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王佳琪(), 魏皓琦, 苟阿静, 刘佳兴, 周昕霖, 葛坤()
收稿日期:
2023-12-21
修回日期:
2024-03-05
出版日期:
2024-03-11
通讯作者:
葛坤
作者简介:
王佳琪(1988—),女,博士,副教授,jiaqiwang@hrbeu.edu.cn
基金资助:
Jiaqi WANG(), Haoqi WEI, Ajing GOU, Jiaxing LIU, Xinlin ZHOU, Kun GE()
Received:
2023-12-21
Revised:
2024-03-05
Online:
2024-03-11
Contact:
Kun GE
摘要:
气体水合物技术在海水淡化、水合物蓄冷、CO2封存等领域有着广阔的应用前景,水合物快速生成是制约水合物技术应用的关键问题之一。利用自主搭建的CO2水合物可视化生成实验装置进行了纳米流体中CO2水合物生成特性的实验研究,分析了纳米粒子对CO2水合物生成特性的影响。结果表明,与纯水相比,纳米流体体系中气体消耗量增加了2.17 mmol/mol,且诱导时间缩短了277.5 min。对不同种类的纳米流体中CO2水合物生成特性的研究发现,氧化铜纳米流体中水合物生成的诱导时间最短,只有179 min。氧化铜纳米流体对CO2水合物的促进存在一个最佳浓度,CO2水合物耗气量随着氧化铜纳米流体质量分数的增加先增加后减少。不同种类的纳米流体中CO2水合物生成过程中形态学图像存在较大差异。
中图分类号:
王佳琪, 魏皓琦, 苟阿静, 刘佳兴, 周昕霖, 葛坤. 纳米粒子作用下CO2水合物生成机理研究[J]. 化工学报, DOI: 10.11949/0438-1157.20231357.
Jiaqi WANG, Haoqi WEI, Ajing GOU, Jiaxing LIU, Xinlin ZHOU, Kun GE. Study on the formation mechanism of CO2 hydrate under the action of nanoparticles[J]. CIESC Journal, DOI: 10.11949/0438-1157.20231357.
不同纳米流体体系 | 去离子水体积/ml | 纳米粒子种类 | 纳米粒子质量/g |
---|---|---|---|
0.1%石墨纳米流体 | 50 | 石墨纳米粒子 | 0.05 |
0.08%石墨纳米流体 | 50 | 石墨纳米粒子 | 0.04 |
0.08%铜纳米流体 | 50 | 铜纳米粒子 | 0.04 |
0.08%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.04 |
0.04%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.02 |
0.06%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.03 |
0.1%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.05 |
表1 配制各纳米流体所需实验材料用量
Table 1 Prepare a scale of experimental materials required for each nanofluid
不同纳米流体体系 | 去离子水体积/ml | 纳米粒子种类 | 纳米粒子质量/g |
---|---|---|---|
0.1%石墨纳米流体 | 50 | 石墨纳米粒子 | 0.05 |
0.08%石墨纳米流体 | 50 | 石墨纳米粒子 | 0.04 |
0.08%铜纳米流体 | 50 | 铜纳米粒子 | 0.04 |
0.08%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.04 |
0.04%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.02 |
0.06%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.03 |
0.1%氧化铜纳米流体 | 50 | 氧化铜纳米粒子 | 0.05 |
图7 不同种类纳米粒子对水合物生成过程耗气量变化曲线的影响
Fig.7 Effect of different types of nanoparticles on the variation curve of gas consumption in the hydrate generation process
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