化工学报 ›› 2023, Vol. 74 ›› Issue (3): 1370-1378.DOI: 10.11949/0438-1157.20221588
刘海芹(), 李博文, 凌喆, 刘亮, 俞娟(
), 范一民, 勇强
收稿日期:
2022-12-09
修回日期:
2023-02-21
出版日期:
2023-03-05
发布日期:
2023-04-19
通讯作者:
俞娟
作者简介:
刘海芹(1999—),女,硕士研究生,liuhaiqin@njfu.edu.cn
基金资助:
Haiqin LIU(), Bowen LI, Zhe LING, Liang LIU, Juan YU(
), Yimin FAN, Qiang YONG
Received:
2022-12-09
Revised:
2023-02-21
Online:
2023-03-05
Published:
2023-04-19
Contact:
Juan YU
摘要:
以植物源半乳甘露聚糖(GM)为原料,1-苯基-2-丙炔-1-酮(PPK)为醚化试剂,通过绿色高效的羟基-炔点击化学改性技术,成功地在室温条件下制备得到兼具优异力学性能、疏水性能和紫外屏蔽性能的半乳甘露聚糖苯丙基烯酮醚(GMPPK)薄膜。结果表明:羟基-炔点击化学可以实现GM表面羟基的高效醚化。与未改性的GM薄膜相比,由于PPK分子的引入,GMPPK薄膜表现新的紫外屏蔽性(GMPPK2在275 nm处的屏蔽率高达98.86%)、疏水性(水接触角从74.9°增加至96.5°)和耐水溶胀性。此外,随—OH∶PPK的反应摩尔比增加,GMPPK2薄膜的力学性能进一步增加,其拉伸应力为44.7 MPa,韧性为1.7 MJ/m3,杨氏模量为25.3 MPa,分别是未改性GM薄膜的2.2倍、1.9倍和2.4倍。研究结果可为开发高性能半乳甘露聚糖包装薄膜材料的应用研究奠定理论基础。
中图分类号:
刘海芹, 李博文, 凌喆, 刘亮, 俞娟, 范一民, 勇强. 羟基-炔点击化学改性半乳甘露聚糖薄膜的制备及性能研究[J]. 化工学报, 2023, 74(3): 1370-1378.
Haiqin LIU, Bowen LI, Zhe LING, Liang LIU, Juan YU, Yimin FAN, Qiang YONG. Facile preparation and properties of chemically modified galactomannan films via mild hydroxy-alkyne click reaction[J]. CIESC Journal, 2023, 74(3): 1370-1378.
图2 GM和不同接枝比例GMPPK的紫外吸收光谱图(a)、红外光谱图(b)与固体13C NMR谱图(c)
Fig.2 UV absorption spectra (a),FT-IR (b) and solid 13C NMR spectra (c) of GM and GMPPK with different grafting ratios
Samples | Element content and bond types/% | |||||
---|---|---|---|---|---|---|
C | O | —C | C—O—C | C—OH | C—H/C—C | |
GM | 68.57 | 31.43 | — | 12.73 | 47.30 | 39.97 |
GMPPK1 | 71.05 | 28.95 | 5.96 | 12.79 | 39.37 | 41.47 |
GMPPK2 | 72.53 | 27.47 | 4.25 | 13.49 | 38.93 | 42.95 |
GMPPK3 | 72.55 | 27.45 | 4.98 | 13.11 | 38.52 | 43.01 |
表1 由 XPS 确定的GM和不同比例GMPPK薄膜的表面元素组成
Table 1 Elemental surface composition of GM films and GMPPK films with different grafting ratios determined from XPS
Samples | Element content and bond types/% | |||||
---|---|---|---|---|---|---|
C | O | —C | C—O—C | C—OH | C—H/C—C | |
GM | 68.57 | 31.43 | — | 12.73 | 47.30 | 39.97 |
GMPPK1 | 71.05 | 28.95 | 5.96 | 12.79 | 39.37 | 41.47 |
GMPPK2 | 72.53 | 27.47 | 4.25 | 13.49 | 38.93 | 42.95 |
GMPPK3 | 72.55 | 27.45 | 4.98 | 13.11 | 38.52 | 43.01 |
图5 GM和不同接枝比例GMPPK薄膜的水接触角(a)和耐水性照片(b)
Fig.5 Water contact angle (a) and water resistance photos (b) of GM films and GMPPK films with different grafting ratios
图6 GM和不同接枝比例GMPPK薄膜的水蒸气透过率(a)、氧气透过率(b)和抗氧化性(c)
Fig.6 Water vapor transmission rate (a), oxygen transmission rate (b) and oxidation resistance (c) of GM films and GMPPK films with different grafting ratios
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