GO/PEDOT复合材料修饰阳极的制备及其在MFC中的应用

doi:10.11949/j.issn.0438-1157.20160595

化工学报 ›› 2016, Vol. 67 ›› Issue (10): 4406-4412.DOI: 10.11949/j.issn.0438-1157.20160595

GO/PEDOT复合材料修饰阳极的制备及其在MFC中的应用

霍庆城¹, 黄仁亮², 齐崴^1,3, 苏荣欣^1,3, 何志敏^1,3

1 天津大学化工学院, 化学工程研究所, 天津 300072;
2 天津大学环境科学与工程学院, 天津 300072;
3 化学工程联合国家重点实验室(天津大学), 天津 300072

收稿日期:2016-05-04 修回日期:2016-05-27 出版日期:2016-10-05 发布日期:2016-10-05
通讯作者: 齐崴, 黄仁亮
基金资助:
北洋青年学者计划项目（2012）。

Preparation and application of GO/PEDOT composite anode for MFC

HUO Qingcheng¹, HUANG Renliang², QI Wei^1,3, SU Rongxin^1,3, HE Zhimin^1,3

1 Chemical Engineering Research Institute, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China;
3 State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China

Received:2016-05-04 Revised:2016-05-27 Online:2016-10-05 Published:2016-10-05
Supported by:
supported by the Beiyang Young Scholar Program of Tianjin University (2012).

摘要/Abstract

摘要：

微生物燃料电池（MFC）是一种利用微生物将有机物中的化学能直接转化成电能的装置，通过改善阳极特性可以有效提高微生物燃料电池的产电性能。通过恒电流法电沉积制备了氧化石墨烯/聚3,4-乙烯二氧噻吩（GO/PEDOT）复合材料修饰碳毡（CF）阳极。通过循环伏安法和交流阻抗法考察了电极特性。将其应用到微生物燃料电池中，对其产电性能进行评价。结果表明，GO/PEDOT-CF电极具有较大的比表面积和优良的电化学性能；以GO/PEDOT-CF为阳极的微生物燃料电池，产电性能良好，其最大功率密度和最大电流密度达到1.138 W·m^-2和4.714 A·m^-2，分别是未修饰阳极的4.80倍和5.51倍。因此，GO/PEDOT复合材料是一种优良的阳极修饰材料，可有效提高MFC的产电性能。

关键词: 恒电流法, 复合材料, 电化学, 微生物燃料电池, 功率密度

Abstract:

A microbial fuel cell (MFC) is an innovative power output device. The properties of the anode is a critical factor for improving the performance of MFC. In this study, a graphene oxide/poly(3,4-ethylenedioxythiophene) (GO/PEDOT) composite was prepared and used for modification of carbon felt (CF) via the electrodeposition with constant current. The cyclic voltammetry and electrochemical impedance characteristics of the electrode were evaluated. Furthermore, the as-prepared anode was applied in MFC and its electrogenesis capacity was investigated. The results showed that the GO/PEDOT-CF electrode had a large specific surface area and good electrochemical performance. When the GO/PEDOT-CF anode was used in MFC, the maximum power density and current density were up to 1.138 W·m^-2 and 4.714 A·m^-2, respectively, which were 4.80 times and 5.51 times higher than those of unmodified anodes. These results demonstrated that the GO/PEDOT composite is a kind of effective anode materials for improving electricity generation of MFC.

Key words: constant current, composites, electrochemistry, microbial fuel cell, power density

中图分类号:

O646
X382

霍庆城, 黄仁亮, 齐崴, 苏荣欣, 何志敏. GO/PEDOT复合材料修饰阳极的制备及其在MFC中的应用[J]. 化工学报, 2016, 67(10): 4406-4412.

HUO Qingcheng, HUANG Renliang, QI Wei, SU Rongxin, HE Zhimin. Preparation and application of GO/PEDOT composite anode for MFC[J]. CIESC Journal, 2016, 67(10): 4406-4412.

参考文献 33

[1]	LOGAN B E, BERT H, REN R, et al. Microbial fuel cells:methodology and technology[J]. Environmental Science & Technology, 2006, 40(17):5181-5192.
[2]	BEHERA M, JANA P S, GHANGREKAR M M. Performance evaluation of low cost microbial fuel cell fabricated using earthen pot with biotic and abiotic cathode[J]. Bioresource Technology, 2010, 101(4):1183-1189.
[3]	JEFFREY C, KOPP R J, PORTNEY P R. Energy resources and global development[J]. Science, 2003, 302(5650):1528-1531.
[4]	EDIGER V S, KENTEL E. Renewable energy potential as an alternative to fossil fuels in Turkey[J]. Energy Conversion & Management, 1999, 40(7):743-755.
[5]	LOGAN B E. Exoelectrogenic bacteria that power microbial fuel cells[J]. Nature Reviews Microbiology, 2009, 7(5):375-781.
[6]	LI C, ZHANG L, DING L, et al. Effect of conductive polymers coated anode on the performance of microbial fuel cells (MFCs) and its biodiversity analysis[J]. Biosensors & Bioelectronics, 2011, 26(10):4169-4176.
[7]	KUMAR G G, SARATHI V G S, NAHM K S. Recent advances and challenges in the anode architecture and their modifications for the applications of microbial fuel cells[J]. Biosensors & Bioelectronics, 2013, 43:461-75.
[8]	OLIVEIRA V B, SIMOES M, MELO L F, et al. Overview on the developments of microbial fuel cells[J]. Biochemical Engineering Journal, 2013, 73(8):53-64.
[9]	NOVOSELOV K S, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696):666-669.
[10]	GOMEZ-NAVARRO, WEITZ R T, BITTNER A M, et al. Electronic transport properties of individual chemically reduced graphene oxide sheets[J]. Nano Letters, 2007, 7(11):3499-3503.
[11]	CHITARA B, KRUPANIDHI S B, RAO C N R. Solution processed reduced graphene oxide ultraviolet detector[J]. Applied Physics Letters, 2011, 99(11):113114-3.
[12]	NOVOSELOV K S. The rise of graphene[J]. Nature Materials, 2007, 6(3):183-191.
[13]	LIN L Y. A novel core-shell multi-walled carbon nanotube@graphene oxide nanoribbon heterostructure as a potential supercapacitor material[J]. Journal of Materials Chemistry A, 2013, 1(37):11237-11245.
[14]	LOH K P, BAO Q, EDA G, et al. Graphene oxide as a chemically tunable platform for optical applications[J]. Nature Chemistry, 2010, 2(12):1015-1024.
[15]	WANG H, HAO Q, YANG X, et al. Graphene oxide doped polyaniline for supercapacitors[J]. Electrochemistry Communications, 2009, 11(6):1158-1161.
[16]	ZHANG Y, MO G, LI X, et al. A graphene modified anode to improve the performance of microbial fuel cells[J]. Journal of Power Sources, 2011, 196(13):5402-5407.
[17]	DA C, LONGHUA T, JINGHONG L. Graphene-based materials in electrochemistry[J]. Chemical Society Reviews, 2010, 39(8):3157-3180.
[18]	JING L, YAN Q, GUO C X, et al. Graphene/carbon cloth anode for high-performance mediatorless microbial fuel cells[J]. Bioresource Technology, 2012, 114(3):275-280.
[19]	YUAN Y, ZHOU S, ZHAO B, et al. Microbially-reduced graphene scaffolds to facilitate extracellular electron transfer in microbial fuel cells[J]. Bioresource Technology, 2012, 116:453-458.
[20]	TANG J, CHEN S, YONG Y, et al. In situ formation of graphene layers on graphite surfaces for efficient anodes of microbial fuel cells[J]. Biosensors & Bioelectronics, 2015, 71:387-395.
[21]	ZHANG K, ZHANG L, ZHAO X, et al. Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J]. Chemistry of Materials, 2010, 22(4):1392-1401.
[22]	YONG Y C, DONG X C, CHAN-PARK M B, et al. Macroporous and monolithic anode based on polyaniline hybridized three-dimensional graphene for high-performance microbial fuel cells[J]. ACS Nano, 2012, 6(3):2394-2400.
[23]	WANG Y, ZHAO C E, SUN D, et al. A graphene/poly(3,4-ethylenedioxythiophene) hybrid as an anode for high-performance microbial fuel cells[J]. Chempluschem, 2013, 78(8):823-829.
[24]	LV Z, CHEN Y, WEI H, et al. One-step electrosynthesis of polypyrrole/graphene oxide composites for microbial fuel cell application[J]. Electrochimica Acta, 2013, 111(6):366-373.
[25]	UWE S, JULIANE N, FRITZ S. A generation of microbial fuel cells with current outputs boosted by more than one order of magnitude[J]. Angewandte Chemie, 2003, 42(25):2880-2883.
[26]	PRASAD D, ARUN S A, PADMANABAN S, et al. Direct electron transfer with yeast cells and construction of a mediatorless microbial fuel cell[J]. Biosensors & Bioelectronics, 2007, 22(11):2604-2610.
[27]	YUAN Y, KIM S H. Improved performance of a microbial fuel cell with polypyrrole/carbon black composite coated carbon paper anodes[J]. Bulletin-Korean Chemical Society, 2008, 29(29):1344-1348.
[28]	FENG C, MA L, LI F, et al. A polypyrrole/anthraquinone-2,6-disulphonic disodium salt (PPy/AQDS)-modified anode to improve performance of microbial fuel cells[J]. Biosensors & Bioelectronics, 2010, 25(6):1516-1520.
[29]	KELLY T L, YANO K, WOLF M O. Supercapacitive properties of PEDOT and carbon colloidal microspheres[J]. ACS Applied Materials & Interfaces, 2009, 1(11):2536-2543.
[30]	YONG H K, SACHSE C, MACHALA M L, et al. Highly conductive PEDOT:PSS electrode with optimized solvent and thermal post-treatment for ITO-free organic solar cells[J]. Advanced Functional Materials, 2011, 21(6):1076-1081.
[31]	刘兴倩, 王许云, 郭庆杰. PEDOT/MWCNTs复合阳极的制备及在MFC中的应用[J]. 化工学报, 2013, 64(5):1773-1779. LIU X Q, WANG X Y, GUO Q J. Preparation and application of PEDOT/MWCNTs composite anode for MFC[J]. CIESC Journal, 2013, 64(5):1773-1779.
[32]	STANKOVICH S, DIKIN D A, PINER R D, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J]. Carbon, 2007, 45(7):1558-1565.
[33]	FERRARI A C. Raman spectroscopy of graphene and graphite:disorder, electron-phonon coupling, doping and nonadiabatic effects[J]. Solid State Communications, 2007, 143(1):47-57.

GO/PEDOT复合材料修饰阳极的制备及其在MFC中的应用

Preparation and application of GO/PEDOT composite anode for MFC

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 33

相关文章 15

编辑推荐

Metrics

本文评价

[1]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[2]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[3]	胡兴枝, 张皓焱, 庄境坤, 范雨晴, 张开银, 向军. 嵌有超小CeO₂纳米粒子的碳纳米纤维的制备及其吸波性能[J]. 化工学报, 2023, 74(8): 3584-3596.
[4]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[5]	张琦钰, 高利军, 苏宇航, 马晓博, 王翊丞, 张亚婷, 胡超. 碳基催化材料在电化学还原二氧化碳中的研究进展[J]. 化工学报, 2023, 74(7): 2753-2772.
[6]	葛加丽, 管图祥, 邱新民, 吴健, 沈丽明, 暴宁钟. 垂直多孔碳包覆的FeF₃正极的构筑及储锂性能研究[J]. 化工学报, 2023, 74(7): 3058-3067.
[7]	屈园浩, 邓文义, 谢晓丹, 苏亚欣. 活性炭/石墨辅助污泥电渗脱水研究[J]. 化工学报, 2023, 74(7): 3038-3050.
[8]	张澳, 罗英武. 低模量、高弹性、高剥离强度丙烯酸酯压敏胶[J]. 化工学报, 2023, 74(7): 3079-3092.
[9]	王杰, 丘晓琳, 赵烨, 刘鑫洋, 韩忠强, 许雍, 蒋文瀚. 聚电解质静电沉积改性PHBV抗氧化膜的制备与性能研究[J]. 化工学报, 2023, 74(7): 3068-3078.
[10]	张蒙蒙, 颜冬, 沈永峰, 李文翠. 电解液类型对双离子电池阴阳离子储存行为的影响[J]. 化工学报, 2023, 74(7): 3116-3126.
[11]	崔张宁, 胡紫璇, 吴雷, 周军, 叶干, 刘田田, 张秋利, 宋永辉. 可降解纤维素基材料的耐水性能研究进展[J]. 化工学报, 2023, 74(6): 2296-2307.
[12]	李振, 张博, 王丽伟. PEG-EG固-固相变材料的制备和性能研究[J]. 化工学报, 2023, 74(6): 2680-2688.
[13]	张谭, 刘光, 李晋平, 孙予罕. Ru基氮还原电催化剂性能调控策略[J]. 化工学报, 2023, 74(6): 2264-2280.
[14]	蔡斌, 张效林, 罗倩, 党江涛, 左栗源, 刘欣梅. 导电薄膜材料的研究进展[J]. 化工学报, 2023, 74(6): 2308-2321.
[15]	代佳琳, 毕唯东, 雍玉梅, 陈文强, 莫晗旸, 孙兵, 杨超. 热物性对混合型CPCMs固液相变特性影响模拟研究[J]. 化工学报, 2023, 74(5): 1914-1927.