CIESC Journal ›› 2022, Vol. 73 ›› Issue (1): 255-265.DOI: 10.11949/0438-1157.20211149
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Qianhao WANG1,2(),Lu ZHAO1(),Fulin SUN1,3,Kegong FANG1
Received:
2021-08-12
Revised:
2021-11-10
Online:
2022-01-18
Published:
2022-01-05
Contact:
Lu ZHAO
通讯作者:
赵璐
作者简介:
王乾浩(1994—),男,硕士研究生,基金资助:
CLC Number:
Qianhao WANG, Lu ZHAO, Fulin SUN, Kegong FANG. Production of syngas derived from H2S-CO2via synergy of ZSM-5 catalyst and non-thermal plasma[J]. CIESC Journal, 2022, 73(1): 255-265.
王乾浩, 赵璐, 孙付琳, 房克功. ZSM-5催化剂与低温等离子体协同转化H2S-CO2制合成气[J]. 化工学报, 2022, 73(1): 255-265.
Si/Al比 | 比表面积/(m2/g) | 介电常数ε |
---|---|---|
25 | 305 | 3.15 |
38 | 318 | 3.27 |
50 | 324 | 3.37 |
80 | 306 | 3.42 |
200 | 307 | 3.49 |
Table 1 Specific surface area and dielectric constant of ZSM-5 catalysts with various Si/Al molar ratios
Si/Al比 | 比表面积/(m2/g) | 介电常数ε |
---|---|---|
25 | 305 | 3.15 |
38 | 318 | 3.27 |
50 | 324 | 3.37 |
80 | 306 | 3.42 |
200 | 307 | 3.49 |
Si/Al比 | H2S转化率/% | CO2转化率/% |
---|---|---|
25 | 5.0 | 0.9 |
38 | 2.9 | 0.8 |
50 | 3.5 | 1.3 |
80 | 5.3 | 1.4 |
200 | 5.9 | 1.2 |
Table 2 The thermal conversion of H2S-CO2 in the presence of packing various ZSM-5 catalysts without non-thermal plasma
Si/Al比 | H2S转化率/% | CO2转化率/% |
---|---|---|
25 | 5.0 | 0.9 |
38 | 2.9 | 0.8 |
50 | 3.5 | 1.3 |
80 | 5.3 | 1.4 |
200 | 5.9 | 1.2 |
Fig.4 H2S-CO2 conversion as a function of SEI in the presence of packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml)
Fig.5 Gaseous product distributions, H2 and CO yields and H2/CO molar ratios in H2S-CO2 conversion with packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml)
Fig.6 Q-U Lissajous figures, discharge power and effective capacitance in H2S-CO2 conversion with packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml; input power 95 W)
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