Research progress of MOFs glass membranes in gas separation applications

doi:10.11949/0438-1157.20241230

Abstract

Abstract:

The advent of metal-organic frameworks (MOFs) glass materials serves to complement traditional MOFs materials effectively. With its unique melting characteristics and short-range ordered and long-range disordered ultra-microporous structure, it effectively avoids the intercrystalline defects in polycrystalline MOFs membranes and the incompatibility of phase interfaces in MOFs-based hybrid membranes, bringing new technical options to the field of gas separation membranes. The research history of MOFs glass materials is first reviewed, followed by a systematic summary of the preparation methods for MOFs glass. The latest advancements in the application of MOFs glass membranes in the field of gas separation are introduced. Finally, an analysis is conducted on the challenges faced by MOFs glass membranes in gas separation applications, and potential research directions and solutions are proposed.

Key words: MOFs glass, composite membrane, gas separation, pore regulation, synthesis, transport

摘要：

金属有机框架（metal organic frameworks，MOFs）玻璃材料的出现与传统的MOFs材料形成了良好互补，凭借其独特的熔融特性及短程有序、长程无序的超微孔结构，有效避免了多晶MOFs膜存在的晶间缺陷以及MOFs基杂化膜中相界面不兼容问题，为气体分离膜领域带来了新的技术选择。首先回顾了MOFs玻璃材料的研究历程，系统总结了MOFs玻璃的制备方法，介绍了MOFs玻璃膜在气体分离领域的最新研究进展，最后针对MOFs玻璃膜气体分离发展面临的问题进行了分析，并提出了潜在的研究方向和解决方案。

关键词: MOFs玻璃, 复合膜, 气体分离, 孔隙调控, 合成, 传递

CLC Number:

TQ 028.8

Haofan ZHAO, Haojie REN, Zongkai LIU, Guanying DONG, Yatao ZHANG. Research progress of MOFs glass membranes in gas separation applications[J]. CIESC Journal, 2025, 76(5): 2042-2054.

赵浩帆, 任豪杰, 刘宗凯, 董冠英, 张亚涛. MOFs玻璃膜在气体分离领域的研究进展[J]. 化工学报, 2025, 76(5): 2042-2054.

Figures/Tables 8

Fig.1 (a) Melting-quenching process of MOFs glass[13]; (b) Crystal structures of typical ZIFs glass precursors and corresponding melting temperature Tm and decomposition temperature Td

Fig.2 Schematic representation of solvothermal， ultrasonic， mechanical ball milling and electrochemical assisted synthesis methods

Fig.3 SEM images of ZIF-62 prepared by different methods

Fig. 4 (a) Schematic diagram of the ligand exchange process of ZIF-8[52]; (b) Schematic diagram of the ligand structure modification of UiO-67[53]

Fig.5 (a) EDXS patterns of ZIF-62 glass films[63]; (b) Single gas permeance as a function of gas kinetic diameter[63]; (c) SEM image of the cross-section of agZIF-62 glass films prepared by atomic layer deposition[65]; (d) SEM image of the cross-section of the corresponding ZIF-62 glass films prepared by electrochemical assisted method[51]; (e) CO2/N2 and (f) CO2/CH4 separation performance of electrochemically assisted method of preparation of glass films [51]

Fig.6 (a) Effect of PEI decomposition process on the formation of agfZIF-62[69]; (b) High-resolution TEM image of agfZIF-62[69]; (c) Comparison of gas separation performance of agfZIF-62 membrane[69]

Fig. 7 (a) Preparation process of CGC membranes[75]; (b) Modelling of transmembrane transport of C2H6 molecules[75]; (c) Gas separation properties of ag[(ZIF-62)1-X (ZIF-8) X ] membranes[75]

Fig. 8 (a) Cross-sectional SEM images of ZIF-62/PIM-1 [(1), (3)] and agZIF-62/PIM-1 [(2), (4)][44]; (b) Comparison of agZIF-62/PIM-1 performance[44]; (c) Cross-sectional SEM images of ZIF-62/PBI [(1), (3)] and agZIF-62/PBI [(2), (4)][80]; (d) Comparison of agZIF-62/PBI performance[80]

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