功能化碳微球能级的电化学表征

doi:10.3969/j.issn.0438-1157.2014.08.036

化工学报 ›› 2014, Vol. 65 ›› Issue (8): 3114-3121.DOI: 10.3969/j.issn.0438-1157.2014.08.036

功能化碳微球能级的电化学表征

闫翎鹏^1,2, 郝亚敏^1,2, 杨维佳^1,2, 杨永珍^1,3, 刘旭光^1,4, 许并社^1,3

1 新材料界面科学与工程教育部重点实验室太原理工大学, 山西太原 030024;
2 太原理工大学材料科学与工程学院, 山西太原 030024;
3 太原理工大学新材料工程技术研究中心, 山西太原 030024;
4 太原理工大学化学化工学院, 山西太原 030024

收稿日期:2013-10-17 修回日期:2014-02-17 出版日期:2014-08-05 发布日期:2014-08-05
通讯作者: 杨永珍，刘旭光
基金资助:
国家自然科学基金项目（21176169，51152001）；国家国际科技合作专项项目（2012DFR50460）；国家教育部博士点基金项目（20101402110007）；山西省科技创新重点团队项目（2012041011）；山西省回国留学人员科研资助项目（2012-038）；教育部长江学者与创新团队发展计划项目（IRT0972）。

Electrochemical characterization of energy level of functionalized carbon microspheres

YAN Lingpeng^1,2, HAO Yamin^1,2, YANG Weijia^1,2, YANG Yongzhen^1,3, LIU Xuguang^1,4, XU Bingshe^1,3

1 Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
2 School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
3 Research Center of Advanced Material Science and Technology, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
4 School of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

Received:2013-10-17 Revised:2014-02-17 Online:2014-08-05 Published:2014-08-05
Supported by:
supported by the National Natural Science Foundation of China (21176169, 51152001), the International Science & Technology Cooperation Program of China (2012DFR50460), the Ph.D. Programs Foundation of Ministry of Education of China (20101402110007), the Shanxi Provincial Key Innovative Research Team in Science and Technology (2012041011), the Research Projectsupported by Shanxi Scholarship Council of China (2012-038) and the Program for Changjiang Scholar and Innovative Research Team in University (IRT0972).

摘要/Abstract

摘要： 分别采用水热法和化学气相沉积（CVD）法，制备两种同粒径（约360 nm）的碳微球（CMSs），对CVD法制备的CMSs （CCMSs）用混酸溶液（浓硫酸：浓硝酸=3：1）进行酸化处理，在其表面引入含氧官能团，而水热法制备的CMSs（HCMSs）不作处理；然后在N，N'-二环己基碳二亚胺的作用下，用1，6-己二胺分别修饰两种CMSs。通过场发射扫描电子显微镜和傅里叶红外光谱仪对产物的形貌和结构进行表征分析，采用热重分析仪和电化学工作站对产物的热稳定性和能级结构进行表征分析，并用荧光分析仪对产物的光学性能进行表征分析。结果表明：两种CMSs都满足作为聚合物太阳能电池受体材料的能级要求，且胺化修饰可以提高CMSs的LUMO能级；HCMSs在形貌、溶剂中的分散性以及热稳定性等方面都优于CCMSs，比CCMSs更适合作聚合物太阳能电池的受体材料。

关键词: 纳米粒子, 水热, 太阳能, 电化学

Abstract: Two kinds of carbon microspheres (CMSs) were prepared by the hydrothermal method and chemical vapor deposition (CVD), the CMSs prepared by CVD (CCMSs) were oxidized by a mixture of concentrated sulfuric acid and nitric acid (volume ratio of 3:1) to improve their surface activity, while the CMSs prepared by the hydrothermal method (HCMSs) were used as obtained. Then, two kinds of CMSs reacted with1,6-hexanediamine to prepare aminated CMSs with N,N'-dicyclohexyl carbodiimide as condensation agent. The morphology and structure of products were characterized with field emission scanning electron microscopy and Fourier transform infrared spectrometry. The thermostability and energy level structure were characterized with thermogravimetry and electrochemical analysis, the optical properties were characterized with fluorescence analysis. Both CMSs met the requirement of energy level as receptor materials in polymer solar cell, and amination increased the LUMO energy level of CMSs. HCMSs was superior to CCMSs in morphology, dispersibility in solvents and thermal stability, so HCMSs could be more suitable for using as the receptor materials of polymer solar cell.

Key words: nanoparticles, hydrothermal, solar energy, electrochemistry

中图分类号:

TB332

闫翎鹏, 郝亚敏, 杨维佳, 杨永珍, 刘旭光, 许并社. 功能化碳微球能级的电化学表征[J]. 化工学报, 2014, 65(8): 3114-3121.

YAN Lingpeng, HAO Yamin, YANG Weijia, YANG Yongzhen, LIU Xuguang, XU Bingshe. Electrochemical characterization of energy level of functionalized carbon microspheres[J]. CIESC Journal, 2014, 65(8): 3114-3121.

参考文献 20

[1]	Wang Yanmin, Wei Wei, Liu Xin, Gu Yijie. Research progress on polymer heterojunction solar cells[J]. Solar Energy Materials and Solar Cells, 2012, 98: 129-145
[2]	Zhang Tianhui(张天慧), Piao Lingyu(朴玲钰), Zhao Suling(赵谡玲), Xu Zheng(徐征), Yang Lei(杨磊), Liu Xiangzhi(刘祥志), Ju Siting(鞠思婷). New progress in study of organic solar cell materials[J]. Journal of Chinese Journal of Organic Chemistry(有机化学), 2011, 31(2): 260-272
[3]	Yang Zhenglong(杨正龙), Bu Yilong(卜弋龙), Chen Qiuyun(陈秋云). High efficiency low band gap conjugated polymer materials for solar cells[J]. Progress in Chemistry(化学进展), 2011, 23(12): 2607-2616
[4]	Cai Wanzhu, Wang Ming, Zhang Jie, Wang Ergang, Yang Tingbing, He Chao, Moon Ji-Sun, Wu Hongbin, Gong Xiong, Cao Yong. Solvent effect leading to high performance of bulk heterojunction polymer solar cells by novel polysilafluorence derivatives[J]. The Journal of Chemical Physics C, 2011, 115(5): 2314-2319
[5]	Xu Bingshe, Han Peide, Liu Xuguang, Bao Huiqiang, Li Tianbao, Chen Mingwei, Hideki Ichinose. Theoretical investigation of the reflectivity of fullerene-(C60,C70)/AIN multilayers in UV region[J]. Solid State Communications, 2005, 133(6): 353-356
[6]	Zhang Zhuxia, Han Peide, Liu Xuguang, Zhao Junfu, Jia Husheng, Zeng Fangui, Xu Bingshe. First principle calculations of the electronic properties of the fullerene derivative as an electron acceptor in organic solar cells[J]. The Journal of Chemical Physics C, 2008, 112(48): 19158-19161
[7]	Yang Yongzhen(杨永珍). Surface Chemistry of Carbon Microbeads(碳微球表面化学)[M]. Beijing: Chemical Industry Press, 2012: 11-12
[8]	Yang Yongzhen(杨永珍), Song Jingjing(宋静静), Li Yong(李勇), Liu Xuguang(刘旭光), Xu Bingshe(许并社). Functional modification of carbon microspheres by 1,6-hexanediamine[J]. CIESC Journal (化工学报), 2012, 63(10): 3350-3357
[9]	Yang Yongzhen(杨永珍), Han Yanxing(韩艳星), Li Sha(李莎), Liu Hongyan(刘红艳), Liu Xuguang(刘旭光), Xu Bingshe(许并社). Surface modification of carbon microspheres by ionization[J]. CIESC Journal (化工学报), 2010, 61(10): 2662-2666
[10]	Hou Xianbing(侯宪兵), Ma Xiaoyan(马晓燕), Zhu Xiaobo(朱小波). Research progress of donor materials for application in polymer solar cells[J]. Polymer Bulletin(高分子通报), 2012(1): 88-95
[11]	Guo Xingmei, Yang Yongzhen, Zhao Xuexia, Liu Xuguang. Carbon spheres surface modification and dispersion in polymer matrix[J]. Applied Surface Science, 2012, 261: 159-165
[12]	Li Min, Li Wei, Liu Shouxin. Hydrothermal synthesis, characterization, and KOH activation of carbon spheres from glucose[J]. Carbohydrate Research, 2011, 346(8): 999-1004
[13]	Ratchahat S, Viriya-empikul N, Faungnawakij K, Charinpanitkul T, Soottitantawat A. Synthesis of carbon microspheres from starch by hydrothermal process[J]. Science Journal, 2010, 1(2): 40-45
[14]	Yang Yongzhen(杨永珍), Liu Weifeng(刘伟峰), Han Yanxing(韩艳星), Liu Xuguang(刘旭光), Xu Bingshe(许并社). Self-assembly film of functionalized carbon microsphere[J]. CIESC Journal(化工学报), 2011, 62(4): 1020-1026
[15]	Zhao Huijun(赵慧君), Yang Yongzhen(杨永珍), Liu Xuguang(刘旭光), Xu Bingshe(许并社). Preparation of surface molecularly imprinted matrix materials porous carbon microspheres from glucose by hydrothermal carbonization method[J]. China Science Paper(中国科技论文), 2012, 7(12): 898-903
[16]	Li Yongfang(李永舫). High efficiency conjugated polymer donor and fullerene derivative acceptor photovoltaic materials for polymer solar cells[J]. Polymer Bulletin(高分子通报), 2011(10): 33-49
[17]	Li Yunchao(李运超), Wen Jing(温婧), Liu Jinjin(刘进进), Jiang Feng(姜峰), Li Yongfang(李永舫). Electrochemical investigation of the bandgap structures and electronic properties of semiconductor nanocrystals[J]. Progress in Chemistry(化学进展), 2011, 23(11): 2215-2224
[18]	Ding Bangdong(丁邦东), Zhang Jimei(张积梅), Zhu Wenqing(朱文清), Zheng Xinyou(郑新友), Wu Youzhi(吴有智), Jiang Xueyin(蒋雪茵), Zhang Zhilin(张志林), Xu Shaohong(许少鸿). Convenient electrochemical method to determine the energy level of organic electroluminescent materials[J]. Chinese Journal of Luminescence(发光学报), 2003, 24(6): 606-611
[19]	Subbiah J, Amb C M, Irfan I, Gao Y, Reynolds J R, So F. High-efficiency inverted polymer solar cells with double interlayer[J]. Applied Materials and Interfaces, 2012, 4(2): 866-870
[20]	Li Gang, Zhu Rui, Yang Yang. Polymer solar cell[J]. Nature Photonics, 2012, 6: 153-161

功能化碳微球能级的电化学表征

Electrochemical characterization of energy level of functionalized carbon microspheres

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