碳纳米管填充PDMS膜的渗透汽化性能

doi:10.3969/j.issn.0438-1157.2014.01.035

化工学报 ›› 2014, Vol. 65 ›› Issue (1): 271-278.DOI: 10.3969/j.issn.0438-1157.2014.01.035

碳纳米管填充PDMS膜的渗透汽化性能

韩小龙^1,2, 张杏梅^1,3, 马晓迅¹, 李继定²

1 西北大学化工学院, 陕西西安 710069;
2 清华大学化学工程系, 化学工程联合国家重点实验室, 北京 100084;
3 宝鸡文理学院化学化工学院, 陕西宝鸡 721013

收稿日期:2013-07-01 修回日期:2013-11-25 出版日期:2014-01-05 发布日期:2014-01-05
通讯作者: 韩小龙
作者简介:韩小龙（1976-），男，博士，讲师。
基金资助:
化学工程联合国家重点实验室开放课题项目（SKL-ChE-12A01）；国家高技术研究发展计划项目（2012AA03A607）；陕西省教育厅项目（2010JK408）；西北大学科研启动基金项目（PR13022）。

Pervaporation performance of carbon nanotube filled PDMS membranes

HAN Xiaolong^1,2, ZHANG Xingmei^1,3, MA Xiaoxun¹, LI Jiding²

1 School of Chemical Engineering, Northwest University, Xi'an 710069, Shaanxi, China;
2 State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
3 Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013, Shaanxi, China

Received:2013-07-01 Revised:2013-11-25 Online:2014-01-05 Published:2014-01-05
Supported by:
supported by the State Key Laboratory of Chemical Engineering（SKL-ChE-12A01）, the National High Technology Research and Development Program of China (2012AA03A607), and NWU Young Teachers Scientific Research Foundation (PR13022).

摘要/Abstract

摘要： 将碳纳米管（CNTs）填充到PDMS中制备出CNTs/PDMS杂化膜，并将其用于乙醇/水体系的分离，发现由多壁碳纳米管制备的膜分离性能优于单壁碳纳米管填充膜，在40℃下，进料乙醇浓度为5%（质量分数）时，膜的分离因子可由8.3提高到10.0，渗透通量为206.2 g·（m²·h）^-1；采用十二烷基三氯硅烷对多壁碳纳米管进行修饰，并对修饰前后碳纳米管的性能进行表征，研究表明修饰后碳纳米管表面形成疏水层，碳纳米管的疏水性增强；将修饰后的碳纳米管填充到PDMS中，可进一步提高杂化膜对乙醇的选择性，膜的分离因子可提高到11.3，渗透通量为130.9 g·（m²·h）^-1。

关键词: 膜, 分离, 渗透蒸发, 碳纳米管, 聚二甲基硅氧烷

Abstract: Single wall carbon nanotubes (SWNT), multiwall carbon nanotubes (MWNT) and dodecyltrichlorosilane modified MWNT were incorporated into polydimethylsiloxane (PDMS) for separation of ethanol/water mixture via pervaporation. The pervaporation results showed that separation performance of MWNT/PDMS hybrid membrane was better than that of SWNT/PDMS hybrid membrane. When MWNT/PDMS hybrid membranes were used to separate 5%(mass) ethanol aqueous solution at 40℃, a separation factor of 10.0 and total flux of 206.2 g·(m²·h)^-1 were observed. The pervaporation selectivity of MWNT/PDMS membrane could be effectively improved by dodecyltrichlorosilane modification, and the modified MWNT/PDMS hybrid membrane showed a separation factor of 11.3 and total flux of 130.9 g·(m²·h)^-1 for 5%(mass) ethanol feed concentration at 40℃.

Key words: membranes, separation, pervaporation, carbon nanotubes, PDMS

中图分类号:

TQ028.8

韩小龙, 张杏梅, 马晓迅, 李继定. 碳纳米管填充PDMS膜的渗透汽化性能[J]. 化工学报, 2014, 65(1): 271-278.

HAN Xiaolong, ZHANG Xingmei, MA Xiaoxun, LI Jiding. Pervaporation performance of carbon nanotube filled PDMS membranes[J]. CIESC Journal, 2014, 65(1): 271-278.

参考文献 21

[1]	Gryta M, Morawski A M, Tomaszewska M. Ethanol production inmembrane distillation bioreactor[J]. Catalysis Today, 2000, 56:15-165
[2]	Nakao S I, Saitoh F, Asakura T, Toda K, Kimura S. Continuous etanol extraction by pervaporation from a membrane bioreactor[J]. Journal of Membrance Science, 1987, 30:273-287
[3]	Yue Guojun(岳国君), Dong Hongxing(董红星), Liu Wenxin(刘文信), et al. Chemical engineering analysis of fuel ethanol process[J]. Chemical Industry and Engineering Progress (化工进展), 2011, 30(1):144-149
[4]	Qiu Chunsheng(邱春生), Jia Xiaoqiang(贾晓强), Wen Jianping(闻建平), et al. Progress in fuel ethanol production waste treatment and resource recovery[J]. Chemical Industry and Engineering Progress (化工进展), 2010, 29(9):1747-1766
[5]	Vane L M, Namboodiri V V, Bowen T C. Hydrophobic zeolite-silicone rubber mixed matrix membranes for ethanol-water separation: effect of zeolite and silicone component selection on pervaporation performance[J]. Journal of Membrane Science, 2008, 308(1/2): 230-241
[6]	Zhan X, Li J, Huang J, et al. Pervaporation properties of PDMS membranes cured with different cross-linking reagents for ethanol concentration from aqueous solutions[J]. Chinese Journal of Polymer Science, 2009, 27(4): 533-542
[7]	Han X L, Wang L, Li J D, Zhan X, Chen J, Yang J C. Separation of ethanol from ethanol/water mixtures by pervaporation with silicone rubber membranes:effect of silicone rubbers[J]. Journal of Applied Polymer Science, 2011, 119:3413-3421
[8]	Garcia M, Sanz M T, Beltran S. Separation by pervaporation of ethanol from aqueous solutions and effect of other components present in fermentation broths[J]. Journal of Chemical Technology and Biotechnol., 2009, 84: 1873-1882
[9]	Li Lei(李磊), Tan Shujuan(谭淑娟), Jiang Donghua(蒋冬华), et al. Influence of support layer of composite PDMS membranes on performance of hydrophobic pervaporation[J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2006, 57(1):61-65
[10]	Xu Lingfang(徐玲芳), Xiangli Fenjuan(相里粉娟), Chen Yiwei(陈祎纬), et al. Influence of simulated ethanol fermentation components on pervaporation performance of PDMS/ceramic composite membranes[J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2006, 57(1):1466-1472
[11]	Hou Dan(侯丹), Wei Wang(卫旺), Xia Shanshan(夏珊珊), et al. Influence of inorganic salts on pervaporation performance of PDMS/ceramic composite membranes[J]. CIESC Journal (化工学报), 2009, 60(2):389-393
[12]	Zhan X, Li J, Chen J, et al. Pervaporation of ethanol/water mixtures with high flux by zeolite-filled PDMS/PVDF composite membranes[J]. Chinese Journal of Polymer Science, 2009, 27(6): 771-780
[13]	Bai Yunxiang(白云翔), Yang Le(杨乐), Gu Jin(顾瑾), et al. ZSM-5-filled HTPB-based polyurethane membranes for pervaporation separation of isopropyl acetate/water mixtures[J]. Chemical Industry and Engineering Progress (化工进展), 2011, 30(9):1919-1925
[14]	Yi S, Su Y, Wan Y. Preparation and characterization of vinyltriethoxysilane (VTES) modified silicalite-1/PDMS hybrid pervaporation membrane and its application in ethanol separation from dilute aqueous solution[J]. Journal of Membrane Science, 2010, 360(1/2): 341-351
[15]	Gu Jin(顾瑾), Wang Anna(王安娜), Sun Yuping(孙余凭). Study of polyamide composite reverse osmosis membrane filled with modified silicalite-1[J]. Chemical Engineering (China) (化学工程), 2012, 40(6):72-76
[16]	Xu Guoqiang(徐国强), Yu Jiang(余江), Wang Kang(王康). Preparation of montmorillonite filled PDMS hybrid membrane and its pervaporation on ethanol over water[J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2007, 58(2):391-395
[17]	Huang Y, Zhang P, Fu J, et al. Pervaporation of ethanol aqueous solution by polydimethylsiloxane/polyphosphazene nanotube nanocomposite membranes[J]. Journal of Membrane Science, 2009, 339(1/2): 85-92
[18]	Peng F, Pan F, Sun H, et al. Novel nanocomposite pervaporation membranes composed of poly (vinyl alcohol) and chitosan-wrapped carbon nanotube[J]. Journal of Membrane Science, 2007, 300(1/2): 13-19
[19]	Peng F, Hu C, Jiang Z. Novel ploy (vinyl alcohol)/carbon nanotube hybrid membranes for pervaporation separation of benzene/ cyclohexane mixtures[J]. Journal of Membrane Science, 2007, 297(1/2): 236-242
[20]	Zhang Chao(张超), Guo Shuzhong(郭述忠), Wang Weizhi(汪伟志). Fluorinated multi-walled carbon nanotubes and fabrication of polyurethane composite films with hydrophobic surface[J]. Acta Chimica Sinica(化学学报), 2009(9): 1001-1007
[21]	Zhao Juan(赵娟). Contrast study of single-wall carbon nanotube synthesis by different condition[D]. Taiyuan:Taiyuan University of Technology, 2008

碳纳米管填充PDMS膜的渗透汽化性能

Pervaporation performance of carbon nanotube filled PDMS membranes

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