Recent advances in catalytic methods of CO2 hydrogenation to clean energy

doi:10.11949/0438-1157.20200115

Abstract

Abstract:

Excessive CO₂ emissions have caused a serious greenhouse effect. The use of CO₂ hydrogenation technology can achieve high-value products while reducing CO₂emissions. Therefore, it has been widely concerned by researchers. In recent years, the research on the hydrogenation of CO₂ has gradually increased, but there are few related reviews to comprehensively explore multiple catalytic methods. In this paper, the relatively new CO₂ hydrogenation technologies are roughly divided into 4 types: photocatalysis, electrocatalysis, biocatalysis, and plasma catalysis. From the perspective of catalysts, the research status and latest progress of four new CO₂ hydrogenation technologies above are summarized, and their reaction mechanisms are briefly introduced. At the same time, based on the analysis of the current research status, the related problems that need to be further studied and solved for the four hydrogenation technologies are pointed out, and the development and industrialization of CO₂ hydrogenation technology are prospected.

Key words: CO₂, hydrogenation, photocatalysis, electrocatalysis, biocatalysis, plasma catalysis

摘要：

CO₂的过量排放引发了严重的温室效应，采用CO₂氢化技术在实现CO₂减排的同时又可生成高价值的产物，因此受到研究人员的广泛关注。近年来，关于CO₂氢化的研究逐渐增多，但是综合探讨多种催化技术的相关综述较少。本文将较为新型的CO₂氢化技术大致分为光催化、电催化、生物催化以及等离子体催化4种。主要从催化剂的角度，对以上4种新型CO₂氢化技术的研究现状和最新进展进行了归纳，并简要介绍了其反应机理。同时，基于研究现状的分析，指出了4种氢化技术的进一步研究方向和需要解决的相关问题，并对CO₂氢化技术的发展作出了展望。

关键词: CO₂, 氢化, 光催化, 电催化, 生物催化, 等离子体催化

CLC Number:

X 701.7

Qi ZHOU, Honglei DING, Detong GUO, Weiguo PAN, Wei DU. Recent advances in catalytic methods of CO₂ hydrogenation to clean energy[J]. CIESC Journal, 2020, 71(8): 3428-3443.

周柒, 丁红蕾, 郭得通, 潘卫国, 杜威. CO₂催化氢化制清洁能源的研究进展及趋势[J]. 化工学报, 2020, 71(8): 3428-3443.

Figures/Tables 14

References 131

1	Li S, Guo L, Ishihara T. Hydrogenation of CO₂ to methanol over Cu/AlCeO catalyst[J]. Catalysis Today, 2020, 339: 352-361.
2	Sgouridis S, Carbajales-Dale M, Csala D, et al. Comparative net energy analysis of renewable electricity and carbon capture and storage [J]. Nat. Energy, 2019, 4(6): 456-465.
3	Mac Dowell N, Fennell P S, Shah N, et al. The role of CO₂ capture and utilization in mitigating climate change [J]. Nat. Clim. Change, 2017, 7(4): 243-249.
4	Wang L, Yi Y, Guo H, et al. Atmospheric pressure and room temperature synthesis of methanol through plasma-catalytic hydrogenation of CO₂ [J]. ACS Catalysis, 2017, 8(1): 90-100.
5	Snoeckx R, Bogaerts A. Plasma technology — a novel solution for CO₂ conversion? [J]. Chem. Soc. Rev., 2017, 46(19): 5805-5863.
6	Rahmatmand B, Rahimpour M R, Keshavarz P. Introducing a novel process to enhance the syngas conversion to methanol over Cu/ZnO/Al₂O₃ catalyst[J]. Fuel Processing Technology, 2019, 193: 159-179.
7	Sperling D. Beyond oil and gas: the methanol economy [J]. Energ. J., 2007, 28(1): 178-189.
8	Low J, Cheng B, Yu J. Surface modification and enhanced photocatalytic CO₂ reduction performance of TiO₂: a review[J]. Applied Surface Science, 2017, 392: 658-686.
9	曹晨熙, 陈天元, 丁晓旭, 等. 负载型铟基催化剂二氧化碳加氢动力学研究[J]. 化工学报, 2019, 70(10): 3985-3993.
	Cao C X, Chen T Y, Ding X X, et al. Kinetics study on supported indium-based catalysts in carbon dioxide hydrogenation [J]. CIESC Journal, 2019, 70(10): 3985-3993.
10	Li N X, Zou X Y, Liu M, et al. Enhanced visible light photocatalytic hydrogenation of CO₂ into methane over a Pd/Ce-TiO₂ nanocomposition [J]. The Journal of Physical Chemistry C, 2017, 121(46): 25795-25804.
11	Yan Y B, Yu Y L, Huang S L, et al. Adjustment and matching of energy band of TiO₂-based photocatalysts by metal ions (Pd, Cu, Mn) for photoreduction of CO₂ into CH₄ [J]. J. Phys. Chem. C, 2017, 121(2): 1089-1098.
12	Tahir M, Tahir B. Dynamic photocatalytic reduction of CO₂ to CO in a honeycomb monolith reactor loaded with Cu and N doped TiO₂ nanocatalysts [J]. Applied Surface Science, 2016, 377: 244-252
13	Butburee T, Sun Z, Centeno A, et al. Improved CO₂ photocatalytic reduction using a novel 3-component heterojunction[J]. Nano Energy, 2019, 62: 426-433.
14	Low J X, Zhang L Y, Tong T, et al. TiO₂/MXene Ti₃C₂ composite with excellent photocatalytic CO₂reduction activity [J]. Journal of Catalysis, 2018, 361: 255-266.
15	Xu Y J, Wang S, Yang J, et al. In-situ grown nanocrystal TiO₂ on 2D Ti₃C₂ nanosheets for artificial photosynthesis of chemical fuels [J]. Nano Energy, 2018, 51: 442-450.
16	Zhang X F, Liu Y, Dong S L, et al. One-step hydrothermal synthesis of a TiO₂-Ti₃C₂T_x nanocomposite with small sized TiO₂ nanoparticles[J]. Ceramics International, 2017, 43(14): 11065-11070.
17	Xu F Y, Zhang J J, Zhu B C, et al. CuInS₂ sensitized TiO₂ hybrid nanofibers for improved photocatalytic CO₂ reduction [J]. Appl. Catal. B-Environ., 2018, 230: 194-202.
18	Rambabu Y, Kumar U, Singhal N, et al. Photocatalytic reduction of carbon dioxide using graphene oxide wrapped TiO₂ nanotubes [J]. Applied Surface Science, 2019, 485: 48-55.
19	Fu F Y, Shown I, Li C S, et al. KSCN-induced interfacial dipole in black TiO₂ for enhanced photocatalytic CO₂ reduction [J]. ACS Applied Materials & Interfaces, 2019, 11(28): 25186-25194.
20	Ye J, He J H, Wang S, et al. Nickel-loaded black TiO₂ with inverse opal structure for photocatalytic reduction of CO₂ under visible light [J]. Separation and Purification Technology, 2019, 220: 8-15.
21	Zhao J, Li Y X, Zhu Y Q, et al. Enhanced CO₂ photoreduction activity of black TiO₂-coated Cu nanoparticles under visible light irradiation: role of metallic Cu [J]. Appl. Catal. A-Gen., 2016, 510: 34-41.
22	Liao F, Huang Y, Ge J, et al. Morphology-dependent interactions of ZnO with Cu nanoparticles at the materials interface in selective hydrogenation of CO₂ to CH₃OH [J]. Angewandte Chemie, 2011, 50(9): 2162-2175.
23	Deng K, Hu B, Lu Q, et al. Cu/g-C₃N₄ modified ZnO/Al₂O₃ catalyst: methanol yield improvement of CO₂ hydrogenation [J]. Catalysis Communications, 2017, 100: 81-84.
24	Li M M J, Zeng Z Y, Liao F L, et al. Enhanced CO₂ hydrogenation to methanol over CuZn nanoalloy in Ga modified Cu/ZnO catalysts [J]. Journal of Catalysis, 2016, 343: 157-167.
25	Wang Z J, Song H, Pang H, et al. Photo-assisted methanol synthesis via CO₂ reduction under ambient pressure over plasmonic Cu/ZnO catalysts [J]. Appl. Catal. B-Environ., 2019, 250: 10-16.
26	Martin O, Martin A J, Mandelli C, et al. Indium oxide as a superior catalyst for methanol synthesis by CO₂ hydrogenation [J]. Angewandte Chemie, 2016, 55(21): 6261-6265.
27	Gondal M A, Dastageer M A, Oloore L E, et al. Laser induced selective photo-catalytic reduction of CO₂ into methanol using In₂O₃-WO₃ nano-composite [J]. J. Photoch. Photobio. A, 2017, 343: 40-50.
28	Guan J R, Wang H Q, Lu J Z, et al. Enhanced photocatalytic reduction of CO₂ by fabricating In₂O₃/CeO₂/HATP hybrid multi-junction photocatalyst [J]. Journal of the Taiwan Institute of Chemical Engineers, 2019, 99: 93-103.
29	Pan Y X, You Y, Xin S, et al. Photocatalytic CO₂ reduction by carbon-coated indium-oxide nanobelts [J]. Journal of the American Chemical Society, 2017, 139(11): 4123-4129.
30	Wang L, Ghoussoub M, Wang H, et al. Photocatalytic hydrogenation of carbon dioxide with high selectivity to methanol at atmospheric pressure [J]. Joule, 2018, 2(7): 1369-1381.
31	Sharma N, Das T, Kumar S, et al. Photocatalytic activation and reduction of CO₂ to CH₄ over single phase nano Cu₃SnS₄: a combined experimental and theoretical study [J]. ACS Applied Energy Materials, 2019, 2(8): 5677-5685.
32	Li P, Hou C C, Zhang X H, et al. Ethylenediamine-functionalized CdS/tetra(4-carboxyphenyl) porphyrin iron (III) chloride hybrid system for enhanced CO₂ photoreduction [J]. Applied Surface Science, 2018, 459: 292-299.
33	Kandy M M, Gaikar V G. Enhanced photocatalytic reduction of CO₂ using CdS/Mn₂O₃ nanocomposite photocatalysts on porous anodic alumina support with solar concentrators [J]. Renew. Energ., 2019, 139: 915-923.
34	Jin J, Yu J G, Guo D P, et al. A hierarchical Z-scheme CdS-WO₃ photocatalyst with enhanced CO₂ reduction activity [J]. Small, 2015, 11(39): 5262-5271.
35	Wei Z H, Wang Y F, Li Y Y, et al. Enhanced photocatalytic CO₂ reduction activity of Z-scheme CdS/BiVO₄ nanocomposite with thinner BiVO₄ nanosheets [J]. Journal of CO₂ Utilization, 2018, 28: 15-25.
36	Li Y Y, Wei Z H, Fan J B, et al. Photocatalytic CO₂ reduction activity of Z-scheme CdS/CdWO₄ catalysts constructed by surface charge directed selective deposition of CdS [J]. Applied Surface Science, 2019, 483: 442-452.
37	Ijaz S, Ehsan M F, Ashiq M N, et al. Flower-like CdS/CdV₂O₆ composite for visible-light photoconversion of CO₂ into CH₄ [J]. Materials & Design, 2016, 107: 178-186.
38	Baran T, Wojtyla S, Dibenedetto A, et al. Zinc sulfide functionalized with ruthenium nanoparticles for photocatalytic reduction of CO₂ [J]. Appl. Catal. B-Environ., 2015, 178: 170-176.
39	Meng X G, Zuo G F, Zong P X, et al. A rapidly room-temperature-synthesized Cd/ZnS: Cu nanocrystal photocatalyst for highly efficient solar-light-powered CO₂ reduction [J]. Appl. Catal. B-Environ., 2018, 237: 68-73.
40	Primo A, He J B, Jurca B, et al. CO₂ methanation catalyzed by oriented MoS₂ nanoplatelets supported on few layers graphene [J]. Appl. Catal. B-Environ., 2019, 245: 351-359.
41	Akple M S, Low J, Wageh S, et al. Enhanced visible light photocatalytic H₂-production of g-C₃N₄/WS₂ composite heterostructures [J]. Applied Surface Science, 2015, 358: 196-203.
42	Tian N, Zhang Y H, Li X W, et al. Precursor-reforming protocol to 3D mesoporous g-C₃N₄ established by ultrathin self-doped nanosheets for superior hydrogen evolution [J]. Nano Energy, 2017, 38: 72-81.
43	Mondelli C, Puertolas B, Ackermann M, et al. Enhanced base-free formic acid production from CO₂ on Pd/g-C₃N₄ by tuning of the carrier defects [J]. ChemSusChem, 2018, 11(17): 2859-2869.
44	Adekoya D O, Tahir M, Amin N A S. g-C₃N₄/(Cu/TiO₂) nanocomposite for enhanced photoreduction of CO₂ to CH₃OH and HCOOH under UV/visible light [J]. Journal of CO₂ Utilization, 2017, 18: 261-274.
45	Wang Y L, Tian Y, Yan L K, et al. DFT study on sulfur-doped g-C₃N₄ nanosheets as a photocatalyst for CO₂ reduction reaction [J]. J. Phys. Chem. C, 2018, 122(14): 7712-7719.
46	Wang F, Ye Y H, Cao Y H, et al. The favorable surface properties of heptazine based g-C₃N₄ (001) in promoting the catalytic performance towards CO₂ conversion [J]. Applied Surface Science, 2019, 481: 604-610.
47	Low J, Yu J, Ho W. Graphene-based photocatalysts for CO₂ reduction to solar fuel [J]. The Journal of Physical Chemistry Letters, 2015, 6(21): 4244-4251.
48	Ahmed G, Raziq F, Hanif M, et al. Oxygen-cluster-modified anatase with graphene leads to efficient and recyclable photo-catalytic conversion of CO₂ to CH₄ supported by the positron annihilation study[J]. Scientific Reports, 2019, 9(1): 1-8.
49	Wang S L, Xu M, Peng T Y, et al. Porous hypercrosslinked polymer-TiO₂-graphene composite photocatalysts for visible-light-driven CO₂ conversion [J]. Nat. Commun, 2019, 10(1): 676.
50	Hou S L, Dong J, Zhao B. Formation of C—X bonds in CO₂ chemical fixation catalyzed by metal-organic frameworks[J]. Advanced Materials, 2020, 32(3): 1806163.
51	Ye J Y, Johnson J K. Design of Lewis pair-functionalized metal organic frameworks for CO₂ hydrogenation[J]. ACS Catalysis, 2015, 5(5): 2921-2928.
52	Jia J, brien P G O, He L, et al. Visible and near-infrared photothermal catalyzed hydrogenation of gaseous CO₂ over nanostructured Pd@Nb₂O₅ [J]. Advanced Science, 2016, 3(10): 1600189.
53	Chen G, Gao R, Zhao Y, et al. Alumina-supported CoFe alloy catalysts derived from layered-double-hydroxide nanosheets for efficient photothermal CO₂ hydrogenation to hydrocarbons[J]. Advanced Materials, 2018, 30(3): 1704663.
54	Li J, Ye Y H, Ye L Q, et al. Sunlight induced photo-thermal synergistic catalytic CO₂ conversion via localized surface plasmon resonance of MoO_3-_x [J]. J. Mater. Chem. A, 2019, 7(6): 2821-2830.
55	Wang L, Liu X X, Dang Y L, et al. Enhanced solar induced photo-thermal synergistic catalytic CO₂ conversion by photothermal material decorated TiO₂ [J]. Solid. State. Sci., 2019, 89: 67-73.
56	Meng X, Wang T, Liu L, et al. Photothermal conversion of CO₂ into CH₄ with H₂ over Group VIII nanocatalysts: an alternative approach for solar fuel production [J]. Angewandte Chemie, 2014, 53(43): 11478-11482.
57	Ren J, Ouyang S, Xu H, et al. Targeting activation of CO₂ and H₂ over Ru-loaded ultrathin layered double hydroxides to achieve efficient photothermal CO₂ methanation in flow-type system[J]. Advanced Energy Materials, 2017, 7(5): 1601657.
58	Zhao F G, Fan L L, Xu K J, et al. Hierarchical sheet-like Cu/Zn/Al nanocatalysts derived from LDH/MOF composites for CO₂ hydrogenation to methanol[J]. Journal of CO₂ Utilization, 2019, 33: 222-232.
59	Zhu D D, Liu J L, Qiao S Z. Recent advances in inorganic heterogeneous electrocatalysts for reduction of carbon dioxide[J]. Advanced Materials, 2016, 28(18): 3423-3452.
60	Hjorth I, Nord M, Nning M R, et al. Electrochemical reduction of CO₂ to synthesis gas on CNT supported Cu_xZn_1-_xO catalysts[J]. Catalysis Today, 2019, DOI: 10.1016/j.cattod.2019.02.045. DOI URL
61	Nielsen D U, Hu X M, Daasbjerg K, et al. Chemically and electrochemically catalysed conversion of CO₂ to CO with follow-up utilization to value-added chemicals[J]. Nature Catalysis, 2018, 1(4): 244-254.
62	Zhu S, Jiang B, Cai W B, et al. Direct observation on reaction intermediates and the role of bicarbonate anions in CO₂ electrochemical reduction reaction on Cu surfaces[J]. Journal of the American Chemical Society, 2017, 139(44): 15664-15667.
63	Luo W, Nie X, Janik M J, et al. Facet dependence of CO₂ reduction paths on Cu electrodes [J]. ACS Catalysis, 2015, 6(1): 219-229.
64	Perez-Gallent E, Figueiredo M C, Calle-Vallejo F, et al. Spectroscopic observation of a hydrogenated CO dimer intermediate during CO reduction on Cu(100) electrodes [J]. Angewandte Chemie, 2017, 56(13): 3621-3624.
65	Jiao Y, Zheng Y, Chen P, et al. Molecular scaffolding strategy with synergistic active centers to facilitate electrocatalytic CO₂ reduction to hydrocarbon/alcohol[J]. Journal of the American Chemical Society, 2017, 139(49): 18093-18100.
66	Ma S, Sadakiyo M, Heima M, et al. Electroreduction of carbon dioxide to hydrocarbons using bimetallic Cu-Pd catalysts with different mixing patterns [J]. Journal of the American Chemical Society, 2017, 139(1): 47-50.
67	Kattel S, Yan B, Yang Y, et al. Optimizing binding energies of key intermediates for CO₂ hydrogenation to methanol over oxide-supported copper [J]. Journal of the American Chemical Society, 2016, 138(38): 12440-12450.
68	Ning H, Wang X, Wang W, et al. Cubic Cu₂O on nitrogen-doped carbon shells for electrocatalytic CO₂ reduction to C₂H₄ [J]. Carbon, 2019, 146: 218-223.
69	Nolan M. Adsorption of CO₂ on heterostructures of Bi₂O₃ nanocluster-modified TiO₂ and the role of reduction in promoting CO₂ activation [J]. ACS Omega., 2018, 3(10): 13117-13128.
70	Zhai L N, Cui C N, Zhao Y T, et al. Titania-modified silver electrocatalyst for selective CO₂ reduction to CH₃OH and CH₄ from DFT study [J]. J. Phys. Chem. C, 2017, 121(30): 16275-16282.
71	Yang X F, Kattel S, Senanayake S D, et al. Low pressure CO₂ hydrogenation to methanol over gold nanoparticles activated on a CeO_x/TiO₂ interface [J]. Journal of the American Chemical Society, 2015, 137(32): 10104-10107.
72	Kangvansura P, Chew L M, Kongmark C, et al. Effects of potassium and manganese promoters on nitrogen-doped carbon nanotube-supported iron catalysts for CO₂ hydrogenation [J]. Engineering, 2017, 3(3): 385-392.
73	Castelo-Quibén J, Bailón-García E, Pérez-Fernández F J, et al. Mesoporous carbon nanospheres with improved conductivity for electro-catalytic reduction of O₂ and CO₂[J]. Carbon, 2019, 155: 88-99.
74	Wang W, Chu W, Wang N, et al. Mesoporous nickel catalyst supported on multi-walled carbon nanotubes for carbon dioxide methanation [J]. International Journal of Hydrogen Energy, 2016, 41(2): 967-975.
75	Li J, Zhou Y, Xiao X, et al. Regulation of Ni-CNT interaction on Mn-promoted nickel nanocatalysts supported on oxygenated CNTs for CO₂ selective hydrogenation [J]. ACS Applied Materials & Interfaces, 2018, 10(48): 41224-41236.
76	Nguyen L T M, Park H, Banu M, et al. Catalytic CO₂ hydrogenation to formic acid over carbon nanotube-graphene supported PdNi alloy catalysts [J]. RSC Adv., 2015, 5(128): 105560.
77	Din I U, Shaharun M S, Naeem A, et al. Carbon nanofiber-based copper/zirconia catalyst for hydrogenation of CO₂ to methanol [J]. Journal of CO₂ Utilization, 2017, 21: 145-155.
78	Roldan L, Marco Y, Garcia-Bordeje E. Origin of the excellent performance of Ru on nitrogen-doped carbon nanofibers for CO₂ hydrogenation to CH₄ [J]. ChemSusChem., 2017, 10(6): 1139-1144.
79	Castelo-Quibén J, Elmouwahidi A, Maldonado-Hódar F, et al. Metal-carbon-CNF composites obtained by catalytic pyrolysis of urban plastic residues as electro-catalysts for the reduction of CO₂ [J]. Catalysts, 2018, 8(5): 198-209.
80	Díaz J A, Romero A, García-Minguillán A M, et al. Carbon nanofibers and nanospheres-supported bimetallic (Co and Fe) catalysts for the Fischer–Tropsch synthesis [J]. Fuel Processing Technology, 2015, 138: 455-462.
81	Zhang C H, Yang S Z, Wu J J, et al. Electrochemical CO₂ reduction with atomic iron-dispersed on nitrogen-doped graphene [J]. Advanced Energy Materials, 2018, 8(19): 1703487.
82	Rogers C, Perkins W S, Veber G, et al. Synergistic enhancement of electrocatalytic CO₂ reduction with gold nanoparticles embedded in functional graphene nanoribbon composite electrodes [J]. Journal of the American Chemical Society, 2017, 139(11): 4052-4061.
83	Huang J, Guo X, Wei Y, et al. A renewable, flexible and robust single layer nitrogen-doped graphene coating Sn foil for boosting formate production from electrocatalytic CO₂ reduction [J]. Journal of CO₂ Utilization, 2019, 33: 166-170.
84	Han P, Yu X, Yuan D, et al. Defective graphene for electrocatalytic CO₂ reduction [J]. Journal of Colloid and Interface Science, 2019, 534: 332-357.
85	Wu J J, Liu M J, Sharma P P, et al. Incorporation of nitrogen defects for efficient reduction of CO₂via two-electron pathway on three-dimensional graphene foam [J]. Nano Letters, 2016, 16(1): 466-470.
86	Bhatia S K, Bhatia R K, Jeon J M, et al. Carbon dioxide capture and bioenergy production using biological system—a review [J]. Renew. Sust. Energ. Rev., 2019, 110: 143-158.
87	Wang Y Z, Li M F, Zhao Z P, et al. Effect of carbonic anhydrase on enzymatic conversion of CO₂ to formic acid and optimization of reaction conditions [J]. J. Mol. Catal. B-Enzym., 2015, 116: 89-94.
88	Lee L C, Xing X, Zhao Y. Environmental engineering of Pd nanoparticle catalysts for catalytic hydrogenation of CO₂ and bicarbonate [J]. ACS Applied Materials & Interfaces, 2017, 9(44): 38436-38344.
89	Nielsen C F, Lange L, Meyer A S. Classification and enzyme kinetics of formate dehydrogenases for biomanufacturing via CO₂ utilization [J]. Biotechnology Advances, 2019, 37(7): 107408.
90	Yu X. Conversion of carbon dioxide to formate by a formate dehydrogenase from Cupriavidus necator[D/OL]. UC Riverside, 2018. https: //escholarship.org/uc/item/1vn4h6xj.
91	Shiekh B A, Kaur D, Kumar S. Bio-mimetic self-assembled computationally designed catalysts of Mo and W for hydrogenation of CO₂/dehydrogenation of HCOOH inspired by the active site of formate dehydrogenase [J]. Phys. Chem. Chem. Phys., 2019, 21(38): 21370-21380.
92	Piazzetta P, Marino T, Russo N, et al. Direct hydrogenation of carbon dioxide by an artificial reductase obtained by substituting rhodium for zinc in the carbonic anhydrase catalytic center. A mechanistic study [J]. ACS Catalysis, 2015, 5(9): 5397-5409.
93	Chen X, Yang X. Bioinspired design and computational prediction of iron complexes with pendant amines for the production of methanol from CO₂ and H₂ [J]. The Journal of Physical Chemistry Letters, 2016, 7(6): 1035-1041.
94	Dubey A, Nencini L, Fayzullin R R, et al. Bio-inspired Mn(I) complexes for the hydrogenation of CO₂ to formate and formamide [J]. ACS Catalysis, 2017, 7(6): 3864-3868.
95	Yang L, Wang H, Zhang N, et al. The reduction of carbon dioxide in iron biocatalyst catalytic hydrogenation reaction: a theoretical study [J]. Dalton Transactions, 2013, 42(31): 11186-11193.
96	Mourato C, Martins M, Da Silva S M, et al. A continuous system for biocatalytic hydrogenation of CO₂ to formate [J]. Bioresource Technology, 2017, 235: 149-156.
97	Blanchet E, Vahlas Z, Etcheverry L, et al. Coupled iron-microbial catalysis for CO₂ hydrogenation with multispecies microbial communities [J]. Chemical Engineering Journal, 2018, 346: 307-316.
98	Roger M, Brown F, Gabrielli W, et al. Efficient hydrogen- dependent carbon dioxide reduction by Escherichia coli [J]. Curr. Biol., 2018, 28(1): 140-145.
99	Luo J, Meyer A S, Mateiu R V, et al. Cascade catalysis in membranes with enzyme immobilization for multi-enzymatic conversion of CO₂ to methanol [J]. New Biotechnology, 2015, 32(3): 319-327.
100	Schlager S, Fuchsbauer A, Haberbauer M, et al. Carbon dioxide conversion to synthetic fuels using biocatalytic electrodes [J]. J. Mater. Chem. A, 2017, 5(6): 2429-2443.
101	Kuk S K, Gopinath K, Singh R K, et al. NADH-free electroenzymatic reduction of CO₂ by conductive hydrogel-conjugated formate dehydrogenase [J]. ACS Catalysis, 2019, 9(6): 5584-5589.
102	Jang J, Jeon B W, Kim Y H. Bioelectrochemical conversion of CO₂ to value added product formate using engineered Methylobacterium extorquens[J]. Scientific Reports, 2018, 8(1): 1-7.
103	Bertini F, Gorgas N, Stöger B, et al. Efficient and mild carbon dioxide hydrogenation to formate catalyzed by Fe (II) hydrido carbonyl complexes bearing 2, 6-(diaminopyridyl) diphosphine pincer ligands[J]. ACS Catalysis, 2016, 6(5): 2889-2893.
104	Bertini F, Glatz M, Gorgas N, et al. Carbon dioxide hydrogenation catalysed by well-defined Mn (I) PNP pincer hydride complexes[J]. Chemical Science, 2017, 8(7): 5024-5029.
105	Schieweck B G, Westhues N F, Klankermayer J. A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates[J]. Chemical Science, 2019, 10(26): 6519-6523.
106	刘昌俊, 郭秋婷, 叶静云, 等. 二氧化碳转化催化剂研究进展及相关问题思考[J]. 化工学报, 2016, 67(1): 6-13.
	Liu C J, Guo Q T, Ye J Y, et al. Perspective on catalyst investigation for CO₂ conversion and related issues[J]. CIESC Journal, 2016, 67(1): 6-13.
107	Zhao T, Ullah N, Hui Y, et al. Review of plasma-assisted reactions and potential applications for modification of metal-organic frameworks [J]. Frontiers of Chemical Science and Engineering, 2019, 13(3): 444-457.
108	郭得通, 丁红蕾, 潘卫国, 等. CO₂催化转化的研究现状及趋势[J]. 中国电机工程学报, 2019, 39(24): 7242-7252+7497.
	Guo D T, Ding H L, Pan W G, et al. Recent advances in catalyzed conversion and utilization of CO₂ [J]. Proceedings of the CSEE, 2019, 39(24): 7242-7252+7497.
109	Zeng Y, Tu X. Plasma-catalytic CO₂ hydrogenation at low temperatures[J]. IEEE Transactions on Plasma Science, 2016, 44(4): 405-411.
110	Chen H, Mu Y, Shao Y, et al. Nonthermal plasma (NTP) activated metal–organic frameworks (MOFs) catalyst for catalytic CO₂ hydrogenation[J]. AIChE Journal, 2020, 66(4): e16853.
111	Parastaev A, Hoeben W F L M, van Heesch B E J M, et al. Temperature-programmed plasma surface reaction: an approach to determine plasma-catalytic performance [J]. Applied Catalysis B: Environmental, 2018, 239: 168-177.
112	De Bie C, van Dijk J, Bogaerts A. CO₂ hydrogenation in a dielectric barrier discharge plasma revealed [J]. The Journal of Physical Chemistry C, 2016, 120(44): 25210-25224.
113	Aerts R, Somers W, Bogaerts A. Carbon dioxide splitting in a dielectric barrier discharge plasma: a combined experimental and computational study [J]. ChemSusChem, 2015, 8(4): 702-716.
114	Zhou A, Chen D, Ma C, et al. DBD plasma-ZrO₂ catalytic decomposition of CO₂ at low temperatures [J]. Catalysts, 2018, 8(7): 256-267.
115	Amouroux J, Cavadias S. Electrocatalytic reduction of carbon dioxide under plasma DBD process[J]. Journal of Physics D: Applied Physics, 2017, 50(46): 465501.
116	Ray D, Saha R. DBD plasma assisted CO₂ decomposition: influence of diluent gases[J]. Catalysts, 2017, 7(9): 244-255.
117	Zeng Y, Tu X. Plasma-catalytic hydrogenation of CO₂ for the cogeneration of CO and CH₄ in a dielectric barrier discharge reactor: effect of argon addition[J]. Journal of Physics D: Applied Physics, 2017, 50(18): 184004.
118	Li J, Sun Y, Wang B, et al. Effect of plasma on catalytic conversion of CO₂ with hydrogen over Pd/ZnO in a dielectric barrier discharge reactor [J]. Journal of Physics D: Applied Physics, 2019, 52(24): 244001.
119	Zhou R, Rui N, Fan Z, et al. Effect of the structure of Ni/TiO₂ catalyst on CO₂ methanation [J]. International Journal of Hydrogen Energy, 2016, 41(47): 22017-22025.
120	Heijkers S, Bogaerts A. CO₂ conversion in a gliding arc plasmatron: elucidating the chemistry through kinetic modeling [J]. The Journal of Physical Chemistry C, 2017, 121(41): 22644.
121	Zhang H, Li L, Li X D, et al. Warm plasma activation of CO₂ in a rotating gliding arc discharge reactor [J]. Journal of CO₂ Utilization, 2018, 27: 472-479.
122	Li L, Zhang H, Li X D, et al. Plasma-assisted CO₂ conversion in a gliding arc discharge: improving performance by optimizing the reactor design [J]. Journal of CO₂ Utilization, 2019, 29: 296-303.
123	Liu J B, Li X S, Liu J L, et al. Insight into gliding arc (GA) plasma reduction of CO₂ with H₂: GA characteristics and reaction mechanism[J]. Journal of Physics D: Applied Physics, 2019, 52(28): 284001.
124	Ananthanarasimhan J, Rao L, Shivapuji A M, et al. Characterization and applications of non-magnetic rotating gliding arc reactors—a brief review[J]. Frontiers in Advanced Materials Research, 2019, 1(1): 31-38.
125	Chen G, Britun N, Godfroid T, et al. An overview of CO₂ conversion in a microwave discharge: the role of plasma-catalysis [J]. Journal of Physics D: Applied Physics, 2017, 50(8): 084001.
126	Chen G, Britun N, Godfroid T, et al. Role of plasma catalysis in the microwave plasma‐assisted conversion of CO₂ [M]//Green Chemical Processing and Synthesis. Intech, 2017.
127	Belov I, VermeIiren V, Paulussen S, et al. Carbon dioxide dissociation in a microwave plasma reactor operating in a wide pressure range and different gas inlet configurations [J]. Journal of CO₂ Utilization, 2018, 24: 386-397.
128	De La Fuente J F, Moreno S H, Stankiewicz A I, et al. Reduction of CO₂ with hydrogen in a non-equilibrium microwave plasma reactor [J]. International Journal of Hydrogen Energy, 2016, 41(46): 21067-21077.
129	De La Fuente J F, Moreno S H, Stankiewicz A I, et al. On the improvement of chemical conversion in a surface-wave microwave plasma reactor for CO₂ reduction with hydrogen (the reverse water-gas shift reaction) [J]. International Journal of Hydrogen Energy, 2017, 42(18): 12943-12955.
130	Yang R L, Zhang D Y, Zhu K W, et al. In situ study of the conversion reaction of CO₂ and CO₂-H₂ mixtures in radio frequency discharge plasma[J]. Acta Physico-Chimica Sinica, 2019, 35(3): 292-298.
131	Huang Q, Zhang D, Wang D, et al. Carbon dioxide dissociation in non-thermal radiofrequency and microwave plasma [J]. Journal of Physics D: Applied Physics, 2017, 50(29): 294001.

催化剂	主要产物	产率/(μmol/(g·h))	选择性/%	文献
Pd/Ce-TiO₂	CH₄	73.5	—	[12]
TiO₂/Ti₃C₂	CH₄	4.4	—	[16]
SCN-H-Ni-TiO₂	CH₃CHO	11.3	—	[21]
Cu/plate ZnO/Al₂O₃	CH₃OH	—	72.7	[24]
Cu-g-C₃N₄-ZnO/Al₂O₃	CH₃OH	5730.0	—	[25]
Cu/ZnGa₂O₄–ZnO	CH₃OH	—	50.0	[26]
Cu/ZnO	CH₃OH	127.8	—	[27]
In₂O₃/ZrO₂	CH₃OH	—	100.0	[28]
In₂O₃-WO₃	CH₃OH	496.0	—	[29]
In₂O_3-_x(OH)_y	CH₃OH	60.0	50.0	[32]
Cu₃SnS₄	CH₄	14.0	80.0	[33]
CdV₂O₆	CH₄	1.0	—	[39]
CdS/CdV₂O₆	CH₄	2.8	—	[39]
2%Cd/ZnS:0.2%Cu	HCOOH	3.2	99.0	[41]
g-C₃N₄/(Cu/TiO₂)	CH₃OH	429.0	—	[51]
TiO₂/rGO	CH₄	49.0	—	[52]
HCP-TiO₂-FG	CH₄	27.6	87.4	[53]

催化剂	主要产物	产率/(μmol/(g·h))	选择性/%	文献
Pd/Ce-TiO₂	CH₄	73.5	—	[12]
TiO₂/Ti₃C₂	CH₄	4.4	—	[16]
SCN-H-Ni-TiO₂	CH₃CHO	11.3	—	[21]
Cu/plate ZnO/Al₂O₃	CH₃OH	—	72.7	[24]
Cu-g-C₃N₄-ZnO/Al₂O₃	CH₃OH	5730.0	—	[25]
Cu/ZnGa₂O₄–ZnO	CH₃OH	—	50.0	[26]
Cu/ZnO	CH₃OH	127.8	—	[27]
In₂O₃/ZrO₂	CH₃OH	—	100.0	[28]
In₂O₃-WO₃	CH₃OH	496.0	—	[29]
In₂O_3-_x(OH)_y	CH₃OH	60.0	50.0	[32]
Cu₃SnS₄	CH₄	14.0	80.0	[33]
CdV₂O₆	CH₄	1.0	—	[39]
CdS/CdV₂O₆	CH₄	2.8	—	[39]
2%Cd/ZnS:0.2%Cu	HCOOH	3.2	99.0	[41]
g-C₃N₄/(Cu/TiO₂)	CH₃OH	429.0	—	[51]
TiO₂/rGO	CH₄	49.0	—	[52]
HCP-TiO₂-FG	CH₄	27.6	87.4	[53]

催化剂	主要产物	产率/ (μmol/(g ·h))	选择性/%	文献
MoO_3-_x	CH₄	2.1	—	[54]
Ru/Al₂O₃	CH₄	—	99.2	[56]
Pd/Al₂O₃	CH₄	—	98.6	[56]
Ni/Al₂O₃	CH₄	—	99.0	[56]
CoFeAl-LDH-650	CH₄	—	60.6	[53]
Ru@FL-LDHs	CH₄	277000.0	99.3	[57]
CA-LDO	CH₃OH	—	40.0	[58]
CZA-LDO	CH₃OH	—	88.0	[58]

催化剂	主要产物	产率/ (μmol/(g ·h))	选择性/%	文献
MoO_3-_x	CH₄	2.1	—	[54]
Ru/Al₂O₃	CH₄	—	99.2	[56]
Pd/Al₂O₃	CH₄	—	98.6	[56]
Ni/Al₂O₃	CH₄	—	99.0	[56]
CoFeAl-LDH-650	CH₄	—	60.6	[53]
Ru@FL-LDHs	CH₄	277000.0	99.3	[57]
CA-LDO	CH₃OH	—	40.0	[58]
CZA-LDO	CH₃OH	—	88.0	[58]

催化剂	主要产物	法拉第效率(FE)/%	选择性/%	过电位/V	文献
Cu/ZrO₂	CH₃OH	—	28.3	—	[67]
Cu/TiO₂	CH₃OH	—	19.1	—	[67]
K/Mn/Fe/NCNT	CO	—	72.1	—	[72]
Cu-ZrO₂/CNFs	CH₃OH	—	67.0	—	[77]
5% Ru/NCNF	CH₄	—	99.0	—	[78]
2b-AuNP	CO	71	—	0.47	[82]
SL-NG@Sn	formate	92	—	-1.00	[83]

Recent advances in catalytic methods of CO₂ hydrogenation to clean energy

CO₂催化氢化制清洁能源的研究进展及趋势

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 14

References 131

Related Articles 15

Recommended Articles

Metrics

Comments

催化剂	主要产物	产率	TON	文献
50%-Pd@ICRM	HCOOH	—	204	[88]
Pd@ICRM	HCOOH	—	250	[88]
C. necator FdsABG	HCOOH	—	1.9	[90]
Mn₂(bipy)₂(CO)₆-DBU	HCOOH	98.0%	6250	[94]
D. desulfuricans	HCOOH	14000.0 μmol/(g·h)	—	[96]
microbial-FeCl₃	HCOOH	34.6 mg/(L·h)	—	[97]
PANi-ClFDH	HCOOH	1.4 μmol/(h·cm²)	—	[101]
Fe(PNP^H-iPr)(H)(CO)(Br)	HCOOH	98.0%	1220	[103]
Fe(PNP^Me-iPr)(H)(CO)(Br)	HCOOH	98.0%	9840	[103]
Fe(PNP^NMe-iPr)(H)2(CO)	HCOOH	>99.0%	10000	[104]
Mn(PNPNHiPr)(H)(CO)2	HCOOH	63.0%	31600	[104]
Ni(BF₄)₂/NP₃	HCOOH	—	4650710	[105]

类型	催化剂	主要产物	选择性/%	能源效率/%	CO₂转化率/%	文献
DBD	Mn/γ-Al₂O₃	CO	77.7		10.2	[109]
	PbTiO₃	CH₄	75	—	15.0	[111]
	ZrO₂ pellets	CO	95	7.0	52.1	[114]
	Ni/Al₂O₃-60% Ar	CH₄	7.6	2.2	56.1	[117]
	Pd/ZnO	CH₄; CO	—	—	32.5	[118]
GA	N₂：10%→95%	CO	—	12.0	12.7	[121]
MW	NiO/TiO₂(Ar-P)	CO	—	18.0	43.0	[126]
	(20000 Pa)	CO	—	23.0	38.0	[127]
	（H₂∶CO₂ = 1）	CO	100	—	60.0	[129]
	（H₂∶CO₂ = 3）	CO		6	80	[128]
RF	pure CO₂	CO	—	—	66.0	[130]
	25% H₂	CO	—	—	21.6	[130]
	91% H₂	CO	—	—	65.2	[130]

[1]	Tianyang YANG, Huiming ZOU, Hui ZHOU, Chunlei WANG, Changqing TIAN. Experimental investigation on heating performance of vapor-injection CO₂ heat pump for electric vehicles at -30℃ [J]. CIESC Journal, 2023, 74(S1): 272-279.
[2]	Baomin DAI, Qilong WANG, Shengchun LIU, Jianing ZHANG, Xinhai LI, Fandi ZONG. Thermodynamic performance analysis of combined cooling and heating system based on combination of CO₂ with the zeotropic refrigerant assisted subcooled [J]. CIESC Journal, 2023, 74(S1): 64-73.
[3]	Meisi CHEN, Weida CHEN, Xinyao LI, Shangyu LI, Youting WU, Feng ZHANG, Zhibing ZHANG. Advances in silicon-based ionic liquid microparticle enhanced gas capture and conversion [J]. CIESC Journal, 2023, 74(9): 3628-3639.
[4]	Yepin CHENG, Daqing HU, Yisha XU, Huayan LIU, Hanfeng LU, Guokai CUI. Application of ionic liquid-based deep eutectic solvents for CO₂ conversion [J]. CIESC Journal, 2023, 74(9): 3640-3653.
[5]	Feifei YANG, Shixi ZHAO, Wei ZHOU, Zhonghai NI. Sn doped In₂O₃ catalyst for selective hydrogenation of CO₂ to methanol [J]. CIESC Journal, 2023, 74(8): 3366-3374.
[6]	Yaxin CHEN, Hang YUAN, Guanzhang LIU, Lei MAO, Chun YANG, Ruifang ZHANG, Guangya ZHANG. Advances in enzyme self-immobilization mediated by protein nanocages [J]. CIESC Journal, 2023, 74(7): 2773-2782.
[7]	Xiaoling TANG, Jiarui WANG, Xuanye ZHU, Renchao ZHENG. Biosynthesis of chiral epichlorohydrin by halohydrin dehalogenase based on Pickering emulsion system [J]. CIESC Journal, 2023, 74(7): 2926-2934.
[8]	Guixian LI, Abo CAO, Wenliang MENG, Dongliang WANG, Yong YANG, Huairong ZHOU. Process design and evaluation of CO₂ to methanol coupled with SOEC [J]. CIESC Journal, 2023, 74(7): 2999-3009.
[9]	Lei MAO, Guanzhang LIU, Hang YUAN, Guangya ZHANG. Efficient preparation of carbon anhydrase nanoparticles capable of capturing CO₂ and their characteristics [J]. CIESC Journal, 2023, 74(6): 2589-2598.
[10]	Xiqing ZHANG, Yanting WANG, Yanhong XU, Shuling CHANG, Tingting SUN, Ding XUE, Lihong ZHANG. Effect of Mg content on isobutane dehydrogenation properties over nanosheets supported Pt-In catalysts [J]. CIESC Journal, 2023, 74(6): 2427-2435.
[11]	Hao WANG, Siyang TANG, Shan ZHONG, Bin LIANG. An investigation of the enhancing effect of solid particle surface on the CO₂ desorption behavior in chemical sorption process with MEA solution [J]. CIESC Journal, 2023, 74(4): 1539-1548.
[12]	Can YANG, Xueqi SUN, Minghua SHANG, Jian ZHANG, Xiangping ZHANG, Shaojuan ZENG. Research status and prospect of CO₂ absorption and separation by phase-change ionic liquid systems [J]. CIESC Journal, 2023, 74(4): 1419-1432.
[13]	Jianghuai ZHANG, Zhong ZHAO. Robust minimum covariance constrained control for C₃ hydrogenation process and application [J]. CIESC Journal, 2023, 74(3): 1216-1227.
[14]	Yin XU, Jie CAI, Lu CHEN, Yu PENG, Fuzhen LIU, Hui ZHANG. Advances in heterogeneous visible light photocatalysis coupled with persulfate activation for water pollution control [J]. CIESC Journal, 2023, 74(3): 995-1009.
[15]	Mengxin LIANG, Yan GUO, Shidong WANG, Hongwei ZHANG, Pei YUAN, Xiaojun BAO. Study on preparation of Pd catalyst supported on carbon nitride for the selective hydrogenation of SBS [J]. CIESC Journal, 2023, 74(2): 766-775.