CIESC Journal ›› 2024, Vol. 75 ›› Issue (7): 2556-2564.DOI: 10.11949/0438-1157.20240047
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Lu YANG1(), Congcong LIU2, Tongtong MENG1, Boyuan ZHANG1, Tengfei YANG1(
), Wen’an DENG3, Xiaobin WANG1(
)
Received:
2024-01-10
Revised:
2024-05-20
Online:
2024-08-09
Published:
2024-07-25
Contact:
Tengfei YANG, Xiaobin WANG
杨露1(), 刘聪聪2, 孟彤彤1, 张博远1, 杨腾飞1(
), 邓文安3, 王晓斌1(
)
通讯作者:
杨腾飞,王晓斌
作者简介:
杨露(1998—),女,硕士研究生,350641167@qq.com
基金资助:
CLC Number:
Lu YANG, Congcong LIU, Tongtong MENG, Boyuan ZHANG, Tengfei YANG, Wen’an DENG, Xiaobin WANG. Hydrogenation and coke-suppression performance of dispersed catalyst in coal/heavy oil co-processing reactions[J]. CIESC Journal, 2024, 75(7): 2556-2564.
杨露, 刘聪聪, 孟彤彤, 张博远, 杨腾飞, 邓文安, 王晓斌. 分散型催化剂在煤/重油共炼体系中的加氢抑焦作用[J]. 化工学报, 2024, 75(7): 2556-2564.
性质 | 褐煤 | 常渣 |
---|---|---|
挥发分含量/%(质量分数,daf) | 58.4 | / |
固定碳含量/%(质量分数,daf) | 41.6 | / |
灰分含量/%(质量分数,ad) | 4.5 | — |
密度(20℃)/(g·cm-3) | 1.475 | 0.998 |
黏度(100℃)/(mm2·s-1) | / | 294.3 |
硫含量/%(质量分数) | 0.61 | 2.38 |
氮含量/%(质量分数) | 0.66 | 0.62 |
氢/碳摩尔比 | 0.912 | 1.526 |
初馏点~360℃馏分/%(质量分数) | / | 1.8 |
360~480℃馏分/%(质量分数) | / | 85.5 |
>480℃馏分/%(质量分数) | / | 12.7 |
正庚烷沥青质含量/%(质量分数) | / | 10.2 |
甲苯不溶物含量/%(质量分数) | / | — |
Table 1 Main properties of Indonesia lignite and MRAR
性质 | 褐煤 | 常渣 |
---|---|---|
挥发分含量/%(质量分数,daf) | 58.4 | / |
固定碳含量/%(质量分数,daf) | 41.6 | / |
灰分含量/%(质量分数,ad) | 4.5 | — |
密度(20℃)/(g·cm-3) | 1.475 | 0.998 |
黏度(100℃)/(mm2·s-1) | / | 294.3 |
硫含量/%(质量分数) | 0.61 | 2.38 |
氮含量/%(质量分数) | 0.66 | 0.62 |
氢/碳摩尔比 | 0.912 | 1.526 |
初馏点~360℃馏分/%(质量分数) | / | 1.8 |
360~480℃馏分/%(质量分数) | / | 85.5 |
>480℃馏分/%(质量分数) | / | 12.7 |
正庚烷沥青质含量/%(质量分数) | / | 10.2 |
甲苯不溶物含量/%(质量分数) | / | — |
固体残渣 样品 | 相对含量/% | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
芳香碳 | 烷基碳 | 羰/羧基碳 | 桥联碳 | 质子化芳香碳 | 氧连芳香碳 | 烷基侧链芳香碳 | 甲(氧)基碳 | 亚/次甲基碳 | 氧连烷基碳 | |
SR0 | 71.6 | 28.4 | 17.8 | 10.9 | 26.2 | 6.3 | 10.4 | 15.6 | 12.8 | 8.8 |
SR500 | 62.5 | 37.5 | 13.9 | 9.5 | 22.7 | 5.8 | 10.6 | 16.4 | 21.1 | 8.2 |
SR1500 | 62.3 | 37.7 | 13.2 | 9.0 | 24.6 | 5.3 | 10.2 | 18.1 | 19.6 | 7.4 |
Table 2 Relative proportions of different organic carbons in solid residues
固体残渣 样品 | 相对含量/% | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
芳香碳 | 烷基碳 | 羰/羧基碳 | 桥联碳 | 质子化芳香碳 | 氧连芳香碳 | 烷基侧链芳香碳 | 甲(氧)基碳 | 亚/次甲基碳 | 氧连烷基碳 | |
SR0 | 71.6 | 28.4 | 17.8 | 10.9 | 26.2 | 6.3 | 10.4 | 15.6 | 12.8 | 8.8 |
SR500 | 62.5 | 37.5 | 13.9 | 9.5 | 22.7 | 5.8 | 10.6 | 16.4 | 21.1 | 8.2 |
SR1500 | 62.3 | 37.7 | 13.2 | 9.0 | 24.6 | 5.3 | 10.2 | 18.1 | 19.6 | 7.4 |
固体残渣 样品 | 最高热解 温度Tm/℃ | 活化能Ea/ (kJ·mol-1) | 指前因子A/s-1 | 拟合度R2 |
---|---|---|---|---|
SR0 | 479.5 | 49.9 | 18.89 | 0.992 |
SR500 | 468.2 | 41.8 | 5.14 | 0.998 |
SR1500 | 455.3 | 36.1 | 2.83 | 0.997 |
Table 3 Pyrolysis kinetic parameters for solid residues at the maximum pyrolysis temperature
固体残渣 样品 | 最高热解 温度Tm/℃ | 活化能Ea/ (kJ·mol-1) | 指前因子A/s-1 | 拟合度R2 |
---|---|---|---|---|
SR0 | 479.5 | 49.9 | 18.89 | 0.992 |
SR500 | 468.2 | 41.8 | 5.14 | 0.998 |
SR1500 | 455.3 | 36.1 | 2.83 | 0.997 |
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