柴油烃类族组成分离技术研究进展

doi:10.11949/0438-1157.20230773

摘要/Abstract

摘要：

随着我国炼油技术的不断提高与新能源的开发利用，燃料市场趋向饱和，柴油出现明显过剩。将柴油通过分离手段转油为化，实现族组分中芳烃/非芳烃的高效低碳分离，是实现柴油高值化利用、缓解过剩问题的重要途径。首先阐述了我国柴油族组成的分布规律，提出针对直馏柴油与催化裂化柴油（FCC柴油）进行分离时切入点的差异；详细介绍了柴油中芳烃与链烷烃的分离技术，如溶剂萃取、膜分离、吸附分离、尿素络合等，并分析讨论了各种分离技术的优劣势以及未来研究方向；最后对柴油中芳烃与链烷烃的分离进行了总结与展望。

关键词: 柴油, 分离, 溶剂萃取, 膜, 吸附, 脱蜡

Abstract:

With the continuous improvement of China’s refining technology and the development and utilization of new energy sources, the fuel market is gradually saturated, and there is an obvious surplus of diesel. Converting diesel into oil through separation to achieve efficient and low-carbon separation of aromatic hydrocarbons/non-aromatic hydrocarbons in the components is an important way to achieve high-value utilization of diesel and alleviate the problem of excess. This article first explains the distribution pattern of diesel family composition in China, and proposes the differences in entry points for the separation of straight-run diesel and catalytically cracked diesel (FCC diesel). The separation technology of aromatics and paraffins in diesel is introduced in detail, such as solvent extraction, membrane separation, adsorption separation and urea dewaxing etc. The advantages and disadvantages of various separation techniques and their future research directions are discussed. Finally, the separation of aromatics and paraffins in diesel oil is summarized and prospected.

Key words: diesel, separation, solvent extraction, membranes, adsorption, dewaxing

中图分类号:

TQ 028

王尤佳, 赵亮, 高金森, 徐春明. 柴油烃类族组成分离技术研究进展[J]. 化工学报, 2024, 75(1): 20-32.

Youjia WANG, Liang ZHAO, Jinsen GAO, Chunming XU. Research progress on separation technology of diesel hydrocarbon components[J]. CIESC Journal, 2024, 75(1): 20-32.

图/表 6

参考文献 95

1	瞿国华. 我国清洁柴油生产的热点和难点[J]. 石油化工技术与经济, 2019, 35(3): 1-6.
	Qu G H. Hot spots and difficulties in the production of clean diesel in China[J]. Technology & Economics in Petrochemicals, 2019, 35(3): 1-6.
2	郭春垒, 范景新, 臧甲忠, 等. 柴油高值化综合利用技术发展现状及分析[J]. 化工进展, 2018, 37(11): 4205-4213.
	Guo C L, Fan J X, Zang J Z, et al. Development of high-value utilization technologies of diesel[J]. Chemical Industry and Engineering Progress, 2018, 37(11): 4205-4213.
3	Choi Y, Lee J, Shin J, et al. Selective hydroconversion of naphthalenes into light alkyl-aromatic hydrocarbons[J]. Applied Catalysis A: General, 2015, 492: 140-150.
4	熊磊, 朱宏武, 张金亚, 等. 海底分离技术的最新进展[J]. 石油机械, 2010, 38(10): 75-78.
	Xiong L, Zhu H W, Zhang J Y, et al. Recent advances in seabed separation technology[J]. China Petroleum Machinery, 2010, 38(10): 75-78.
5	王华, 刘艳飞, 彭东明, 等. 膜分离技术的研究进展及应用展望[J]. 应用化工, 2013, 42(3): 532-534.
	Wang H, Liu Y F, Peng D M, et al. The development of membrane separation technology and its application prospect[J]. Applied Chemical Industry, 2013, 42(3): 532-534.
6	张一舸, 曹祖宾, 杨帆, 等. 世界油砂分离技术进展[J]. 天然气工业, 2008, 28(12): 110-113, 149.
	Zhang Y G, Cao Z B, Yang F, et al. World development status of oil-sand separation technologies[J]. Natural Gas Industry, 2008, 28(12): 110-113, 149.
7	Sholl D S, Lively R P. Seven chemical separations to change the world[J]. Nature, 2016, 532: 435-437.
8	任连岭, 徐鹏, 葛锐. 烃族组成对柴油储存安定性影响研究[J]. 西南石油大学学报(自然科学版), 2018, 40(2): 176-182.
	Ren L L, Xu P, Ge R. Effects of hydrocarbon composition on the stability of diesel storage[J]. Journal of Southwest Petroleum University (Science & Technology Edition), 2018, 40(2): 176-182.
9	侯亚洲, 魏晓丽, 毛安国. 直馏柴油催化裂化生产轻质芳烃的研究[J]. 石油炼制与化工, 2017, 48(10): 35-40.
	Hou Y Z, Wei X L, Mao A G. Study on straight-run diesel fraction to light aromatics[J]. Petroleum Processing and Petrochemicals, 2017, 48(10): 35-40.
10	王佳. 柴油烃类组成分子水平预测研究[D]. 北京: 石油化工科学研究院, 2015.
	Wang J. Study on predicting composition of diesel oil hydrocarbon in molecular level[D]. Beijing: Research Institute of Petroleum Processing, 2015.
11	徐先荣, 毛安国. 催化裂化柴油轻重馏分的裂化性能研究[J]. 炼油技术与工程, 2007, 37(6): 1-5.
	Xu X R, Mao A G. Study on the catalytic cracking performance of FCC LCO[J]. Petroleum Refinery Engineering, 2007, 37(6): 1-5.
12	李梦瑶. FCC柴油加氢精制过程中组成结构变化规律研究[D]. 东营: 中国石油大学(华东), 2016.
	Li M Y. Study on composition and structures of the FCC diesel in hydrotreating process[D]. Dongying: China University of Petroleum, 2016.
13	张锐, 鞠雪艳, 李云, 等. 催化裂化柴油加氢处理生产高密度喷气燃料的研究[J]. 石油炼制与化工, 2022, 53(1): 46-52.
	Zhang R, Ju X Y, Li Y, et al. Development of the LCO hydrotreating technology to produce high-density jet fuel[J]. Petroleum Processing and Petrochemicals, 2022, 53(1): 46-52.
14	米多. 芳烃抽提技术进展[J]. 化学工业, 2009, 27(8): 34-37, 45.
	Mi D. Recent progress of extraction technologies for aromatics[J]. Chemical Industry, 2009, 27(8): 34-37, 45.
15	施志国, 张翠金. 芳烃抽提技术研究进展[J]. 化肥设计, 2018, 56(2): 4-8.
	Shi Z G, Zhang C J. Research progress of aromatic extraction[J]. Chemical Fertilizer Design, 2018, 56(2): 4-8.
16	齐江, 延玉臻, 李林, 等. 溶剂萃取法提高催化裂化柴油十六烷值的研究[J]. 石油炼制与化工, 1997, 28(11): 7-9.
	Qi J, Yan Y Z, Li L, et al. Improving LCO cetane number by solvent extraction[J]. Petroleum Processing and Petrochemicals, 1997, 28(11): 7-9.
17	谢琼玉, 徐斌. 催化裂化柴油溶剂抽提降芳烃工艺技术研究[J]. 石油炼制与化工, 2012, 43(4):10-14.
	Xie Q Y, Xu B. Research on the solvent extraction of aromatic hydrocarbon from FCC diesel fractions[J]. Petroleum Processing and Petrochemicals, 2012, 43(4):10-14.
18	Li H, Guo J, Zhang Y, et al. Influence of solvent structure on the extraction of aromatics from FCC diesel and computational thermodynamics study[J]. Fuel Processing Technology, 2021, 224: 107021.
19	Li H, Guo J J, Zhang Y H, et al. Research on separation of aromatics from FCC diesel using organic solvent: a combination of experiments and quantum chemical calculations[J]. Fuel, 2022, 308: 121982.
20	熊良铨, 吕贞, 刘亚娟, 等. 溶剂萃取脱除橡胶油中多环芳烃试验探讨[J]. 润滑油, 2011, 26(1): 56-60.
	Xiong L Q, Lv Z, Liu Y J, et al. Study on the removal of polycyclic aromatic hydrocarbon from rubber oil with solvent extraction[J]. Lubricating Oil, 2011, 26(1): 56-60.
21	唐晓东, 杨谨, 仝保田, 等. 催化裂化柴油萃取脱芳烃技术研究[J]. 石油炼制与化工, 2020, 51(8): 12-18.
	Tang X D, Yang J, Tong B T, et al. Study on aromatics removal from FCC diesel by extraction[J]. Petroleum Processing and Petrochemicals, 2020, 51(8): 12-18.
22	栗红. FCC柴油芳烃组分萃取分离过程基础研究[D]. 北京: 中国石油大学(北京), 2022.
	Li H. Fundamental research on the FCC diesel extraction process for aromatics separation[D]. Beijing: China University of Petroleum, 2022.
23	边超. 催化裂化柴油抽提芳烃工艺研究[D]. 天津: 河北工业大学, 2016.
	Bian C. The study on aromatics extraction process of FCC diesel oil[D]. Tianjin: Hebei University of Technology, 2016.
24	Holbrey J D, Reichert W M, Nieuwenhuyzen M, et al. Liquid clathrate formation in ionic liquid-aromatic mixtures[J]. Chemical Communications, 2003(4): 476-477.
25	Meindersma G W, Hansmeier A R, de Haan A B. Ionic liquids for aromatics extraction. Present status and future outlook[J]. Industrial & Engineering Chemistry Research, 2010, 49(16): 7530-7540
26	Meindersma G W, de Haan A B. Cyano-containing ionic liquids for the extraction of aromatic hydrocarbons from an aromatic/aliphatic mixture[J]. Science China Chemistry, 2012, 55(8): 1488-1499.
27	Larriba M, Navarro P, García J, et al. Liquid-liquid extraction of toluene from heptane using [emim][DCA], [bmim][DCA], and [emim][TCM] ionic liquids[J]. Industrial & Engineering Chemistry Research, 2013, 52(7): 2714-2720.
28	Manohar C V, Banerjee T, Mohanty K. Co-solvent effects for aromatic extraction with ionic liquids[J]. Journal of Molecular Liquids, 2013, 180: 145-153.
29	Li G X, Gao Q H, Liu Q H, et al. Extraction of polycyclic aromatic hydrocarbons from fluid catalytic cracking diesel with ionic liquids[J]. AIChE Journal, 2023, 69(2): e17914.
30	高腾飞, 李国选, 雷志刚. 从催化裂化柴油中分离联苯的溶剂筛选: 实验和计算热力学[J]. 化工学报, 2022, 73(12): 5314-5323.
	Gao T F, Li G X, Lei Z G. Solvents selection for separation of bicyclic aromatics from FCC diesel: experimental and computational thermodynamics[J]. CIESC Journal, 2022, 73(12): 5314-5323.
31	Liu Q H, Li G X, Gui C M, et al. Solvents evaluation for extraction of polycyclic aromatics from FCC diesel: experimental and computational thermodynamics[J]. Chemical Engineering Science, 2022, 264: 118205.
32	张宇豪, 王永涛, 陈丰, 等. 清洁油品生产中溶剂萃取分离技术的研究进展[J]. 中国科学: 化学, 2018, 48(4): 319-328.
	Zhang Y H, Wang Y T, Chen F, et al. Development of solvent extraction separation process for clean oil production[J]. Scientia Sinica (Chimica), 2018, 48(4): 319-328.
33	杨启炜, 鲍宗必, 邢华斌, 等. 离子液体萃取分离结构相似化合物研究进展[J]. 化工进展, 2019, 38(1): 91-99.
	Yang Q W, Bao Z B, Xing H B, et al. Research progress on the extractive separation of structurally-related compounds by ionic liquids[J]. Chemical Industry and Engineering Progress, 2019, 38(1): 91-99.
34	秦建国, 李树白, 姚培, 等. 咪唑类离子液体脱除油品中芳烃和有机硫的研究进展[J]. 上海化工, 2021, 46(6): 59-63.
	Qin J G, Li S B, Yao P, et al. Progress in the removal of aromatics and organic sulfur from petroleum products by imidazole ionic liquids[J]. Shanghai Chemical Industry, 2021, 46(6): 59-63.
35	凌长见. 模拟柴油组分在聚合物膜中扩散行为的分子模拟与实验研究[D]. 上海: 华东理工大学, 2013.
	Ling C J. Diffusion behavior of model diesel components in polymer membranes by molecular dynamic simulation and experimental study[D]. Shanghai: East China University of Science and Technology, 2013.
36	罗世龙, 张中, 韩坤坤, 等. 膜分离技术在食品工业中的应用研究进展[J]. 安徽农业科学, 2021, 49(6): 43-45.
	Luo S L, Zhang Z, Han K K, et al. Research progress on application of membrane separation technology in food industry[J]. Journal of Anhui Agricultural Sciences, 2021, 49(6): 43-45.
37	赵丽红, 郭佳艺. 膜分离技术在再生水中的应用及膜污染研究进展[J]. 科学技术与工程, 2021, 21(19): 7874-7883.
	Zhao L H, Guo J Y. The application of membrane separation technology in reclaimed water and the progress of membrane fouling research[J]. Science Technology and Engineering, 2021, 21(19): 7874-7883.
38	王晓丽, 王生辉, 黄鹏飞, 等. 膜分离技术在生态修复工程中的应用[J]. 盐科学与化工, 2021, 50(4): 4-6, 13.
	Wang X L, Wang S H, Huang P F, et al. Application of membrane separation technology to solve the ecological restoration[J]. Journal of Salt Science and Chemical Industry, 2021, 50(4): 4-6, 13.
39	杨立明, 徐利文, 郭勇. 渗透汽化分离芳烃/烷烃混合体系的研究进展[J]. 化学进展, 2001, 13(4): 303-309.
	Yang L M, Xu L W, Guo Y. Advances in pervaporation membranes for separating mixtures of aromatic and aliphatic hydrocarbons[J]. Progress in Chemistry, 2001, 13(4): 303-309.
40	方志平, 姜忠义. 苯-环己烷分离渗透蒸发膜的研究进展与展望[J]. 石油化工, 2005, 34(9): 885-890.
	Fang Z P, Jiang Z Y. Progress and prospect in pervaporation membrane for separation of benzene and cyclohexane[J]. Petrochemical Technology, 2005, 34(9): 885-890.
41	徐利文, 杨立明, 王玉玲, 等. 含砜基聚酰亚胺膜渗透汽化分离苯/环己烷混合物的研究[J]. 高分子材料科学与工程, 2003, 19(2): 184-187.
	Xu L W, Yang L M, Wang Y L, et al. The pervaporation properties of sulfonyl-containing polyimide membranes to benzene/cyclohexane mixtures[J]. Polymer Materials Science & Engineering, 2003, 19(2): 184-187.
42	Roizard D, Nilly A, Lochon P. Preparation and study of crosslinked polyurethane films to fractionate toluene-n-heptane mixtures by pervaporation[J]. Separation and Purification Technology, 2001, 22(23): 45-52.
43	Roychowdhury S, Mitra D. Separation of phenanthrene/n-tetradecane mixtures (model diesel) via pervaporation using an aromatic polyimide membrane[J]. Polymer Engineering & Science, 2017, 57(4): 392-402.
44	Roychowdhury S, Mitra D. Fabrication of aromatic polyimide membrane to study the pervaporative separation of phenanthrene/n-tetradecane mixtures (model diesel) and process optimization using response surface methodology[J]. Chemical Engineering Communications, 2017, 204(1): 64-78.
45	Roychowdhury S, Mitra D. Separation of polyaromatic hydrocarbons from model diesel composition via pervaporation using a fabricated aromatic polyimide membrane and process optimization[J]. Environmental Progress & Sustainable Energy, 2018, 37(6): 1982-1992.
46	王连英, 杨国明, 辛靖, 等. 吸附工艺脱除柴油中芳烃的研究进展[J]. 石化技术与应用, 2021, 39(1): 66-69.
	Wang L Y, Yang G M, Xin J, et al. Research progress on removal of diesel aromatics by adsorption process[J]. Petrochemical Technology & Application, 2021, 39(1): 66-69.
47	刘剑. 柴油脱芳烃技术研究进展[J]. 精细石油化工进展, 2018, 19(6): 38-41.
	Liu J. Research progress on dearomatization of diesel oil[J]. Advances in Fine Petrochemicals, 2018, 19(6): 38-41.
48	赵闯, 范景新, 郭春垒, 等. 柴油芳烃吸附剂的失活研究[J]. 无机盐工业, 2020, 52(8): 98-102.
	Zhao C, Fan J X, Guo C L, et al. Study on deactivation of diesel aromatic adsorbent[J]. Inorganic Chemicals Industry, 2020, 52(8): 98-102.
49	刘凡, 温舒晴, 王昌, 等. 活性炭固定床吸附分离溶液中表面活性剂和多环芳烃[J]. 化工环保, 2017, 37(6): 693-698.
	Liu F, Wen S Q, Wang C, et al. Adsorption and separation of surfactants and polycyclic aromatic hydrocarbons from solution in activated carbon fixed bed[J]. Environmental Protection of Chemical Industry, 2017, 37(6): 693-698.
50	Bu J, Loh G, Gwie C G, et al. Desulfurization of diesel fuels by selective adsorption on activated carbons: competitive adsorption of polycyclic aromatic sulfur heterocycles and polycyclic aromatic hydrocarbons[J]. Chemical Engineering Journal, 2011, 166(1): 207-217.
51	于廷云, 梁红玉, 徐勇, 等. 吸附法精制催化裂化柴油[J]. 抚顺石油学院学报, 2001, 21(4): 44-46.
	Yu T Y, Liang H Y, Xu Y, et al. Study on absorption refining of FCC diesel oil[J]. Journal of Fushun Petroleum Institute, 2001, 21(4): 44-46.
52	韩龙年, 陈新国, 辛靖, 等. 催化柴油增值化、高值化利用工业应用技术发展现状及分析[J]. 石油与天然气化工, 2022, 51(6): 34-40.
	Han L N, Chen X G, Xin J, et al. Development status and analysis of industrial application technology for value-added and high-value utilization of catalytic diesel oil[J]. Chemical Engineering of Oil & Gas, 2022, 51(6): 34-40.
53	郭春垒, 万馨, 秦培尧. 全球首创:柴油吸附分离技术实现成功应用让成品油不过剩[J]. 中国石油石化, 2020(15): 56-57.
	Guo C L, Wan X, Qin P Y. The world’s first: diesel adsorption and separation technology realizes successful application so that there is no surplus of refined oil products[J]. China Petrochem, 2020(15): 56-57.
54	臧甲忠, 于海斌, 李滨, 等. 一种由劣质柴油生产清洁柴油和轻质芳烃的方法: 105542849B[P]. 2017-06-23.
	Zang J Z, Yu H B, Li B, et al. A method for producing clean diesel oil and light aromatics from inferior diesel fuel: 105542849B[P]. 2017-06-23.
55	Marti-Rujas J, Desmedt A, Harris K D M, et al. Bidirectional transport of guest molecules through the nanoporous tunnel structure of a solid inclusion compound[J]. The Journal of Physical Chemistry C, 2009, 113(2): 736-743.
56	Toudic B, Garcia P, Odin C, et al. Hidden degrees of freedom in aperiodic materials[J]. Science, 2008, 319(5859): 69-71.
57	Schmider J, Müller K. ²H NMR investigations of the hexadecane/urea inclusion compound[J]. The Journal of Physical Chemistry A, 1998, 102(7): 1181-1193.
58	Smith A E. The crystal structure of the urea-hydrocarbon complexes[J]. Acta Crystallographica, 1952, 5(2): 224-235.
59	Kobe K A, Reinhart L R. Separation of organic compounds with urea and thiourea[J]. Journal of Chemical Education, 1959, 36(6): 300-301.
60	Redlich O, Gable C M, Dunlop A K, et al. Addition compounds of urea and organic substances[J]. Journal of the American Chemical Society, 1950, 72(9): 4153-4160.
61	Yata N. Studies on the urea-dewaxing of lubricating oils[J]. Bulletin of the Japan Petroleum Institute, 1962, 4: 35-44.
62	姚致远, 黄荣荣, 姜仁玲, 等. 尿素络合法生产重质液体石蜡的工艺研究[J]. 化学工业与工程技术, 2001, 22(6): 11-12.
	Yao Z Y, Huang R R, Jiang R L, et al. Study on process of producing heavy liquid paraffin by urea complex[J]. Journal of Chemical Industry & Engineering, 2001, 22(6): 11-12.
63	苏重时, 全辉, 朱华艺, 等. 高含蜡的沈北原油尿素脱蜡生产变压器油的研究[J]. 石油炼制与化工, 1998, 29(11): 38-41.
	Su Z S, Quan H, Zhu H Y, et al. Production of transformer oil from highly paraffinic Shenbei crude by urea dewaxing technology[J]. Petroleum Processing and Petrochemicals, 1998, 29(11): 38-41.
64	赵军, 潘大壮. 三种原油的直馏柴油馏分尿素脱蜡研究[J]. 沈阳化工学院学报, 2006, 20(1): 4-8.
	Zhao J, Pan D Z. Study on urea dewaxing among straight-run diesel distillate of three crudes[J]. Journal of Shenyang Institute of Chemical Technology, 2006, 20(1): 4-8.
65	Marquart J R, Dellow G B, Freitas E R. Determination of noraml paraffins in petroleum heavy distillates by urea adduction and gas chromatography[J]. Analytical Chemistry, 1968, 40(11): 1633-1637.
66	温树棠. 尿素脱蜡工艺现状及其发展前景[J]. 辽宁化工, 1985, 14(3): 39-43.
	Wen S T. Present situation and development prospect of urea dewaxing process[J]. Liaoning Chemical Industry, 1985, 14(3): 39-43.
67	韩德奇, 洪国忠, 李平. 我国液体石蜡生产技术与重液蜡市场分析[J]. 化工科技市场, 2001, 24(8): 20-22.
	Han D Q, Hong G Z, Li P. Production technology of liquid wax and market analysis of heavy liquid wax[J]. Chemial Technology Market, 2001, 24(8): 20-22.
68	邵光涛, 袁炜. 液体石蜡分离技术在费-托合成油中的应用研究进展[J]. 炼油技术与工程, 2018, 48(3): 1-4.
	Shao G T, Yuan W. Study on application of liquid paraffin separation technologies in F-T synthetic oil[J]. Petroleum Refinery Engineering, 2018, 48(3): 1-4.
69	王世宏. 相变储能石蜡材料的制备及性能研究[D]. 沈阳: 沈阳建筑大学, 2011.
	Wang S H. The preparation and properties research of paraffin phase change energy storage materials[D]. Shenyang: Shenyang Jianzhu University, 2011.
70	Degnan Jr T F. Applications of zeolites in petroleum refining[J]. Topics in Catalysis, 2000, 13(4): 349-356.
71	王哲. 费托合成石脑油中低碳数正构烃与异构烃的络合分离研究[D]. 杭州: 浙江大学, 2022.
	Wang Z. Study on complexation separation of normal and isomeric hydrocarbons with medium and low carbon number in Fischer-Tropsch synthetic naphtha[D]. Hangzhou: Zhejiang University, 2022.
72	林本宽. BP公司MS₂及UCC公司ISOSIV分子筛脱蜡技术考察[J]. 炼油设计, 1987, 17(1): 19-26.
	Lin B K. Investigation on dewaxing technology of MS₂ of BP company and ISOSIV molecular sieve of UCC company[J]. Petroleum Refinery Engineering, 1987, 17(1): 19-26.
73	李娟. 分子筛脱蜡模拟移动床工业过程的模拟计算与分析[D]. 南京: 南京工业大学, 2005.
	Li J. Simulation and analysis of industrial paraffins separation process on molecular sieve by simulated moving bed adsorption[D]. Nanjing: Nanjing University of Technology, 2005.
74	武劲松. 新建分子筛脱蜡装置的设计及生产标定[J]. 当代化工, 2003, 32(2): 118-120.
	Wu J S. Design and evaluation of Molex unit[J]. Contemporary Chemical Industry, 2003, 32(2): 118-120.
75	蔡吉乡. 国产5A分子筛使用后期运行状况的研究和优化[J]. 精细石油化工进展, 2005, 6(4): 18-21.
	Cai J X. Research and optimization of evening application of homemade 5A zeolite[J]. Advances in Fine Petrochemicals, 2005, 6(4): 18-21.
76	丁云龙. 国产NWA型吸附剂在Molex装置上的工业应用[J]. 当代石油石化, 2003, 11(4): 34-36.
	Ding Y L. Application of China-made NWA adsorbent in Molex units[J]. Petroleum & Petrochemical Today, 2003, 11(4): 34-36.
77	顾文忠, 陈喜, 徐宏祥. 国产5A分子筛在Molex装置上运行初期分析[J]. 精细石油化工进展, 2000, 1(3): 38-42.
	Gu W Z, Chen X, Xu H X. Analysis of early application of homemade 5A zeolite on Molex unit[J]. Advances in Fine Petrochemicals, 2000, 1(3): 38-42.
78	王富城. 国产NWA-Ⅲ型分子筛在分子筛脱蜡装置上的应用[J]. 精细石油化工进展, 2015, 16(3): 35-38.
	Wang F C. Application of domestic NWA-Ⅲ molecular sieve in molecular sieve dewaxing unit[J]. Advances in Fine Petrochemicals, 2015, 16(3): 35-38.
79	奚瀚, 陈乐, 陈群, 等. 分离液体石蜡的5A分子筛吸附剂的制备[J]. 石油化工, 2012, 41(12): 1368-1372.
	Xi H, Chen L, Chen Q, et al. Preparation of 5A molecular sieve absorbent for separation of liquid paraffin[J]. Petrochemical Technology, 2012, 41(12): 1368-1372.
80	楚迎亚, 陈乐, 陈群. 正硅酸乙酯为硅源制备吸附分离液蜡的5A分子筛的研究[J]. 石油化工, 2014, 43(6): 631-636.
	Chu Y Y, Chen L, Chen Q. Preparation of 5A molecular sieve from ethyl orthosilicate for separation of liquid paraffin[J]. Petrochemical Technology, 2014, 43(6): 631-636.
81	潘慧. 微晶蜡溶剂脱蜡制备过程的基础研究[D]. 上海: 华东理工大学, 2012.
	Pan H. Basic research on microcrystalline wax production process by solvent dewaxing[D]. Shanghai: East China University of Science and Technology, 2012.
82	Sadulaeva A S, Ol’kov P L, Syrkin A M. Ethers-as solvents in dewaxing of raffinates: communication 1[J]. Chemistry and Technology of Fuels and Oils, 2006, 42(3): 183-187.
83	As’Ad A M, Yeneneh A M, Obanijesu E O. Solvent dewaxing of heavy crude oil with methyl ethyl ketone[J]. Journal of Petroleum & Environmental Biotechnology, 2015, 6(2): 1-5.
84	Tripathy A, Nimisha, Nath G, et al. Experimental and artificial neural network based analysis of solvent blends for dewaxing of crude oil[J]. Egyptian Journal of Petroleum, 2021, 30(1): 1-5.
85	徐春明, 杨朝合. 石油炼制工程[M]. 4版. 北京: 石油工业出版社, 2009: 546-556.
	Xu C M, Yang C H. Petroleum Refinery Engineering[M]. 4th ed. Beijing: Petroleum Industry Press, 2009: 546-556.
86	Taylor R J, McCormack A J. Study of solvent and catalytic lube oil dewaxing by analysis of feedstocks and products[J]. Industrial & Engineering Chemistry Research, 1992, 31(7): 1731-1738.
87	Al-Ameeri R, Fahim M A, Ijam M J, et al. Solvent dewaxing of Kuwait heavy gas oil[J]. Journal of The University of Kuwait-Science, 1985, 12(2): 181-189.
88	武玉民, 刘丹凤. 柴油稀释冷却脱蜡新工艺的研究[J]. 山东轻工业学院学报(自然科学版), 1995, 9(1): 24-25, 45.
	Wu Y M, Liu D F. A study on the new technology of diesel oil dilution and dewaxing[J]. Journal of Shandong Institute of Light Industry (Natural Science Edition), 1995, 9(1): 24-25, 45.
89	吕涯, 孙磊, 康晓丽. 选择性溶剂萃取生产低凝柴油的溶剂筛选和溶剂选择性的表征[J]. 化学世界, 2008, 49(2): 93-97, 106.
	Lv Y, Sun L, Kang X L. Screening of solvent and characterization of selectivity in solvent extraction for production of low freezing point diesel fuel[J]. Chemical World, 2008, 49(2): 93-97, 106.
90	吕涯, 陈淑芬. 热力学模型预测低温下柴油中正构烷烃的析出[J]. 化工进展, 2007, 26(12): 1743-1748.
	Lü Y, Chen S F. Prediction of the settling of n-alkane in diesel by thermodynamic model[J]. Chemical Industry and Engineering Progress, 2007, 26(12): 1743-1748.
91	Lü Y, Shi J J, Sun L. Investigation of the selection of extraction solvent for extracting the n-alkane from diesel by means of solubility parameters theory[J]. Journal of Fuel Chemistry and Technology, 2008, 36(3): 297-301.
92	吕涯, 郭婷. 两维新溶解度参数和柴油脱蜡溶剂的选择[J]. 化工学报, 2009, 60(12): 2963-2968.
	Lyu Y, Guo T. Two-dimensional solubility parameters and dewaxing solvent selection for diesels[J]. CIESC Journal, 2009, 60(12): 2963-2968.
93	吕涯, 闫凯, 孙磊. 应用三维溶解度参数球形模型研究柴油中正构烷烃的分离[J]. 华东理工大学学报(自然科学版), 2010, 36(6): 755-759.
	Lv Y, Yan K, Sun L. n-Alkanes deposition from diesels by three-dimensional solubility parameters sphere model[J]. Journal of East China University of Science and Technology (Natural Science Edition), 2010, 36(6): 755-759.
94	Qi Y T, Li H P, Qin S R. Influence of paraffin content on low temperature performances of diesel fuel and lube base oil[J]. Petroleum Science and Technology, 2001, 19(3/4): 403-409.
95	王海燕, 李丙庚. 常三线馏分油脱蜡工艺探索及产品应用浅析[J]. 石油商技, 2014, 32(4): 44-47.
	Wang H Y, Li B G. Exploration of dewaxing process of atmospheric third-line distillate oil and analysis of product application [J]. Petroleum Products Application Research, 2014, 32(4): 44-47.

技术类型	分离介质	分离介质的作用	分离对象	具体介质	分离效果	文献
吸附分离	吸附剂：活性炭、分子筛、氧化铝等	吸附剂表面具有对特定组分的选择性吸附能力	加氢精制柴油	MgY分子筛	R=1.32 （长周期）	[48]
溶剂萃取	互不相溶的有机溶剂/ 离子液体体系	利用链烷烃-芳烃溶解能力的差异实现对二者的重新分布	十二烷(1)/1-甲基萘(2)	环丁砜	S=285.50 D₂=0.88	[18]
			十二烷(1)/1-甲基萘(2)	二甲基亚砜	S=179.56 D₂=0.97	[19]
			十六烷(1)/1-甲基萘(2)	[BMIM][BF₄]	S=670.68 D₂=0.27	[29]
膜分离	特定孔径的半透膜	利用浓度差作为动力选择性通过不同组分	十四烷/菲	芳香聚酰亚胺膜	PSI=1.53 kg∙m^-2∙h^-1	[43]

技术类型	分离介质	分离介质的作用	分离对象	具体介质	分离效果	文献
吸附分离	吸附剂：活性炭、分子筛、氧化铝等	吸附剂表面具有对特定组分的选择性吸附能力	加氢精制柴油	MgY分子筛	R=1.32 （长周期）	[48]
溶剂萃取	互不相溶的有机溶剂/ 离子液体体系	利用链烷烃-芳烃溶解能力的差异实现对二者的重新分布	十二烷(1)/1-甲基萘(2)	环丁砜	S=285.50 D₂=0.88	[18]
			十二烷(1)/1-甲基萘(2)	二甲基亚砜	S=179.56 D₂=0.97	[19]
			十六烷(1)/1-甲基萘(2)	[BMIM][BF₄]	S=670.68 D₂=0.27	[29]
膜分离	特定孔径的半透膜	利用浓度差作为动力选择性通过不同组分	十四烷/菲	芳香聚酰亚胺膜	PSI=1.53 kg∙m^-2∙h^-1	[43]

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