PVDF/LFTCO（LaFe0.55Ti0.2Co0.25O3）催化膜类光芬顿降解盐酸四环素

doi:10.11949/0438-1157.20250356

摘要/Abstract

摘要：

医疗领域广泛使用抗生素治疗感染性疾病，然而其高极性、低挥发性的理化特性导致废水中大量药物残留，进而引发环境-生态-健康的风险级联效应，使得细菌具有耐药性的同时破坏水生生态系统。因此，高效处理废水中残存的抗生素十分必要。光催化与光芬顿技术是降解废水中残存抗生素的有效手段，然而现有光催化与光芬顿技术催化剂回收机制不完善、反应器光能利用效率低下，严重阻碍该技术从实验室向工业规模转化。为解决上述问题，本工作通过功能层原位设计，成功制备了PVDF/LFTCO （LaFe_0.55Ti_0.2Co_0.25O₃）催化膜，在光催化与类芬顿氧化协同耦合机制下，催化剂经由光致激发产生光生电子-空穴对，通过电荷分离和转移过程以及氧化还原循环反应，高效激活H₂O₂并生成活性自由基，PVDF/LFTCO催化膜在连续流装置中可稳定高效降解87.78%的盐酸四环素并在90 min内维持该性能。类光芬顿再生后，PVDF/LFTCO催化膜经过五次循环重复使用对盐酸四环素的降解率保持在73.50%，为构建高效废水处理膜提供了创新性解决方案。

关键词: 钙钛矿, 催化膜, 连续流, 催化降解, 盐酸四环素

Abstract:

Antibiotics are widely used in the medical field to treat infectious diseases. However, their high polarity and low volatility physical and chemical properties lead to a large amount of drug residues in wastewater, which in turn triggers a cascade effect of environmental-ecological-health risks, making bacteria resistant and destroying aquatic ecosystems. Consequently, the efficient removal of antibiotic residues from wastewater has become a critical environmental priority. Photocatalytic and photo-Fenton technologies have emerged as promising approaches for degrading antibiotic contaminants. However, existing methodologies are constrained by suboptimal catalyst recovery and limited photoreactor energy utilization, which restrict scalability from laboratory research to industrial implementation. To address these limitations, a PVDF/LFTCO (LaFe_0.55Ti_0.2Co_0.25O₃) catalytic membrane was developed through an in-situ functional layer design. The membrane facilitates photocatalytic and Fenton-like activation for the degradation of tetracycline hydrochloride. Under the synergistically coupled mechanism of photocatalysis and Fenton-like oxidation, catalysts undergo photoexcitation to generate photogenerated electron-hole pairs, which facilitate the efficient activation of H₂O₂ through charge separation and transfer processes coupled with redox cycling, subsequently generating reactive oxygen species. Consequently, the PVDF/LFTCO catalytic membrane exhibits stable and efficient degradation of tetracycline hydrochloride with a removal efficiency of 87.78% in a continuous-flow system, maintaining this performance within 90 min. After photo-Fenton-like regeneration, the degradation rate of tetracycline hydrochloride by the PVDF/LFTCO catalytic membrane after five cycles of reuse remains at 73.50%, providing an innovative solution for the construction of efficient wastewater treatment membranes.

Key words: perovskite, catalytic membrane, continuous flow, catalytic degradation, tetracycline hydrochloride

中图分类号:

TQ 032.4

韩霜, 王秋月, 刘泽贤, 仲兆祥, 邢卫红. PVDF/LFTCO（LaFe_0.55Ti_0.2Co_0.25O₃）催化膜类光芬顿降解盐酸四环素[J]. 化工学报, 2025, 76(10): 5290-5299.

Shuang HAN, Qiuyue WANG, Ze-Xian LOW, Zhaoxiang ZHONG, Weihong XING. Fabrication of PVDF/LFTCO (LaFe_0.55Ti_0.2Co_0.25O₃) catalytic membrane for photo-Fenton-like degradation of tetracycline hydrochloride[J]. CIESC Journal, 2025, 76(10): 5290-5299.

图/表 12

图1 PVDF/LFTCO膜制备流程图

Fig.1 Schematic diagram of PVDF/LFTCO membrane preparation

图2 连续流催化降解实验流程

Fig.2 Schematic diagram of continuous flow catalytic degradation experiment

图3 LFTCO-0.2的SEM图像(a)和元素扫描图像(b)；PVDF膜(c)和2、5和10 mg催化剂负载时PVDF/LFTCO催化膜的SEM图像[(d)~(f)]

Fig.3 SEM image (a) and EDX mapping (b) of LFTCO-0.2; SEM images of PVDF (c) and PVDF/LFTCO catalytic membranes with 2, 5, and 10 mg catalysts loads [(d)—(f)]

表1 PVDF商业膜的产品信息

Table 1 Product information of PVDF commercial membranes

项目	检测结果
孔径	0.22 μm
厚度	100~120 μm
直径	(50.00±0.30) mm
水流速	8.22 ml/(cm²·min)
泡点	300 MPa

图4 LFTCO-0.2、PVDF、PVDF/LFTCO-2、PVDF/LFTCO-5和PVDF/LFTCO-10膜的XRD谱图

Fig.4 XRD patterns of LFTCO-0.2, PVDF, PVDF/LFTCO-2, PVDF/LFTCO-5, and PVDF/LFTCO-10 membranes

图5 LFTCO-0.2、PVDF、PVDF/LFTCO-2、PVDF/LFTCO-5和PVDF/LFTCO-10膜的FTIR谱图

Fig.5 FTIR spectra of LFTCO-0.2, PVDF, PVDF/LFTCO-2, PVDF/LFTCO-5, and PVDF/LFTCO-10 membranes

图6 PVDF/LFTCO膜在不同反应体系下的降解效果[实验条件：初始污染物浓度10 mg/L，催化剂负载量5 mg，H2O2浓度20 mmol/L，膜通量334.39 L/(m2·h)，光照强度100 mW/cm2，不调节溶液pH，具体参数变化除外]

Fig.6 The degradation of PVDF/LFTCO membranes in different reaction systems [Experiment conditions: initial pollutant concentration 10 mg/L, catalyst load 5 mg, H2O2 concentration 20 mmol/L, membrane flux 334.39 L/(m2·h), light intensity 100 mW/cm2, natural pH except for the specific varied parameter]

图7 催化剂负载量(a)、H2O2浓度(b)和膜通量(c)对TCH降解的影响[实验条件：初始污染物浓度10 mg/L，催化剂负载量5 mg，H2O2浓度20 mmol/L，膜通量334.39 L/(m2·h)，光照强度100 mW/cm2，不调节溶液pH，具体参数变化除外]

Fig.7 Effects of catalyst load (a), H2O2 concentration (b) and feed flow rate (c) on TCH degradation [Experiment conditions: initial pollutant concentration 10 mg/L, catalyst load 5 mg, H2O2 concentration 20 mmol/L, membrane flux 334.39 L/(m2·h), light intensity 100 mW/cm2, natural pH except for the specific varied parameter]

表2 PVDF真空过滤负载催化膜对有机污染物的降解工作对比

Table 2 Comparison of organic contaminant degradation performance by PVDF vacuum filtration-supported catalytic membranes of previous researches

催化剂	污染物	催化类型	通量/(L/(m²·h))	去除效果/%	文献
S,N双掺杂碳（SNC）	四环素	过氧一硫酸盐	1726.65	91	[42]
Fe@NC	2,4-二氯苯酚	过氧一硫酸盐	306	99.2	[43]
Cu-MOF-74	四环素	过氧一硫酸盐	274.6	69.8	[44]
CuFeS₂	莫西沙星	过氧一硫酸盐	344.8	68.2	[45]
ZCO	磷酸氯喹	过氧一硫酸盐	192	45.3	[46]
ZnIn₂S₄	盐酸四环素	光催化	84.06	90	[47]
Co@CNT-GO	阿特拉津	过氧一硫酸盐	95.3	79	[48]
LFTCO	盐酸四环素	光芬顿	334.39	87.78	本工作

图8 不同pH条件下TCH的催化降解效果[实验条件：初始污染物浓度10 mg/L，催化剂负载量5 mg，H2O2浓度20 mmol/L，膜通量334.39 L/(m2·h)，光照强度100 mW/cm2]

Fig.8 Catalytic degradation effect of TCH under different pH conditions [Experiment conditions: initial pollutant concentration 10 mg/L, catalyst load 5 mg, H2O2 concentration 20 mmol/L, membrane flux 334.39 L/(m2·h), light intensity 100 mW/cm2]

图9 PVDF/LFTCO膜循环催化降解性能[实验条件：初始污染物浓度10 mg/L，催化剂负载量5 mg，H2O2浓度20 mmol/L，膜通量334.39 L/(m2·h)，光照强度100 mW/cm2]

Fig.9 Cyclic catalytic degradation performance of PVDF/LFTCO membrane [Experiment conditions: initial pollutant concentration 10 mg/L, catalyst load 5 mg, H2O2 concentration 20 mmol/L, membrane flux 334.39 L/(m2·h), light intensity 100 mW/cm2]

图10 PVDF/LFTCO催化膜的金属离子浸出情况(a)；新鲜、催化后以及再生后PVDF/LFTCO催化膜的XRD谱图(b)

Fig.10 Metal ion leaching of PVDF/LFTCO catalytic membranes (a); XRD patterns of fresh, used and regenerated PVDF/LFTCO catalytic membranes (b)

参考文献 49

[1]	Miao S, Zhang Y Y, Li B C, et al. Antibiotic intermediates and antibiotics synergistically promote the development of multiple antibiotic resistance in antibiotic production wastewater[J]. Journal of Hazardous Materials, 2024, 479: 135601.
[2]	Segura Y, Martinez F, Melero J A. Effective pharmaceutical wastewater degradation by Fenton oxidation with zero-valent iron[J]. Applied Catalysis B: Environmental, 2013, 136: 64-69.
[3]	Hu Y R, Lei D D, Wu D, et al. Residual β-lactam antibiotics and ecotoxicity to Vibrio fischeri, Daphnia magna of pharmaceutical wastewater in the treatment process[J]. Journal of Hazardous Materials, 2022, 425: 127840.
[4]	Li J C, Zhao L, Feng M B, et al. Abiotic transformation and ecotoxicity change of sulfonamide antibiotics in environmental and water treatment processes: a critical review[J]. Water Research, 2021, 202: 117463.
[5]	Kumar M, Mazumder P, Mohapatra S, et al. A chronicle of SARS-CoV-2: seasonality, environmental fate, transport, inactivation, and antiviral drug resistance[J]. Journal of Hazardous Materials, 2021, 405: 124043.
[6]	Wang W J, Li G Y, An T C, et al. Photocatalytic hydrogen evolution and bacterial inactivation utilizing sonochemical-synthesized g-C₃N₄/red phosphorus hybrid nanosheets as a wide-spectral-responsive photocatalyst: the role of type Ⅰ band alignment[J]. Applied Catalysis B: Environmental, 2018, 238: 126-135.
[7]	Xia T C, Li Q, Zhao X Y, et al. Bismuth and chlorine dual-doped perovskite chloride as a phase-structure-stable and moisture-resistant solid electrolyte for chloride ion batteries[J]. Advanced Materials, 2024, 36(4): e2310565.
[8]	Simböeck J, Ghiasi M, Schöenebaum S, et al. Electronic parameters in cobalt-based perovskite-type oxides as descriptors for chemocatalytic reactions[J]. Nature Communications, 2020, 11(1): 652.
[9]	Cai R X, Dou J, Krzystowczyk E, et al. Chemical looping air separation with Sr_0.8Ca_0.2Fe_0.9Co_0.1O_3- _δ perovskite sorbent: packed bed modeling, verification, and optimization[J]. Chemical Engineering Journal, 2022, 429: 132370.
[10]	Zheng W, Zhou X Y, Na Y Y, et al. Facile fabrication of regenerable spherical La_0.8Ce_0.2MnO₃ pellet via wet-chemistry molding strategy for elemental mercury removal[J]. Chemical Engineering Journal, 2024, 479: 147659.
[11]	Yang G, Liang Y J, Xiong Z R, et al. Molten salt-assisted synthesis of Ce₄O₇/Bi₄MoO₉ heterojunction photocatalysts for photo-Fenton degradation of tetracycline: enhanced mechanism, degradation pathway and products toxicity assessment[J]. Chemical Engineering Journal, 2021, 425: 130689.
[12]	Sun Y, Li R, Chen X X, et al. A-site management prompts the dynamic reconstructed active phase of perovskite oxide OER catalysts[J]. Advanced Energy Materials, 2021, 11(12): 2003755.
[13]	Zhu Y P, Chen G, Zhong Y J, et al. A surface-modified antiperovskite as an electrocatalyst for water oxidation[J]. Nature Communications, 2018, 9(1): 2326.
[14]	Mathews I, Kantareddy S N R, Sun S J, et al. Self-powered sensors enabled by wide-bandgap perovskite indoor photovoltaic cells[J]. Advanced Functional Materials, 2019, 29(42): 1904072.
[15]	Wang J, Ren Y, Liu H, et al. Ultrathin 2D NbWO₆ perovskite semiconductor based gas sensors with ultrahigh selectivity under low working temperature[J]. Advanced Materials, 2022, 34(2): e2104958.
[16]	Yu R X, Zhao J H, Zhao Z W, et al. Copper substituted zinc ferrite with abundant oxygen vacancies for enhanced ciprofloxacin degradation via peroxymonosulfate activation[J]. Journal of Hazardous Materials, 2020, 390: 121998.
[17]	Vadivel S, Maruthamani D, Habibi-Yangjeh A, et al. Facile synthesis of novel CaFe₂O₄/g-C₃N₄ nanocomposites for degradation of methylene blue under visible-light irradiation[J]. Journal of Colloid and Interface Science, 2016, 480: 126-136.
[18]	Dubey A, Keat C H, Shvartsman V V, et al. Mono-, di-, and tri-valent cation doped BiFe_0.95Mn_0.05O₃ nanoparticles: ferroelectric photocatalysts[J]. Advanced Functional Materials, 2022, 32(43): 2207105.
[19]	Humayun M, Ullah H, Usman M, et al. Perovskite-type lanthanum ferrite based photocatalysts: preparation, properties, and applications[J]. Journal of Energy Chemistry, 2022, 66: 314-338.
[20]	Gabra S, Marek E J, Poulston S, et al. The use of strontium ferrite perovskite as an oxygen carrier in the chemical looping epoxidation of ethylene[J]. Applied Catalysis B: Environmental, 2021, 286: 119821.
[21]	Mehdizadeh P, Amiri O, Rashki S, et al. Effective removal of organic pollution by using sonochemical prepared LaFeO₃ perovskite under visible light[J]. Ultrasonics Sonochemistry, 2020, 61: 104848.
[22]	Vijayaraghavan T, Bradha M, Babu P, et al. Influence of secondary oxide phases in enhancing the photocatalytic properties of alkaline earth elements doped LaFeO₃ nanocomposites[J]. Journal of Physics and Chemistry of Solids, 2020, 140: 109377.
[23]	Chen X, Zhang M, Qin H W, et al. Synergy effect between adsorption and heterogeneous photo-Fenton-like catalysis on LaFeO₃/lignin-biochar composites for high efficiency degradation of ofloxacin under visible light[J]. Separation and Purification Technology, 2022, 280: 119751.
[24]	Yi M, Xia Q, Tan J L, et al. Catalytic-separation technology for highly efficient removal of emerging pollutants, desalination, and antimicrobials: a new strategy for complex wastewater treatment[J]. Chemical Engineering Journal, 2024, 493: 152568.
[25]	Li Y B, He Y, Zhuang J, et al. Dual defense against membrane fouling for efficient and sustainable oil/water separation on a novel super-hydrophilic/underwater superoleophobic and catalytic nanofibrous membrane[J]. Chemical Engineering Journal, 2024, 497: 154489.
[26]	Zhang H L, Zheng Y L, Zhou H W, et al. Nanocellulose-intercalated MXene NF membrane with enhanced swelling resistance for highly efficient antibiotics separation[J]. Separation and Purification Technology, 2023, 305: 122425.
[27]	Kumar M, Sreedhar N, Thomas N, et al. Polydopamine-coated graphene oxide nanosheets embedded in sulfonated poly(ether sulfone) hybrid UF membranes with superior antifouling properties for water treatment[J]. Chemical Engineering Journal, 2022, 433: 133526.
[28]	Pan Y P, Shi Z Z, Li J, et al. Graphene oxide laminates intercalated with Prussian blue nanocube as a photo-Fenton self-cleaning membrane for enhanced water purification[J]. Journal of Membrane Science, 2023, 672: 121465.
[29]	Zheng H A, Li M Y, Jiang S Y, et al. MIL-88A/carbon quantum dots nanomaterials promote the photo-Fenton reaction to enhance the fouling resistance of PVDF membrane[J]. Journal of Membrane Science, 2023, 684: 121855.
[30]	Gao Y X, Yan S M, He Y, et al. A photo-Fenton self-cleaning membrane based on NH₂-MIL-88B (Fe) and graphene oxide to improve dye removal performance[J]. Journal of Membrane Science, 2021, 626: 119192.
[31]	Chen C X, Wang S M, Han F, et al. Synergy of rapid adsorption and photo-Fenton-like degradation in CoFe-MOF/TiO₂/PVDF composite membrane for efficient removal of antibiotics from water[J]. Separation and Purification Technology, 2024, 333: 125942.
[32]	Zheng H A, Xiao C Z, Jiang S Y, et al. Fabrication of PVDF membrane loaded with ultra-thin g-C₃N₄/FeOCl nanomaterials and study on catalytic and antifouling properties[J]. Separation and Purification Technology, 2024, 331: 125641.
[33]	Chen C C, Xie M, Kong L S, et al. Mn₃O₄ nanodots loaded g-C₃N₄ nanosheets for catalytic membrane degradation of organic contaminants[J]. Journal of Hazardous Materials, 2020, 390: 122146.
[34]	Zhong Q, Shi G G, Sun Q, et al. Robust PVA-GO-TiO₂ composite membrane for efficient separation oil-in-water emulsions with stable high flux[J]. Journal of Membrane Science, 2021, 640: 119836.
[35]	Zhou M, Ma X, Ji C Y, et al. Chelating adsorption-engaged anionic dye removal and Fenton-driven regeneration in ferromagnetic Ti/Co-LaFeO₃ perovskite[J]. Chemical Engineering Journal, 2024, 479: 147600.
[36]	Gao B R, Dou M M, Wang J, et al. Effect of carbon nitride synthesized by different modification strategies on the performance of carbon nitride/PVDF photocatalytic composite membranes[J]. Journal of Hazardous Materials, 2022, 422: 126877.
[37]	Lin H B, Fang Q L, Wang W, et al. Prussian blue/PVDF catalytic membrane with exceptional and stable Fenton oxidation performance for organic pollutants removal[J]. Applied Catalysis B: Environmental, 2020, 273: 119047.
[38]	Cao Z, Zhao Y P, Zhou Z H, et al. Efficiency LaFeO₃ and BiOI heterojunction for the enhanced photo-Fenton degradation of tetracycline hydrochloride[J]. Applied Surface Science, 2022, 590: 153081.
[39]	Xie A T, Cui J Y, Yang J, et al. Graphene oxide/Fe(Ⅲ)-based metal-organic framework membrane for enhanced water purification based on synergistic separation and photo-Fenton processes[J]. Applied Catalysis B: Environmental, 2020, 264: 118548.
[40]	Wang Z W, Liu W J, Jin H B, et al. Layered double hydroxide helps LaFeO₃ photocatalyst activate peroxymonosulfate to efficiently degrade dyes[J]. Separation and Purification Technology, 2024, 341: 126832.
[41]	Yi H, Huang D L, Qin L, et al. Selective prepared carbon nanomaterials for advanced photocatalytic application in environmental pollutant treatment and hydrogen production[J]. Applied Catalysis B: Environmental, 2018, 239: 408-424.
[42]	Gong X B, Xie J L, Pan X F, et al. S, N co-doped carbon material functionalized catalytic membrane for efficient peroxymonosulfate activation and continuous refractory pollutants flow-treatment[J]. Chemical Engineering Science, 2023, 282: 119353.
[43]	Ma T G, Ren H J, Liu M J, et al. Nanoconfined catalytic membrane assembled by nitrogen-doped carbon encapsulating Fe-based nanoparticles for rapid removal of 2, 4-dichlorophenol in wastewater by peroxymonosulfate activation[J]. Journal of Hazardous Materials, 2024, 466: 133523.
[44]	Zheng H A, Zhou Y, Wang D R, et al. Surface-functionalized PVDF membranes by facile synthetic Cu-MOF-74 for enhanced contaminant degradation and antifouling performance[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 651: 129640.
[45]	Zhang D Y, Li K F, Fang L, et al. CuFeS₂/MXene-modified polyvinylidene fluoride membrane for antibiotics removal through peroxymonosulfate activation[J]. Water, 2024, 16(11): 1504.
[46]	Xu S T, Feng K, Zhang X, et al. Spinel-based zinc-doped Co₃O₄ (ZCO) catalytic membrane for efficient peroxymonosulfate activation and chloroquine phosphate degradation: an atom doping strategy[J]. Environmental Research, 2025, 275: 121408.
[47]	Gao B, Chen W P, Liu J D, et al. Continuous removal of tetracycline in a photocatalytic membrane reactor (PMR) with ZnIn₂S₄ as adsorption and photocatalytic coating layer on PVDF membrane[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2018, 364: 732-739.
[48]	Liu T, He Y L, He M R, et al. Nanoconfined catalytic membranes assembled by cobalt-loaded carbon nanotubes and graphene oxide for highly efficient water decontamination[J]. Journal of Membrane Science, 2024, 707: 123002.
[49]	Shan Z L, Ma F, You S J, et al. Enhanced visible light photo-Fenton catalysis by lanthanum-doping BiFeO₃ for norfloxacin degradation[J]. Environmental Research, 2023, 216: 114588.

PVDF/LFTCO（LaFe_0.55Ti_0.2Co_0.25O₃）催化膜类光芬顿降解盐酸四环素

Fabrication of PVDF/LFTCO (LaFe_0.55Ti_0.2Co_0.25O₃) catalytic membrane for photo-Fenton-like degradation of tetracycline hydrochloride

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 49

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王三龙, 王跃霖, 曹宇. 基于相异质结的高效无机钙钛矿太阳能电池的性能研究[J]. 化工学报, 2025, 76(3): 1346-1352.
[2]	薛潇, 商敏静, 苏远海. 微反应器内药物连续流合成的研究进展[J]. 化工学报, 2024, 75(4): 1439-1454.
[3]	马浩天, 荆体瑞, 刘程程, 玉散·吐拉甫, 张喆, 王一迪, 王庆宏, 陈春茂, 徐春明. Sr改性LaFeO₃用于甲烷化学链重整的还原性能与动力学研究[J]. 化工学报, 2024, 75(12): 4532-4546.
[4]	吴云, 龚海峰. 疏水改性羰基铁负载TiO₂光催化降解石油烃污染物[J]. 化工学报, 2024, 75(12): 4555-4562.
[5]	马烨玮, 孙艳娜, 高栋, 王海彬, 姚善泾, 林东强. 模型辅助的单抗连续捕获工艺分析和过程优化[J]. 化工学报, 2024, 75(11): 4274-4285.
[6]	范孝雄, 郝丽芳, 范垂钢, 李松庚. LaMnO₃/生物炭催化剂低温NH₃-SCR催化脱硝性能研究[J]. 化工学报, 2023, 74(9): 3821-3830.
[7]	傅予, 刘兴翀, 王瀚雨, 李海敏, 倪亚飞, 邹文静, 雷月, 彭永姗. F₃EACl修饰层对钙钛矿太阳能电池性能提升的研究[J]. 化工学报, 2023, 74(8): 3554-3563.
[8]	杨小芹, 刘馨雨, 杨玉寒, 叶彦, 贾琼, 杨浩男, 秦志宏. 煤基泡沫炭复合F-TiO₂光催化降解苯酚[J]. 化工学报, 2023, 74(12): 4914-4925.
[9]	杨柳青, 赵子瑞, 张军社, 魏进家. 钡含量对（La_0.5Sr_0.5）_1-_x Ba _x Fe_0.6Co_0.4O₃化学链甲烷干重整性能的影响[J]. 化工学报, 2023, 74(10): 4286-4301.
[10]	张婉晨, 陈晓阳, 吕秋秋, 钟秦, 朱腾龙. Co掺杂SrTi_0.3Fe_0.7O_3-_δ 阳极SOFC在化工副产气燃料下的性能及稳定性[J]. 化工学报, 2022, 73(9): 4079-4086.
[11]	艾承燚, 乔金硕, 王振华, 孙旺, 孙克宁. 原位析出纳米合金的PrBaFe₂O_6-_δ 基阳极构筑及其在固体碳燃料电池中的应用研究[J]. 化工学报, 2022, 73(8): 3708-3719.
[12]	徐珂, 史国强, 薛冬峰. 无机杂化钙钛矿团簇材料：介尺度钙钛矿材料发光性质研究[J]. 化工学报, 2022, 73(6): 2748-2756.
[13]	李文怀, 周嵬. 高氧离子电导钙钛矿的影响因素分析和设计策略[J]. 化工学报, 2022, 73(4): 1455-1471.
[14]	董晓珊, 李健, 颜蓓蓓, 陈冠益. 钙钛矿催化剂在生物质热化学利用领域的研究进展[J]. 化工学报, 2022, 73(2): 504-520.
[15]	娄锋炎, 尹佳滨, 段笑南, 王祁宁, 艾宁, 张吉松. 连续微反应加氢技术在脱保护反应中的应用[J]. 化工学报, 2021, 72(2): 761-771.