用于生物气提纯的促进传递膜

doi:10.3969/j.issn.0438-1157.2014.05.006

化工学报

用于生物气提纯的促进传递膜

田志章^1,2, 李奕帆^1,2, 姜忠义^1,2, 王少飞^1,2

1 天津化学化工协同创新中心, 天津 300072;
2 天津大学化工学院绿色合成与转化教育部重点实验室, 天津 300072

收稿日期:2013-12-29 修回日期:2014-03-22 出版日期:2014-05-05 发布日期:2014-05-05
通讯作者: 姜忠义
基金资助:
国家重点基础研究发展计划项目（2013CB733500）；国家高技术研究发展计划项目（2012AA03A611）；国家杰出青年科学基金项目（21125627）。

Facilitated transport membranes for biogas upgrading

TIAN Zhizhang^1,2, LI Yifan^1,2, JIANG Zhongyi^1,2, WANG Shaofei^1,2

1 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;
2 Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Received:2013-12-29 Revised:2014-03-22 Online:2014-05-05 Published:2014-05-05
Supported by:
supported by the National Basic Research Program of China (2013CB733500), the National High Technology Research and Development Program of China (2012AA03A611) and the National Science Fund for Distinguished Young Scholars (21125627).

摘要/Abstract

摘要： 由生物气提纯获得的生物甲烷具有高热值，可作为天然气的替代品。生物气中除主要成分甲烷以外还含有大量的CO₂和少量的水、H₂S以及其他痕量杂质组分，需经过净化提纯方可获得高纯度的生物甲烷。膜分离技术用于生物气提纯具有绿色、高效、能耗低等特点，特别地，促进传递膜因其特殊的传质机制，对于生物甲烷系统提纯具有显著优势。综述了促进传递膜材料及其制备技术，讨论了生物气中水、H₂S杂质对膜过程的影响，同时尝试对膜法生物气提纯的经济性和发展前景进行了分析。

关键词: 生物甲烷, 生物能源, 膜, 分离, 促进传递, 水, 硫化氢

Abstract: Biomethane, purified from biogas, can be utilized as substitute for natural gas owing to its high calorific value (HCV). Typically biogas contains 60%—65% CH₄, 35%—40% CO₂, small amounts of hydrogen sulfide, water vapor and trace amounts of other gases. Treatment of raw biogas must be implemented in order to convert biogas into HCV biomethane. Membrane separation process exhibits many distinct advantages, including low energy consumption, high efficiency, high process flexibility and environment friendliness. Particularly, facilitated transport membrane exhibits predominant features for biogas upgrading because of its unique transport mechanism. Materials for facilitated transport membrane and corresponding preparation methods/technologies are summarized. Influences of impurities, such as water and hydrogen sulfide on membrane separation as well as some techno- economic issues are discussed. Finally, prospects on membrane separation technology in biogas upgrading are presented.

Key words: biomethane, bioenergy, membrane, separation, facilitated transport, water, hydrogen sulfide

中图分类号:

TQ028.8

田志章, 李奕帆, 姜忠义, 王少飞. 用于生物气提纯的促进传递膜[J]. 化工学报, DOI: 10.3969/j.issn.0438-1157.2014.05.006.

TIAN Zhizhang, LI Yifan, JIANG Zhongyi, WANG Shaofei. Facilitated transport membranes for biogas upgrading[J]. CIESC Journal, DOI: 10.3969/j.issn.0438-1157.2014.05.006.

参考文献 38

[1]	Li Wei(李伟), Yang Yi(杨义), Liu Xiaojuan(刘晓娟). Current status and trends in natural gas consumption in China[J]. Sino-Global Energy(中外能源), 2010, 15: 8-12
[2]	Wu Chuangzhi(吴创之), Zhou Zhaoqiu(周肇秋), Yin Xiuli(阴秀丽), Yi Weiming(易维明). Current status of biomass energy development in China[J]. Transactions of the Chinese Society for Agricultural Machinery(农业机械学报), 2009, 40(1): 91-99
[3]	Basu S, Khan A L, Cano-Odena A, Liu C Q, Vankelecom I F J. Membrane-based technologies for biogas separations[J]. Chem. Soc. Rev., 2010, 39(2): 750-768
[4]	Ryckebosch E, Drouillon M, Vervaeren H. Techniques for transformation of biogas to biomethane[J]. Biomass & Bioenergy, 2011, 35: 1633-1645
[5]	Teng Yiwan(滕一万), Wu Fawen(武法文), Wang Hui(王辉), Li Lei(李磊), Zhang Zhibing(张志炳). Research progress of polymeric material of gas separation membrane for gas pair CO2/CH4[J]. Chemical Industry and Engineering Progress(化工进展), 2007, 26(8): 1075-1079
[6]	Zhang Y, Wang Z, Wang S C. Selective permeation of CO2 through new facilitated transport membranes[J]. Desalination, 2002, 145(1/2/3): 385-388
[7]	Ward W J, Robb W L. Carbon dioxide-oxygen separation: facilitated transport of carbon dioxide across a liquid film[J]. Science, 1967, 156: 1481-1484
[8]	Matson S L, Lopez J, Quinn J A. Separation of gases with synthetic membrane[J]. Chem. Eng. Sci., 1983, 38: 503-504
[9]	Meldon J H, Stroeve P, Gregoire C E. Facilitated transport of carbon dioxide, a review[J]. Chem. Eng. Commun., 1982, 16: 263-300
[10]	Zhang Ying(张颖). Studies on the preparation and performance of fixed carrier composite membrane for removal of CO2 from CH4 [D]. Tianjin: Tianjin University, 2002
[11]	Wang Zhi(王志), Yuan Fang(袁芳), Wang Ming(王明), Wang Jixiao(王纪孝), Wang Shichang(王世昌). Membranes for carbon dioxide separation[J]. Membrane Science and Technology(膜科学与技术), 2011, 31(3): 11-17
[12]	Wang Zhi(王志), Zhang Lili(张莉莉), Zhang Ying(张颖), Wang Shichang(王世昌). Facilitated transport membranes for CO2 separation[J]. Membrane Science and Technology(膜科学与技术), 2003, 23(4): 166-171
[13]	Yi Chunhai(伊春海). The effects of casting temperature and humidity on the structure and performance of fixed carrier composite membrane for CO2 separation [D]. Tianjin: Tianjin University, 2014
[14]	Sandru M, Kim T J, Hagg M B. High molecular fixed-site-carrier PVAm membrane for CO2 capture[J]. Desalination, 2009, 240(1/2/3): 298-300
[15]	Kim T J, Vralstad H, Sandru M, Hagg M B. Separation performance of PVAm composite membrane for CO2 capture at various pH levels[J]. J. Membr. Sci., 2013, 428: 218-224
[16]	Deng L Y, Kim T J, Hagg M B. Facilitated transport of CO2 in novel PVAm/PVA blend membrane[J]. J. Membr. Sci., 2009, 340(1/2): 154-163
[17]	Yuan S, Wang Z, Qiao Z, Wang M, Wang J, Wang S. Improvement of CO2/N2 separation characteristics of polyvinylamine by modifying with ethylenediamine[J]. J. Membr. Sci., 2011, 378(1/2): 425-437
[18]	Qiao Z, Wang Z, Zhang C, Yuan S, Zhu Y, Wang J, Wang S. PVAm-PIP/PS composite membrane with high performance for CO2/N2 separation[J]. AIChE J., 2013, 59(1): 215-228
[19]	Li S, Wang Z, Yu X, Wang J, Wang S. High-performance membranes with multi-permselectivity for CO2 separation[J]. Adv. Mater., 2012, 24(24): 3196-3200
[20]	Wang M, Wang Z, Li S, Zhang C, Wang J, Wang S. A high performance antioxidative and acid resistant membrane prepared by interfacial polymerization for CO2 separation from flue gas[J]. Energy Environ. Sci., 2013, 6(2): 539-551
[21]	Huang H, Zhang W, Liu D, Zhong C. Understanding the effect of trace amount of water on CO2 capture in natural gas upgrading in metal-organic frameworks: a molecular simulation study[J]. Ind. Eng. Chem. Res., 2012, 51(30): 10031-10038
[22]	Klaehn J R, Orme C J, Stewart F F, Peterson E S. Humidified gas stream separations at high temperatures using Matrimid 5218[J]. Sep. Sci. Technol., 2012, 47(14/15): 2186-2191
[23]	Chen G Q, Scholes C A, Qiao G G, Kentish S E. Water vapor permeation in polyimide membranes[J]. J. Membr. Sci., 2011, 379(1/2): 479-487
[24]	Liu L, Chakma A, Feng X. Gas permeation through water-swollen hydrogel membranes[J]. J. Membr. Sci., 2008, 310(1/2): 66-75
[25]	El-Azzami L A, Grulke E A. Parametric study of CO2 fixed carrier facilitated transport through swollen chitosan membranes[J]. Ind. Eng. Chem. Res., 2008, 48(2): 894-902
[26]	Cooley T E, Coady A B. Removal of H2S and/or CO2 from a light hydrocarbon stream by use of gas permeable membrane[P]: US, 4130403. 1978-12-19
[27]	Stem S A, Kawakami H, Houde A Y, Zhou G. Material and process for separating carbon dioxide from methane[P]: US, 5591250. 1997-01-07
[28]	Chatterjee G, Houde A A, Stern S A. Poly(ether urethane) and poly(ether urethane urea) membranes with high H2S/CH4 selectivity [J]. J. Membr. Sci., 1997, 135: 479-487
[29]	Uddin M W, Hagg M B. Natural gas sweetening—the effect on CO2-CH4 separation after exposing a facilitated transport membrane to hydrogen sulfide and higher hydrocarbons[J]. J. Membr. Sci., 2012, 423(1/2): 143-149
[30]	Deng L, Hagg M B. Swelling behavior and gas permeation performance of PVAm/PVA blend FSC membrane[J]. J. Membr. Sci., 2010, 363: 295-301
[31]	Rasi S, Veijanen A, Rintala J. Trace compounds of biogas from different biogas production plants[J]. Energy, 2007, 32(8): 1375-1380
[32]	Kim T J, Uddin M W, Sandru M, Hagg M B. The effect of contaminants on the composite membranes for CO2 separation and challenges in up-scaling of the membranes[J]. Energy Proc., 2011, 4: 737-744
[33]	Al-Juaied M, Koros W J. Performance of natural gas membranes in the presence of heavy hydrocarbons[J]. J. Membr. Sci., 2006, 274: 227-243
[34]	Deng L, Hagg M B. Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane[J]. Int. J. Greenh. Gas. Con., 2010, 4: 638-646
[35]	Makaruk A, Miltner M, Harasek M. Membrane biogas upgrading processes for the production of natural gas substitute[J]. Sep. Purif. Technol., 2010, 74: 83-92
[36]	Hao J, Rice P A, Stern S A. Upgrading low-quality natural gas with H2S- and CO2-selective polymer membranes(Ⅰ): Process design and economics of membrane stages without recycle streams[J]. J. Membr. Sci., 2002, 209(1): 177-206
[37]	Hao J, Rice P A, Stern S A. Upgrading low-quality natural gas with H2S- and CO2-selective polymer membranes(Ⅱ): Process design, economics, and sensitivity study of membrane stages with recycle streams[J]. J. Membr. Sci., 2008, 320(1/2): 108-122
[38]	Harasimowicz M, Orluk P, Zakrzewska-Trznadel G, Chmielewski A G. Application of polyimide membranes for biogas purification and enrichment[J]. J. Hazard. Mater., 2007, 144: 698-702

用于生物气提纯的促进传递膜

Facilitated transport membranes for biogas upgrading

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 38

相关文章 15

编辑推荐

Metrics

本文评价

[1]	吴馨, 龚建英, 靳龙, 王宇涛, 黄睿宁. 超声波激励下铝板表面液滴群输运特性的研究[J]. 化工学报, 2023, 74(S1): 104-112.
[2]	苏伟, 马东旭, 金旭, 刘忠彦, 张小松. 表面润湿性对霜层传递特性影响可视化实验研究[J]. 化工学报, 2023, 74(S1): 122-131.
[3]	邵苛苛, 宋孟杰, 江正勇, 张旋, 张龙, 高润淼, 甄泽康. 水平方向上冰中受陷气泡形成和分布实验研究[J]. 化工学报, 2023, 74(S1): 161-164.
[4]	于宏鑫, 邵双全. 水结晶过程的分子动力学模拟分析[J]. 化工学报, 2023, 74(S1): 250-258.
[5]	吴延鹏, 李晓宇, 钟乔洋. 静电纺丝纳米纤维双疏膜油性细颗粒物过滤性能实验分析[J]. 化工学报, 2023, 74(S1): 259-264.
[6]	连梦雅, 谈莹莹, 王林, 陈枫, 曹艺飞. 地下水预热新风一体化热泵空调系统制热性能研究[J]. 化工学报, 2023, 74(S1): 311-319.
[7]	黄琮琪, 吴一梅, 陈建业, 邵双全. 碱性电解水制氢装置热管理系统仿真研究[J]. 化工学报, 2023, 74(S1): 320-328.
[8]	吴迪, 胡斌, 王如竹, 梁俊宇. 水蒸气准饱和压缩高温热泵循环性能分析[J]. 化工学报, 2023, 74(S1): 45-52.
[9]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[10]	杨百玉, 寇悦, 姜峻韬, 詹亚力, 王庆宏, 陈春茂. 炼化碱渣湿式氧化预处理过程DOM的化学转化特征[J]. 化工学报, 2023, 74(9): 3912-3920.
[11]	赵亚欣, 张雪芹, 王荣柱, 孙国, 姚善泾, 林东强. 流穿模式离子交换层析去除单抗聚集体[J]. 化工学报, 2023, 74(9): 3879-3887.
[12]	陈哲文, 魏俊杰, 张玉明. 超临界水煤气化耦合SOFC发电系统集成及其能量转化机制[J]. 化工学报, 2023, 74(9): 3888-3902.
[13]	胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765.
[14]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[15]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.