活性碳纤维对水中喹啉的吸附性能

化工进展

活性碳纤维对水中喹啉的吸附性能

张培1，张小平1，方益民2，兰永辉3

1华南理工大学环境科学与工程学院，工业聚集区污染控制与生态修复教育部重点实验室，广东广州 510006； 2 广东省废物管理中心，广东广州 510308；3东江环保股份有限公司，广东深圳 518057

出版日期:2013-01-05 发布日期:2013-01-25

Adsorption characteristics of quinoline on activated carbon fiber

ZHANG Pei1，ZHANG Xiaoping1，FANG Yimin，LAN Yonghui3

1The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters，College of Environmental Science and Engineering，South China University of Technology，Guangzhou 510006，Guangdong，China；2 Guangdong Waste Mangement Center，Guangzhou 510308，Guangdong, China；3Dongjiang Environmental Co. Ltd.，Shenzhen 518057，Guangdong，China

Online:2013-01-05 Published:2013-01-25

摘要/Abstract

摘要： 采用活性碳纤维（activated carbon fiber，ACF）静态吸附模拟废水中的喹啉，考察了吸附时间、喹啉初始浓度、温度、pH值、有机物等对吸附速率与吸附行为的影响。结果表明，ACF对喹啉的吸附速率快，30 min内基本达到平衡，初始浓度较高时，最终吸附容量较大，达210 mg/g，低温和pH值小于7时，吸附效果较好，苯酚与喹啉产生竞争吸附，配水中的吸附行为能较好的符合Langmuir等温方程，吸附动力学符合准二级动力学模型，热力学参数ΔH0、ΔG0为负值，表明该吸附是一个自发的放热过程。本研究为环境功能材料ACF应用于工业化生产提供了理论依据，有必要在此基础上进行动态吸附实验以及实际焦化废水的吸附处理实验，同时ACF成本高及脱附再生等方面问题还有待进一步深入研究。

关键词: 活性碳纤维, 喹啉, 吸附, 动力学, 热力学

Abstract: The static adsorption of quinoline on activated carbon fiber (ACF) was studied. The factors effecting adsorption efficiency and behaviors such as time，quinoline does，temperature，pH and organic compound were investigated. The results show that quinoline adsorption capacity on ACF was up to 210 mg/g at higher concentration and adsorption efficiency decreased with an increase of temperature. It was found that ACF had good adsorption properties when pH<7. The presence of organic substances inhibits the sorption efficiency. The adsorption isotherms conform to Langmuir adsorption isotherm and the adsorption process fits a pseudo-second-order model. The sorption parameters ΔH0 and ΔG0 were both negative，so the adsorption is spontaneous and exothermic. Scientific basis is offered for environment function material ACF using in industrial production. Based on the experimental results，dynamic adsorption experiment and treatment of coke plant wastewater is necessary. In addition，the problem of the respect such as high cost and desorption regeneration of ACF remain to be further studied.

Key words: activated carbon fiber, quinoline, adsorption, kinetics, thermodynamics

张培1，张小平1，方益民2，兰永辉3. 活性碳纤维对水中喹啉的吸附性能[J]. 化工进展.

ZHANG Pei1，ZHANG Xiaoping1，FANG Yimin，LAN Yonghui3. Adsorption characteristics of quinoline on activated carbon fiber[J]. Chemical Industry and Engineering Progree.

[1]	杨欣, 王文, 徐凯, 马凡华. 高压氢气加注过程中温度特征仿真分析[J]. 化工学报, 2023, 74(S1): 280-286.
[2]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[3]	常明慧, 王林, 苑佳佳, 曹艺飞. 盐溶液蓄能型热泵循环特性研究[J]. 化工学报, 2023, 74(S1): 329-337.
[4]	金正浩, 封立杰, 李舒宏. 氨水溶液交叉型再吸收式热泵的能量及分析[J]. 化工学报, 2023, 74(S1): 53-63.
[5]	程成, 段钟弟, 孙浩然, 胡海涛, 薛鸿祥. 表面微结构对析晶沉积特性影响的格子Boltzmann模拟[J]. 化工学报, 2023, 74(S1): 74-86.
[6]	张化福, 童莉葛, 张振涛, 杨俊玲, 王立, 张俊浩. 机械蒸汽压缩蒸发技术研究现状与发展趋势[J]. 化工学报, 2023, 74(S1): 8-24.
[7]	肖明堃, 杨光, 黄永华, 吴静怡. 浸没孔液氧气泡动力学数值研究[J]. 化工学报, 2023, 74(S1): 87-95.
[8]	毕丽森, 刘斌, 胡恒祥, 曾涛, 李卓睿, 宋健飞, 吴翰铭. 粗糙界面上纳米液滴蒸发模式的分子动力学研究[J]. 化工学报, 2023, 74(S1): 172-178.
[9]	于宏鑫, 邵双全. 水结晶过程的分子动力学模拟分析[J]. 化工学报, 2023, 74(S1): 250-258.
[10]	范孝雄, 郝丽芳, 范垂钢, 李松庚. LaMnO₃/生物炭催化剂低温NH₃-SCR催化脱硝性能研究[J]. 化工学报, 2023, 74(9): 3821-3830.
[11]	杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH₃的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755.
[12]	胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765.
[13]	郑佳丽, 李志会, 赵新强, 王延吉. 离子液体催化合成2-氰基呋喃反应动力学研究[J]. 化工学报, 2023, 74(9): 3708-3715.
[14]	高燕, 伍鹏, 尚超, 胡泽君, 陈晓东. 基于双流体喷嘴的磁性琼脂糖微球的制备及其蛋白吸附性能探究[J]. 化工学报, 2023, 74(8): 3457-3471.
[15]	张曼铮, 肖猛, 闫沛伟, 苗政, 徐进良, 纪献兵. 危废焚烧处理耦合有机朗肯循环系统工质筛选与热力学优化[J]. 化工学报, 2023, 74(8): 3502-3512.