CIESC Journal ›› 2020, Vol. 71 ›› Issue (12): 5578-5588.DOI: 10.11949/0438-1157.20200539

• Catalysis, kinetics and reactors • Previous Articles     Next Articles

Phi zeolite synthesized by template-free method for selective catalytic reduction of NO

YANG Runnong1(),YU Lin1(),ZHAO Xiangyun2,YANG Xiaobo1,2(),GAO Zihan1,FU Guangying3,JIANG Jiuxing3,LIAN Weilin2,LIU Wuyuan1,2,FAN Qun1,2   

  1. 1.Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
    2.Waygreen Environmental Protection Technology Co. , Ltd. , Guangzhou 511441, Guangdong, China
    3.School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China
  • Received:2020-05-09 Revised:2020-07-08 Online:2020-12-05 Published:2020-12-05
  • Contact: YU Lin,YANG Xiaobo

无模板法合成的Phi分子筛在NO选择性催化还原中的应用

杨润农1(),余林1(),赵向云2,杨晓波1,2(),高梓寒1,傅广赢3,姜久兴3,练纬琳2,刘武源1,2,范群1,2   

  1. 1.广东工业大学轻工化工学院,广州市清洁交通能源化学重点实验室,广东 广州 510006
    2.广州市威格林环保科技 有限公司,广东 广州 511441
    3.中山大学化学学院,广东 广州 510275
  • 通讯作者: 余林,杨晓波
  • 作者简介:杨润农(1989—),女,博士研究生,Yangrn0814@163.com
  • 基金资助:
    国家自然科学基金项目(21576054);广东省省级科技计划项目(2016B020241003)

Abstract:

Nitrogen oxide (NOx) is one of the major air pollutants. Using a copper-based zeolite with a chabazite structure (CHA) as a catalyst, the selective catalytic reduction (SCR) technology can effectively remove NOx. This work introduces a low silica CHA type zeolite with structural defects (zeolite Phi, with Si/Al of 4.7). The zeolite Phi is synthesized through a hydrothermal method without adding any template, which is low-cost and environment-friendly. The Cu-exchanged Phi is abundant of surface acidity and isolated Cu2+, showing a superior low-temperature activity, a wide work temperature window and a good hydrothermal stability. The presence of Na or Mg decreases the surface acidity and isolated Cu2+. The hydrothermally aged Na,Cu/Phi and Mg,Cu/Phi present different levels of framework collapse, which correspondingly induces catalyst deactivation.

Key words: zeolite, catalyst, alkali/alkaline earth metal, hydrothermal stability, deactivation, NH3-SCR

摘要:

氮氧化物(NOx)是大气中的一种主要污染物。采用具有菱沸石结构(CHA)的铜基分子筛作为催化剂,通过选择性催化还原(SCR)技术可有效去除NOx。采用一种经济环保的制备方法,在不使用模板剂的条件下水热合成一种具有结构缺陷的低硅铝比CHA型分子筛(Phi,Si/Al=4.7)。结果表明,经Cu离子交换制备的Cu/Phi具有最丰富的表面酸性与孤立态Cu2+,表现出较好的低温活性、较宽的工作温度窗口以及良好的水热稳定性。Na或Mg的存在降低了Cu/Phi的表面酸性及孤立态Cu2+的含量,水热老化后的Na,Cu/Phi和Mg,Cu/Phi均呈现出不同程度的骨架坍塌,相应导致了催化剂失活。

关键词: 分子筛, 催化剂, 碱/碱土金属离子, 水热稳定性, 失活, NH3-SCR

CLC Number: