固废基硫掺杂多孔炭材料制备及其对CO2吸附性能研究进展

doi:10.11949/0438-1157.20230900

摘要/Abstract

摘要：

含碳固废来源广、产量大，其大量堆存严重制约了环境可持续发展，因此含碳固废资源化利用意义重大。利用含碳固废制备多孔炭材料是其清洁高效利用的重要方式之一。对多孔炭进行硫原子掺杂不仅可使材料表面的亲水性得到改善，还可以改变材料表面的化学异质性，生成有利于CO₂捕集的活性位点，强化材料对CO₂分子的吸附作用，从而提高其CO₂吸附容量。简述了固废基硫掺杂多孔炭材料的制备方法，总结了硫掺杂多孔炭材料用于CO₂吸附的最新研究进展，并对硫掺杂多孔炭材料未来发展趋势及其在CO₂吸附领域的工业化应用进行了展望。

关键词: 废物处理, 含碳固废, 硫掺杂多孔炭, 吸附剂, CO₂捕集

Abstract:

Carbon-containing solid wastes have a wide range of sources as well as large output, which seriously restricts the sustainable development of the environment. Therefore, the resource utilization of carbon-containing solid waste is of great significance. The preparation of porous carbon from carbon-containing solid wastes is one of the most important ways to utilize them cleanly and efficiently. Sulfur atom doping of porous carbon can not only improve the hydrophilicity of the material surface, but also changes the chemical heterogeneity, and then generates active sites favorable for CO₂ capture, strengthens the adsorption performance of CO₂ molecules by the material, thus increases the adsorption capacity of CO₂. This paper briefly describes the preparation method of solid waste-based sulfur-doped porous carbon materials, summarizes the latest research progress of sulfur-doped porous carbon materials for CO₂ adsorption, and looks forward to the future development trend of sulfur-doped porous carbon materials and their industrialized application in the field of CO₂ adsorption.

Key words: waste treatment, carbon containing solid waste, sulfur-doped porous carbon, adsorbents, CO₂ capture

中图分类号:

X 511

王宝凤, 王术高, 程芳琴. 固废基硫掺杂多孔炭材料制备及其对CO₂吸附性能研究进展[J]. 化工学报, 2024, 75(2): 395-411.

Baofeng WANG, Shugao WANG, Fangqin CHENG. Progress in preparation and CO₂ adsorption properties of solid waste-based sulfur-doped porous carbon materials[J]. CIESC Journal, 2024, 75(2): 395-411.

图/表 8

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制备方法	反应温度/℃	优势	不足之处	硫掺杂多孔炭特性	文献
热解法	300~1000	操作简单、成本低	所需温度高、能耗大	掺杂量可控	[59]
水热碳化法	160~280	绿色环保、原料适用广	反应时间长、存在高压风险	碳化程度低；比表面积较小	[53]
活化法	600~1200	活化剂可选、制备成本低	腐蚀设备、污染环境	表面官能团丰富；比表面积大	[67]
后处理掺杂法	取决于掺杂步骤	适用范围广、掺杂量易控	需要额外工艺、步骤复杂	掺杂不均匀	[82]

制备方法	反应温度/℃	优势	不足之处	硫掺杂多孔炭特性	文献
热解法	300~1000	操作简单、成本低	所需温度高、能耗大	掺杂量可控	[59]
水热碳化法	160~280	绿色环保、原料适用广	反应时间长、存在高压风险	碳化程度低；比表面积较小	[53]
活化法	600~1200	活化剂可选、制备成本低	腐蚀设备、污染环境	表面官能团丰富；比表面积大	[67]
后处理掺杂法	取决于掺杂步骤	适用范围广、掺杂量易控	需要额外工艺、步骤复杂	掺杂不均匀	[82]

样品	硫含量/％(质量分数)	比表面积/(cm³/g)	总孔容/(cm³/g)	测试条件	CO₂最大捕集量/(mmol/g)	文献
SCEMC	6.56	1627	0.90	25℃，1 bar	2.46	[93]
CSI-800 ox	7.80	1893	1.16	20℃，1 bar	2.90	[81]
CS-1	8.2	2865	2.3	25℃，1 bar	2.06	[83]
S-CX-4-700-KOH	1.23	2051	1.10	0℃，1 bar	5.37	[126]
NSCS-4-700	2.93	1757	0.813	25℃，8bar	11.68	[138]
CS2	2.4	979	0.47	0℃，1 bar	5.63	[66]
NSPC-1-650	1.48	1927	0.36	25℃，5 bar	5.56	[139]
C3800	4.42	1631	1.08	25℃，20 bar	12.9	[9]
SNPC-F127-1	0.14	1512	0.71	25℃，1 bar	4.29	[140]
NSOPC-1	0.26	1292	0.68	25℃，1 bar	3.88	[112]
PFC-S	2.89	488	0.36	30℃，0.125 bar	1.25	[141]
LS-3	1	3626	1.741	25℃，757 Torr	10.89	[142]
NSDCS2700	4.4	2125	0.97	0℃，1 bar	5.6	[104]
GT-550-3	1.21	1213	0.48	25℃，1 bar	5.54	[103]
NSPC-2-500	1.63	1131	0.62	25℃，1 bar	3.73	[105]
HS-550-3	0.42	1600	0.61	25℃，1 bar	4.30	[106]
WT-550-3	0.45	1729	0.69	25℃，1 bar	4.31	[107]
NSAC-(1∶1)500(1)	0.2	1800	0.98	0℃，1 bar	7.02	[143]
PK3800	6.16	1673	0.76	25℃，20 bar	17.29	[144]
NSPC-600-2.5	0.71	1412	0.77	25℃，1 bar	5.51	[145]
ZTC-NS	1.5	1006.5	0.556	25℃，1 bar	6.03	[146]
S-PC-1	1.67	997	0.46	0℃，1 bar	5.13	[134]
SSA1000	8.4	658.08	0.29	25℃，0.15 bar	0.95	[98]

样品	硫含量/％(质量分数)	比表面积/(cm³/g)	总孔容/(cm³/g)	测试条件	CO₂最大捕集量/(mmol/g)	文献
SCEMC	6.56	1627	0.90	25℃，1 bar	2.46	[93]
CSI-800 ox	7.80	1893	1.16	20℃，1 bar	2.90	[81]
CS-1	8.2	2865	2.3	25℃，1 bar	2.06	[83]
S-CX-4-700-KOH	1.23	2051	1.10	0℃，1 bar	5.37	[126]
NSCS-4-700	2.93	1757	0.813	25℃，8bar	11.68	[138]
CS2	2.4	979	0.47	0℃，1 bar	5.63	[66]
NSPC-1-650	1.48	1927	0.36	25℃，5 bar	5.56	[139]
C3800	4.42	1631	1.08	25℃，20 bar	12.9	[9]
SNPC-F127-1	0.14	1512	0.71	25℃，1 bar	4.29	[140]
NSOPC-1	0.26	1292	0.68	25℃，1 bar	3.88	[112]
PFC-S	2.89	488	0.36	30℃，0.125 bar	1.25	[141]
LS-3	1	3626	1.741	25℃，757 Torr	10.89	[142]
NSDCS2700	4.4	2125	0.97	0℃，1 bar	5.6	[104]
GT-550-3	1.21	1213	0.48	25℃，1 bar	5.54	[103]
NSPC-2-500	1.63	1131	0.62	25℃，1 bar	3.73	[105]
HS-550-3	0.42	1600	0.61	25℃，1 bar	4.30	[106]
WT-550-3	0.45	1729	0.69	25℃，1 bar	4.31	[107]
NSAC-(1∶1)500(1)	0.2	1800	0.98	0℃，1 bar	7.02	[143]
PK3800	6.16	1673	0.76	25℃，20 bar	17.29	[144]
NSPC-600-2.5	0.71	1412	0.77	25℃，1 bar	5.51	[145]
ZTC-NS	1.5	1006.5	0.556	25℃，1 bar	6.03	[146]
S-PC-1	1.67	997	0.46	0℃，1 bar	5.13	[134]
SSA1000	8.4	658.08	0.29	25℃，0.15 bar	0.95	[98]

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固废基硫掺杂多孔炭材料制备及其对CO₂吸附性能研究进展

Progress in preparation and CO₂ adsorption properties of solid waste-based sulfur-doped porous carbon materials

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