2019, 356: 414-422.
71	Lu Y C, Liu Y, Zhou C, et al. Preparation of Li₂CO₃ nanoparticles by carbonation reaction using a microfiltration membrane dispersion microreactor[J]. Industrial & Engineering Chemistry Research, 2014, 53(27): 11015-11020.
72	Wang Y, Zhang X L, Wang A J, et al. Synthesis of ZnO nanoparticles from microemulsions in a flow type microreactor[J]. Chemical Engineering Journal, 2014, 235: 191-197.
73	Chin S F, Iyer K S, Raston C L, et al. Size selective synthesis of superparamagnetic nanoparticles in thin fluids under continuous flow conditions[J]. Advanced Functional Materials, 2008, 18(6): 922-927.
74	Yang H W, Luan W L, Tu S T, et al. High-temperature synthesis of CdSe nanocrystals in a serpentine microchannel: wide size tunability achieved under a short residence time[J]. Crystal Growth & Design, 2009, 9(3): 1569-1574.
1	Das S, Pérez-Ramírez J, Gong J, et al. Core-shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO₂[J]. Chemical Society Reviews, 2020, 49(10): 2937-3004.
2	Hepburn C, Adlen E, Beddington J, et al. The technological and economic prospects for CO₂ utilization and removal[J]. Nature, 2019, 575(7781): 87-97.
75	童张法, 胡超, 李立硕, 等. 间歇鼓泡碳化法制备立方形纳米碳酸钙工艺条件优化[J]. 广西科学, 2015, 22(1): 53-59.
	Tong Z F, Hu C, Li L S, et al. Optimization of processing conditions for the preparation of cubic nano-sized calcium carbonate by intermittent bubbling carbonation[J]. Guangxi Sciences, 2015, 22(1): 53-59.
76	张士成, 韩跃新, 蒋军华, 等. 纳米碳酸钙的合成方法[J]. 矿产保护与利用, 1998(3): 11-15.
	Zhang S C, Han Y X, Jiang J H, et al. Synthesis of nano calcium carbonate[J]. Conservation and Utilization of Mineral Resources, 1998(3): 11-15.
3	Yaashikaa P R, Senthil Kumar P, Varjani S J, et al. A review on photochemical, biochemical and electrochemical transformation of CO₂ into value-added products[J]. Journal of CO₂ Utilization, 2019, 33: 131-147.
4	Chen C, Khosrowabadi Kotyk J F, Sheehan S W. Progress toward commercial application of electrochemical carbon dioxide reduction[J]. Chem, 2018, 4(11): 2571-2586.
5	Abolhasani M, Günther A, Kumacheva E. Microfluidic studies of carbon dioxide[J]. Angewandte Chemie International Edition, 2014, 53(31): 7992-8002.
6	Rochelle G T. Amine scrubbing for CO₂ capture[J]. Science, 2009, 325(5948): 1652-1654.
7	Haszeldine R S. Carbon capture and storage: how green can black be?[J]. Science, 2009, 325(5948): 1647-1652.
8	Liu N, Aymonier C, Lecoutre C, et al. Microfluidic approach for studying CO₂ solubility in water and brine using confocal Raman spectroscopy[J]. Chemical Physics Letters, 2012, 551: 139-143.
9	Al-Rawashdeh M, Yu F, Nijhuis T A, et al. Numbered-up gas-liquid micro/milli channels reactor with modular flow distributor[J]. Chemical Engineering Journal, 2012, 207/208: 645-655.
77	徐旺生, 何秉忠, 金士威, 等. 多级喷雾碳化法制备纳米碳酸钙工艺研究[J]. 无机材料学报, 2001, 16(5): 985-988.
	Xu W S, He B Z, Jin S W, et al. Preparation of nanometer calcium carbonate by multistage spray carbonation[J]. Journal of Inorganic Materials, 2001, 16(5): 985-988.
78	Kang F, Wang D, Pu Y, et al. Efficient preparation of monodisperse CaCO₃ nanoparticles as overbased nanodetergents in a high-gravity rotating packed bed reactor[J]. Powder Technology, 2018, 325: 405-411.
79	Boyjoo Y, Pareek V K, Liu J. Synthesis of micro and nano-sized calcium carbonate particles and their applications[J]. J. Mater. Chem. A, 2014, 2(35): 14270-14288.
80	Wang K, Wang Y J, Chen G G, et al. Enhancement of mixing and mass transfer performance with a microstructure minireactor for controllable preparation of CaCO₃ Nanoparticles[J]. Industrial & Engineering Chemistry Research, 2007, 46(19): 6092-6098.
81	Liang Y, Chu G W, Wang J X, et al. Controllable preparation of nano-CaCO₃ in a microporous tube-in-tube microchannel reactor[J]. Chemical Engineering and Processing: Process Intensification, 2014, 79: 34-39.
82	Rong M Z, Zhang M Q, Ruan W H. Surface modification of nanoscale fillers for improving properties of polymer nanocomposites: a review[J]. Materials Science and Technology, 2006, 22(7): 787-796.
83	Lin Y, Chen H B, Chan C M, et al. High impact toughness polypropylene/CaCO₃ nanocomposites and the toughening mechanism[J]. Macromolecules, 2008, 41(23): 9204-9213.
84	Lam T D, Hoang T V, Quang D T, et al. Effect of nanosized and surface-modified precipitated calcium carbonate on properties of CaCO₃/polypropylene nanocomposites[J]. Materials Science and Engineering: A, 2009, 501(1/2): 87-93.
85	Wang C Y, Sheng Y, Hari-Bala, et al. A novel aqueous-phase route to synthesize hydrophobic CaCO₃ particles in situ[J]. Materials Science and Engineering: C, 2007, 27(1): 42-45.
86	Du L, Wang Y J, Luo G S. In situ preparation of hydrophobic CaCO₃ nanoparticles in a gas-liquid microdispersion process[J]. Particuology, 2013, 11(4): 421-427.
87	Benito-Lopez F, Tiggelaar R M, Salbut K, et al. Substantial rate enhancements of the esterification reaction of phthalic anhydride with methanol at high pressure and using supercritical CO₂ as a co-solvent in a glass microreactor[J]. Lab on a Chip, 2007, 7(10): 1345.
88	Han C L, Hu Y P, Wang K, et al. Synthesis of mesoporous silica microspheres by a spray-assisted carbonation microreaction method[J]. Particuology, 2020, 50: 173-180.
89	Park J I, Jagadeesan D, Williams R, et al. Microbubbles loaded with nanoparticles: a route to multiple imaging modalities[J]. ACS Nano, 2010, 4(11): 6579-6586.
10	Gupta R, Fletcher D F, Haynes B S. Taylor flow in microchannels: a review of experimental and computational work[J]. The Journal of Computational Multiphase Flows, 2010, 2(1): 1-31.
11	Zhao Y C, Yao C Q, Chen G W, et al. Highly efficient synthesis of cyclic carbonate with CO₂catalyzed by ionic liquid in a microreactor[J]. Green Chem, 2013, 15(2): 446-452.
12	Inoue T, Schmidt M A, Jensen K F. Microfabricated multiphase reactors for the direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Industrial & Engineering Chemistry Research, 2007, 46(4): 1153-1160.
13	Fadaei H, Scarff B, Sinton D. Rapid microfluidics-based measurement of CO₂ diffusivity in bitumen[J]. Energy & Fuels, 2011, 25(10): 4829-4835.
14	Lefortier S G R, Hamersma P J, Bardow A, et al. Rapid microfluidic screening of CO₂ solubility and diffusion in pure and mixed solvents[J]. Lab on a Chip, 2012, 12(18): 3387.
15	Sell A, Fadaei H, Kim M, et al. Measurement of CO₂ diffusivity for carbon sequestration: a microfluidic approach for reservoir-specific analysis[J]. Environmental Science & Technology, 2013, 47(1): 71-78.
16	Abolhasani M, Abolhasani M, Singh M, et al. Automated microfluidic platform for studies of carbon dioxide dissolution and solubility in physical solvents[J]. Lab on a Chip, 2012, 12(9): 1611-1618.
17	Li W, Liu K, Simms R, et al. Microfluidic study of fast gas-liquid reactions[J]. Journal of the American Chemical Society, 2012, 134(6): 3127-3132.
18	尧超群, 陈光文, 袁权. 微通道内气-液两相传质过程行为及其应用[J]. 化工学报, 2019, 70(10): 3635-3644.
	Yao C Q, Chen G W, Yuan Q. Mass transfer characteristics of gas-liquid two-phase flow in microchannels and applications[J]. CIESC Journal, 2019, 70(10): 3635-3644.
19	Kashid M N, Renken A, Kiwi-Minsker L. Gas-liquid and liquid-liquid mass transfer in microstructured reactors[J]. Chemical Engineering Science, 2011, 66(17): 3876-3897.
20	Tumarkin E, Nie Z H, Park J I, et al. Temperature-controlled ‘breathing’ of carbon dioxide bubbles[J]. Lab on a Chip, 2011, 11(20): 3545.
21	Bousquet P. Regional changes in carbon dioxide fluxes of land and oceans since 1980[J]. Science, 2000, 290(5495): 1342-1346.
22	Dong R, Chu D, Sun Q Q, et al. Numerical simulation of the mass transfer process of CO₂ absorption by different solutions in a microchannel[J]. The Canadian Journal of Chemical Engineering, 2020, 98(12): 2648-2664.
23	Yang L X, Dietrich N, Loubière K, et al. Visualization and characterization of gas-liquid mass transfer around a Taylor bubble right after the formation stage in microreactors[J]. Chemical Engineering Science, 2016, 143: 364-368.
24	Yang L X, Loubière K, Dietrich N, et al. Local investigations on the gas-liquid mass transfer around Taylor bubbles flowing in a meandering millimetric square channel[J]. Chemical Engineering Science, 2017, 165: 192-203.
25	van Baten J M, Krishna R. CFD simulations of mass transfer from Taylor bubbles rising in circular capillaries[J]. Chemical Engineering Science, 2004, 59(12): 2535-2545.
26	Svetlov S D, Abiev R S. Modeling mass transfer in a Taylor flow regime through microchannels using a three-layer model[J]. Theoretical Foundations of Chemical Engineering, 2016, 50(6): 975-989.
27	Zhu C Y, Li C F, Gao X Q, et al. Taylor flow and mass transfer of CO₂ chemical absorption into MEA aqueous solutions in a T-junction microchannel[J]. International Journal of Heat and Mass Transfer, 2014, 73: 492-499.
28	Yao C Q, Dong Z Y, Zhao Y C, et al. An online method to measure mass transfer of slug flow in a microchannel[J]. Chemical Engineering Science, 2014, 112: 15-24.
29	Zhang P, Yao C Q, Ma H Y, et al. Dynamic changes in gas-liquid mass transfer during Taylor flow in long serpentine square microchannels[J]. Chemical Engineering Science, 2018, 182: 17-27.
30	Chu C Y, Zhang F B, Zhu C Y, et al. Mass transfer characteristics of CO₂ absorption into 1-butyl-3-methylimidazolium tetrafluoroborate aqueous solution in microchannel[J]. International Journal of Heat and Mass Transfer, 2019, 128: 1064-1071.
31	Yang L, Tan J, Wang K, et al. Mass transfer characteristics of bubbly flow in microchannels[J]. Chemical Engineering Science, 2014, 109: 306-314.
32	Sun R, Cubaud T. Dissolution of carbon dioxide bubbles and microfluidic multiphase flows[J]. Lab on a Chip, 2011, 11(17): 2924-2928.
33	Sui J S, Yan J Y, Liu D, et al. Continuous synthesis of nanocrystals via flow chemistry technology[J]. Small, 2020, 16(15): 1902828.
34	Matsuoka A, Mae K. Design strategy of a microchannel device for liquid-liquid extraction based on the relationship between mass transfer rate and two-phase flow pattern[J]. Chemical Engineering and Processing - Process Intensification, 2021, 160: 108297.
35	Chen T Y, Desir P, Bracconi M, et al. Liquid–liquid microfluidic flows for ultrafast 5-hydroxymethyl furfural extraction[J]. Industrial & Engineering Chemistry Research, 2021, 60(9): 3723-3735.
36	Cubaud T, Sauzade M, Sun R P. CO₂ dissolution in water using long serpentine microchannels[J]. Biomicrofluidics, 2012, 6(2): 022002.
37	Yue J, Luo L G, Gonthier Y, et al. An experimental study of air-water Taylor flow and mass transfer inside square microchannels[J]. Chemical Engineering Science, 2009, 64(16): 3697-3708.
38	Cubaud T, Tatineni M, Zhong X L, et al. Bubble dispenser in microfluidic devices[J]. Physical Review E, 2005, 72(3): 037302.
39	Nirmal G M, Leary T F, Ramachandran A. Mass transfer dynamics in the dissolution of Taylor bubbles[J]. Soft Matter, 2019, 15(13): 2746-2756.
40	Ho T H M, Sameoto D, Tsai P A. Multiphase CO₂ dispersions in microfluidics: formation, phases, and mass transfer[J]. Chemical Engineering Research and Design, 2021, 174: 116-126.
41	Marre S, Aymonier C, Subra P, et al. Dripping to jetting transitions observed from supercritical fluid in liquid microcoflows[J]. Applied Physics Letters, 2009, 95(13): 134105.
42	Burk M J, Feng S G, Gross M F, et al. Asymmetric catalytic hydrogenation reactions in supercritical carbon dioxide[J]. Journal of the American Chemical Society, 1995, 117(31): 8277-8278.
43	Sauzade M, Cubaud T. Initial microfluidic dissolution regime of CO₂ bubbles in viscous oils[J]. Physical Review E, 2013, 88(5): 051001.
44	Pang Z F, Zhu C Y, Ma Y G, et al. CO₂ absorption by liquid films under Taylor flow in serpentine minichannels[J]. Industrial & Engineering Chemistry Research, 2020, 59(26): 12250-12261.
45	Muradoglu M. Axial dispersion in segmented gas-liquid flow: effects of alternating channel curvature[J]. Physics of Fluids, 2010, 22(12): 122106.
46	Fries D M, von Rohr P R. Liquid mixing in gas-liquid two-phase flow by meandering microchannels[J]. Chemical Engineering Science, 2009, 64(6): 1326-1335.
47	Olah G A. Beyond oil and gas: the methanol economy[J]. Angewandte Chemie International Edition, 2005, 44(18): 2636-2639.
48	Olah G A, Goeppert A, Prakash G K S. Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons[J]. The Journal of Organic Chemistry, 2009, 74(2): 487-498.
49	Yue J, Chen G W, Yuan Q, et al. Hydrodynamics and mass transfer characteristics in gas-liquid flow through a rectangular microchannel[J]. Chemical Engineering Science, 2007, 62(7): 2096-2108.
50	Pang Z F, Jiang S K, Zhu C Y, et al. Mass transfer of chemical absorption of CO₂ in a serpentine minichannel[J]. Chemical Engineering Journal, 2021, 414: 128791.
51	Durgadevi A, Pushpavanam S. An experimental and theoretical investigation of pure carbon dioxide absorption in aqueous sodium hydroxide in glass millichannels[J]. Journal of CO₂ Utilization, 2018, 26: 133-142.
52	Zhou Y F, Yao C Q, Zhang P, et al. Dynamic coupling of mass transfer and chemical reaction for Taylor flow along a serpentine microchannel[J]. Industrial & Engineering Chemistry Research, 2020, 59(19): 9279-9292.
53	Tan J, Lu Y C, Xu J H, et al. Mass transfer performance of gas-liquid segmented flow in microchannels[J]. Chemical Engineering Journal, 2012, 181/182: 229-235.
54	Zhu C Y, Lu Y T, Fu T T, et al. Experimental investigation on gas-liquid mass transfer with fast chemical reaction in microchannel[J]. International Journal of Heat and Mass Transfer, 2017, 114: 83-89.
55	Sobieszuk P, Pohorecki R, Cygański P, et al. Determination of the interfacial area and mass transfer coefficients in the Taylor gas-liquid flow in a microchannel[J]. Chemical Engineering Science, 2011, 66(23): 6048-6056.
56	Yin Y R, Fu T T, Zhu C Y, et al. Dynamics and mass transfer characteristics of CO₂ absorption into MEA/[Bmim][BF₄] aqueous solutions in a microchannel[J]. Separation and Purification Technology, 2019, 210: 541-552.
57	Aghel B, Heidaryan E, Sahraie S, et al. Optimization of monoethanolamine for CO₂ absorption in a microchannel reactor[J]. Journal of CO₂ Utilization, 2018, 28: 264-273.
58	Aghel B, Sahraie S, Heidaryan E, et al. Experimental study of carbon dioxide absorption by mixed aqueous solutions of methyl diethanolamine (MDEA) and piperazine (PZ) in a microreactor[J]. Process Safety and Environmental Protection, 2019, 131: 152-159.
59	Dietrich N, Loubière K, Jimenez M, et al. A new direct technique for visualizing and measuring gas-liquid mass transfer around bubbles moving in a straight millimetric square channel[J]. Chemical Engineering Science, 2013, 100: 172-182.
60	Kováts P, Pohl D, Thévenin D, et al. Optical determination of oxygen mass transfer in a helically-coiled pipe compared to a straight horizontal tube[J]. Chemical Engineering Science, 2018, 190: 273-285.

[1]	宋瑞涛, 王派, 王云鹏, 李敏霞, 党超镔, 陈振国, 童欢, 周佳琦. 二氧化碳直接蒸发冰场排管内流动沸腾换热数值模拟分析[J]. 化工学报, 2023, 74(S1): 96-103.
[2]	张义飞, 刘舫辰, 张双星, 杜文静. 超临界二氧化碳用印刷电路板式换热器性能分析[J]. 化工学报, 2023, 74(S1): 183-190.
[3]	江河, 袁俊飞, 王林, 邢谷雨. 均流腔结构对微细通道内相变流动特性影响的实验研究[J]. 化工学报, 2023, 74(S1): 235-244.
[4]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[5]	刘文竹, 云和明, 王宝雪, 胡明哲, 仲崇龙. 基于场协同和耗散的微通道拓扑优化研究[J]. 化工学报, 2023, 74(8): 3329-3341.
[6]	杨菲菲, 赵世熙, 周维, 倪中海. Sn掺杂的In₂O₃催化CO₂选择性加氢制甲醇[J]. 化工学报, 2023, 74(8): 3366-3374.
[7]	洪瑞, 袁宝强, 杜文静. 垂直上升管内超临界二氧化碳传热恶化机理分析[J]. 化工学报, 2023, 74(8): 3309-3319.
[8]	杨越, 张丹, 郑巨淦, 涂茂萍, 杨庆忠. NaCl水溶液喷射闪蒸-掺混蒸发的实验研究[J]. 化工学报, 2023, 74(8): 3279-3291.
[9]	张琦钰, 高利军, 苏宇航, 马晓博, 王翊丞, 张亚婷, 胡超. 碳基催化材料在电化学还原二氧化碳中的研究进展[J]. 化工学报, 2023, 74(7): 2753-2772.
[10]	董明, 徐进良, 刘广林. 超临界水非均质特性分子动力学研究[J]. 化工学报, 2023, 74(7): 2836-2847.
[11]	郑志航, 马郡男, 闫子涵, 卢春喜. 提升管射流影响区内压力脉动特性研究[J]. 化工学报, 2023, 74(6): 2335-2350.
[12]	毛磊, 刘冠章, 袁航, 张光亚. 可捕集CO₂的纳米碳酸酐酶粒子的高效制备及性能研究[J]. 化工学报, 2023, 74(6): 2589-2598.
[13]	蔺彩虹, 王丽, 吴瑜, 刘鹏, 杨江峰, 李晋平. 沸石中碱金属阳离子对CO₂/N₂O吸附分离性能的影响[J]. 化工学报, 2023, 74(5): 2013-2021.
[14]	李晨曦, 刘永峰, 张璐, 刘海峰, 宋金瓯, 何旭. O₂/CO₂氛围下正庚烷的燃烧机理研究[J]. 化工学报, 2023, 74(5): 2157-2169.
[15]	王皓, 唐思扬, 钟山, 梁斌. MEA吸收CO₂富液解吸过程中固体颗粒表面的强化作用分析[J]. 化工学报, 2023, 74(4): 1539-1548.

微通道内CO₂吸收与传质及资源化利用的研究进展

Progress of absorption, mass transfer and resource utilization of CO₂ in microchannels

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 60

相关文章 15

编辑推荐

Metrics

本文评价