关键词:

甲醇合成, 模拟, 优化, 失活, 拟均相模型

Abstract:

Two optimization strategies for methanol synthesis were proposed to deal with the decreasing activity of the catalysts and were compared by simulation using a plug-flow model.In both strategies the methanol productivity remained constant in the early months by minimizing the operating pressure and was maximized for the remaining months.In the first strategy, the coolant temperature and space velocity were adjusted simultaneously with time on stream to the optimal values.In the second strategy, space velocity was kept constant all the time, while operating pressure was increased until it reached the upper bound and then coolant temperature was optimized.The results showed that the second strategy yielded a slightly smaller methanol productivity.However, since pressure and coolant temperature were adjusted independently, this simpler strategy was more acceptable by the industry.

Key words:

甲醇合成, 模拟, 优化, 失活, 拟均相模型