可控型季铵化降冰片烯衍生物阴离子交换膜的制备

doi:10.11949/j.issn.0438-1157.20151255

化工学报 ›› 2015, Vol. 66 ›› Issue (S2): 257-262.DOI: 10.11949/j.issn.0438-1157.20151255

可控型季铵化降冰片烯衍生物阴离子交换膜的制备

冯磊^1,2, 赵玉彬², 谢晓峰^2,3, 吕亚非¹

1. 北京化工大学材料科学与工程学院, 北京 100029;
2. 清华大学核能与新能源技术研究院, 北京 100084;
3. 清华大学汽车安全与节能国家重点实验室, 北京 100084

收稿日期:2015-07-03 修回日期:2015-07-12 出版日期:2015-08-31 发布日期:2015-08-31
通讯作者: 谢晓峰, 吕亚非
基金资助:
国家高技术研究发展计划项目(2012AA052201);汽车安全与节能国家重点实验室项目(KF14162)。

Preparation of tunable quaternary ammonium functionalized norbornene derivatives anion exchange membrane

FENG Lei^1,2, ZHAO Yubin², XIE Xiaofeng^2,3, LV Yafei¹

1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;
3. State Key laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China

Received:2015-07-03 Revised:2015-07-12 Online:2015-08-31 Published:2015-08-31
Supported by:
supported by the National High Technology Research and Development Program of China (2012AA052201) and State Key Laboratory of Automotive Safety and Energy (KF14162).

摘要/Abstract

摘要：

为了提高阴离子交换膜的离子传导率,本文以降冰片烯二酸酐为原材料,单体中引入两个官能团提高单位体积内离子交换容量制备了阴离子交换膜。通过Materials Studio(MS)软件计算反应能垒,分析判断双季铵化单体形成与否的可行性。模拟计算与实验结果表明:分子结构设计合理,实验方法可行。当单体与降冰片烯比例为1:2.5时,最高离子传导率σ达到65.21 mS·cm^-1,离子交换容量为2.56 mequiv·g^-1,吸水率为22.6%。

关键词: 阴离子交换膜, 降冰片烯, ROMP, 电导率, 模拟

Abstract:

In order to improve the anion-exchange membrane ion conductivity, an anion exchange membrane was prepared which the norbornene anhydride as a raw material monomer, two functional groups were introduced on the monomer for increasing the ion exchange capacity per unit volume.Materials Studio (MS) software was used to calculate energy barrier, analyze the feasibility of forming a judgment diquaternary monomers or not.Simulation and experimental results show that the molecular structure design and the experimental method is feasible.When the monomer and norbornene ratio of 1:2.5, the highest ionic conductivity σ reached 65.21 mS·cm^-1, an ion exchange capacity of 2.56 mequiv·g^-1, the water absorption was 22.6%.

Key words: anion exchange membrane, norbornene, ring-opening metathesis polymerization, conductivity, simulation

中图分类号:

TQ152

冯磊, 赵玉彬, 谢晓峰, 吕亚非. 可控型季铵化降冰片烯衍生物阴离子交换膜的制备[J]. 化工学报, 2015, 66(S2): 257-262.

FENG Lei, ZHAO Yubin, XIE Xiaofeng, LV Yafei. Preparation of tunable quaternary ammonium functionalized norbornene derivatives anion exchange membrane[J]. CIESC Journal, 2015, 66(S2): 257-262.

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可控型季铵化降冰片烯衍生物阴离子交换膜的制备

Preparation of tunable quaternary ammonium functionalized norbornene derivatives anion exchange membrane

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