氯代有机物污染场地的监控自然衰减修复初探

doi:10.11949/j.issn.0438-1157.20150003

化工学报 ›› 2015, Vol. 66 ›› Issue (7): 2361-2369.DOI: 10.11949/j.issn.0438-1157.20150003

氯代有机物污染场地的监控自然衰减修复初探

陈然然¹, 祝欣^2,3, 林玉锁^2,3, 余冉¹, 龙涛^2,3

1 东南大学能源与环境学院, 江苏南京 210096;
2 环境保护部南京环境科学研究所, 江苏南京 210042;
3 国家环境保护土壤环境管理与污染控制重点实验室, 江苏南京 210042

收稿日期:2015-01-04 修回日期:2015-03-08 出版日期:2015-07-05 发布日期:2015-07-05
通讯作者: 余冉, 龙涛
基金资助:
国家高技术研究发展计划项目(SS2013AA062608);国家环境保护土壤环境管理与污染控制重点实验室开放基金(2014)。

Preliminary inquiry of monitored natural attenuation remediation of chlorinated organic compounds contaminated sites

CHEN Ranran¹, ZHU Xin^2,3, LIN Yusuo^2,3, YU Ran¹, LONG Tao^2,3

1 School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu, China;
2 Nanjing Institute of Environmental Sciences, Ministry of Environmental Protection of China, Nanjing 210042, Jiangsu, China;
3 State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing 210042, Jiangsu, China

Received:2015-01-04 Revised:2015-03-08 Online:2015-07-05 Published:2015-07-05
Supported by:
supported by the National High Technology Research and Development Program of China(SS2013AA062608)and the National Environmental Protection Soil Environmental Management and Pollution Control Key Laboratory Open Fund of China (2014).

摘要/Abstract

摘要：

氯代有机物因其高毒性、高富集性、高环境残留的特点及其“致癌、致畸、致突变”效应被美国环保局(EPA)列为优先控制污染物。氯代有机物污染场地的传统物理、化学、生物修复方式修复费用相对较高,对污染场地周边环境影响较大。监控自然衰减(MNA)是一种国际上应用较广的污染场地修复和管理技术,近年来在我国逐渐得到关注,其利用污染物自身的自然衰减作用达到修复目标,从而降低修复成本,规避工程风险。本文重点介绍监控自然衰减技术,并结合氯代有机物自然衰减过程中的生物降解作用、降解途径与机理、主要降解菌和酶等要素对氯代有机物污染场地实施监控自然衰减修复的可行性进行初步探究。

关键词: 氯代有机物, 污染场地, MNA, 自然衰减, 修复, 生物过程, 降解

Abstract:

Due to the high toxicity, potential of biological accumulation, recalcitrance to degradation and the known carcinogenic/teratogenic/mutagenic effects, the chlorinated organic compounds have been listed as priority controlled pollutants by the United States Environmental Protection Agency (EPA). In view of chlorinated pollutants contaminated sites, the traditional physical, chemical and biological remediation methods often impose relatively high costs and considerable impacts on the surrounding environment. The monitored natural attenuation (MNA) is an effective technology for site remediation and management and has been widely used internationally, which gradually attracts more and more attentions in China in recent years. It relies on the intrinsic potential of the pollutants to degrade naturally to meet the remediation requirements, and thereby would reduce treatment costs and lower on-site project risks. This paper focuses on the introduction of MNA technology, as well as the characteristics of chlorinated organic compounds such as the biodegradation pathways and mechanisms during the process of natural attenuation, the main degradation microbial communities and the key biodegradation enzymes. A preliminary discussion on the suitability of implementing MNA remediation on chlorinated organic compounds contaminated sites is provided.

Key words: chlorinated organics compounds, contaminated site, MNA, natural attenuation, remediation, bioprocess, degradation

中图分类号:

陈然然, 祝欣, 林玉锁, 余冉, 龙涛. 氯代有机物污染场地的监控自然衰减修复初探[J]. 化工学报, 2015, 66(7): 2361-2369.

CHEN Ranran, ZHU Xin, LIN Yusuo, YU Ran, LONG Tao. Preliminary inquiry of monitored natural attenuation remediation of chlorinated organic compounds contaminated sites[J]. CIESC Journal, 2015, 66(7): 2361-2369.

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氯代有机物污染场地的监控自然衰减修复初探

Preliminary inquiry of monitored natural attenuation remediation of chlorinated organic compounds contaminated sites

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