抗坏血酸对Fe2+/H2O2体系氧化NO的促进作用

doi:10.11949/j.issn.0438-1157.20141920

化工学报 ›› 2015, Vol. 66 ›› Issue (7): 2636-2642.DOI: 10.11949/j.issn.0438-1157.20141920

抗坏血酸对Fe²⁺/H₂O₂体系氧化NO的促进作用

赵海谦^1,2, 高继慧¹, 周伟¹, 王忠华², 吴少华¹

1 哈尔滨工业大学能源科学与工程学院, 黑龙江哈尔滨150001;
2 东北石油大学土木建筑工程学院, 黑龙江大庆 163318

收稿日期:2014-12-26 修回日期:2015-04-08 出版日期:2015-07-05 发布日期:2015-07-05
通讯作者: 高继慧
基金资助:
国家自然科学基金项目(51176043,91434134);黑龙江省青年科学基金项目(QC2014C047)。

Promotion of ascorbic acid on oxidation of NO by Fe²⁺/H₂O₂ system

ZHAO Haiqian^1,2, GAO Jihui¹, ZHOU Wei¹, WANG Zhonghua², WU Shaohua¹

1 College of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China;
2 Institute of Civil Engineering & Architecture, Northeast Petroleum University, Daqing 163318, Heilongjiang, China

Received:2014-12-26 Revised:2015-04-08 Online:2015-07-05 Published:2015-07-05
Supported by:
supported by the National Natural Science Foundation of China (51176043, 91434134) and the Heilongjiang Province Science Funds for Youths (QC2014C047).

摘要/Abstract

摘要：

采用实验方法研究了低成本环境友好型添加剂抗坏血酸(AA)对Fe²⁺/H₂O₂体系氧化NO气体及其对体系内H₂O₂分解的影响,分析了AA对体系氧化NO能力及H₂O₂分解的影响机制。研究结果表明:AA通过加速Fe³⁺向Fe²⁺的转化而促进Fe²⁺/H₂O₂体系对NO的氧化。[AA]₀:[Fe²⁺]₀对体系氧化NO的能力及H₂O₂的分解具有重要影响。综合考虑NO氧化脱除量及H₂O₂消耗量,合理的[AA]₀:[Fe²⁺]₀为1/3~1/2。AA的分次添加方式可大幅度提升体系氧化NO气体的能力。研究结果可望为发展基于H₂O₂为氧化剂的烟气NO绿色氧化技术提供理论基础。

关键词: Fe²⁺/H₂O₂体系, 抗坏血酸, 羟基自由基, 氧化, 一氧化氮

Abstract:

The influences of ascorbic acid (AA), which is a low cost and eco-friendly additive agent, on NO oxidation and H₂O₂ decomposition in Fe²⁺/H₂O₂ system were experimentally studied and their reaction mechanisms analyzed. The results demonstrated that AA can improve oxidation of Fe²⁺/H₂O₂ system for NO through accelerating the reduction from Fe³⁺ to Fe²⁺. [AA]₀:[Fe²⁺]₀ ratio has important effect on oxidization ability and H₂O₂ decomposition of the system. Taken together the amounts of NO oxidized and H₂O₂ decomposition, the appropriate ratio of [AA]₀:[Fe²⁺]₀ should be between 1/3 to 1/2. Batch add of AA can greatly enhance the oxidation ability of Fe²⁺/H₂O₂ system for NO. These results would be a theoretical basis for the development of NO oxidation technology by H₂O₂.

Key words: Fe²⁺/H₂O₂ system, ascorbic acid, hydroxyl radical, oxidation, nitric oxide

中图分类号:

X511

赵海谦, 高继慧, 周伟, 王忠华, 吴少华. 抗坏血酸对Fe²⁺/H₂O₂体系氧化NO的促进作用[J]. 化工学报, 2015, 66(7): 2636-2642.

ZHAO Haiqian, GAO Jihui, ZHOU Wei, WANG Zhonghua, WU Shaohua. Promotion of ascorbic acid on oxidation of NO by Fe²⁺/H₂O₂ system[J]. CIESC Journal, 2015, 66(7): 2636-2642.

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抗坏血酸对Fe²⁺/H₂O₂体系氧化NO的促进作用

Promotion of ascorbic acid on oxidation of NO by Fe²⁺/H₂O₂ system

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