K2CO3活化空心莲子草制备活性炭及表征

doi:10.11949/j.issn.0438-1157.20151656

化工学报 ›› 2016, Vol. 67 ›› Issue (S1): 353-358.DOI: 10.11949/j.issn.0438-1157.20151656

K₂CO₃活化空心莲子草制备活性炭及表征

陈文婷, 冉启成, 蔡献宗, 黎先发, 徐建蓉

西南科技大学生命科学与工程学院, 四川绵阳 621010

收稿日期:2015-11-03 修回日期:2016-01-27 出版日期:2016-08-31 发布日期:2016-08-31
通讯作者: 黎先发,chuly@scu.edu.cn
基金资助:
四川省教育厅重点项目（14ZA0092）；西南科技大学博士基金项目（14zx7155）。

Preparation and characterization of activated carbon from Alternanthera philoxeroides by K₂CO₃ activation

CHEN Wenting, RAN Qicheng, CAI Xianzong, LI Xianfa, XU Jianrong

School of Life Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China

Received:2015-11-03 Revised:2016-01-27 Online:2016-08-31 Published:2016-08-31
Supported by:
supported by the Key Project of Education Department of Sichuan Province (14ZA0092) and the Doctor Foundation of Southwest University of Science and Technology (14zx7155).

摘要/Abstract

摘要：

以入侵生物空心莲子草为原料，以K₂CO₃为活化剂，经一步共混活化法制备活性炭。研究了K₂CO₃与空心莲子草质量比、活化温度及活化时间对活性炭得率及吸附性能的影响。利用扫描电子显微镜（SEM）对不同温度下得到的活性炭进行了表面形貌观察。实验结果表明，K₂CO₃活化空心莲子草的最佳活化条件为：质量比为1.5，活化温度及时间分别为800℃，3.0 h，此时活性炭得率为13.79%，其碘吸附值及亚甲基蓝吸附值分别为1477 mg·g^-1和384 mg·g^-1。当氮气流量在20～100 ml·min^-1范围内变化时，K₂CO₃的回收率相差不大，且其回收率均能达到80%以上。SEM结果表明活化温度对活性炭孔结构具有明显影响。

关键词: 活性炭, 空心莲子草, 制备, 活化, 吸附

Abstract:

A series of activated carbons (ACs) were prepared from Alternanthera philoxeroides (AP) by K₂CO₃ one-step mixing activation. The effects of various process parameters, such as mixing mass ratio of K₂CO₃ to AP, activation temperature and period, on the adsorptive property and the yield of AC were investigated. The surface morphology of AC were characterized with scanning electron microscopy (SEM). The results indicate that the optimized activation conditions were 1.5 of K₂CO₃ to AP mixing mass ratio, 800℃ of activation temperature, 3.0 h of the activation time. The yield, iodine number and methylene blue (MB) number of AC were 13.79%, 1477 mg·g^-1, 384 mg·g^-1, respectively. The recovery ratios of K₂CO₃ were over 80% when the nitrogen flow rate was no more than 100 ml·min^-1. The SEM images of the ACs showed that the activation temperature has obvious effect on the porous structure.

Key words: activated carbon, Alternanthera philoxeroides, preparation, activation, adsorption

中图分类号:

陈文婷, 冉启成, 蔡献宗, 黎先发, 徐建蓉. K₂CO₃活化空心莲子草制备活性炭及表征[J]. 化工学报, 2016, 67(S1): 353-358.

CHEN Wenting, RAN Qicheng, CAI Xianzong, LI Xianfa, XU Jianrong. Preparation and characterization of activated carbon from Alternanthera philoxeroides by K₂CO₃ activation[J]. CIESC Journal, 2016, 67(S1): 353-358.

参考文献 24

[1]	SHI Z Q, ZHANG J, WANG J, et al. Effect of the capacity design of activated carbon cathode on the electrochemical performance of lithium-ion capacitors[J]. Electrochimica Acta, 2015, 153:476-483.
[2]	ISIL GURTEN INAL I, HOLMES S M, BANFORD A, et al. The performance of supercapacitor electrodes developed fromchemically activated carbon produced from waste tea[J]. Applied Surface Science, 2015, 357:696-703.
[3]	ZHAO Z K, WANG X H. Supported phosphotungstic acid catalyst on modified activated carbon for Friedel-Crafts alkenylation of diverse aromatics to their corresponding α-arylstyrenes[J]. Applied Catalysis A:General, 2015, 503:103-111.
[4]	曲健林, 韩敏, 张秀丽, 等. 棉杆活性炭负载Co-B催化剂催化硼氢化钠水解制氢的性能[J]. 化工学报, 2015, 66(1):105-113. DOI:10.11949/j.issn.0438-1157.20140645. QU J L, HAN M, ZHANG X L, et al. Hydrogen generation by sodium borohydride hydrolysis on Co-B catalysts supported on cotton stalk-based activated carbon[J]. CIESC Journal, 2015, 66(1):105-113. DOI:10.11949/j.issn.0438-1157.20140645.
[5]	DENG H, LI G X, YANG H B, et al. Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation[J]. Chemical Engineering Journal, 2010, 163:373-381.
[6]	LI Y T, PI Y T, LU L M, et al. Hierarchical porous active carbon from fallen leaves by synergy of K2CO3 and their supercapacitor performance[J]. Journal of Power Sources, 2015, 299:519-528.
[7]	常瑞英, 王仁卿, 张依然, 等. 入侵植物空心莲子草的入侵机制及综合管理[J]. 生态与农村环境学报, 2013, 29(1):17-23. CHANG R Y, WANG R Q, ZHANG Y R, et al. Invasion mechanism and integrated management of invasive plant Alternanthera philoxeroides[J]. Journal of Ecology and Rural Environment, 2013, 29(1):17-23.
[8]	陈立立, 余岩, 何兴金. 喜旱莲子草在中国的入侵和扩散动态及其潜在分布区预测[J]. 生物多样性, 2008, 16(8):578-585. DOI:10.3724/SP.J.1003.2008.08195. CHEN L L, YU Y, HE X J. Historical invasion and expansion process of Alternanthera philoxeroides and its potential spread in China[J]. Biodiversity Science, 2008, 16(8):578-585. DOI:10.3724/SP.J.1003.2008.08195.
[9]	李丹, 徐丽, 张震, 等. 喜旱莲子草的利用及其生物防治研究[J]. 中国农学通报, 2013, 29(1):71-75. LI D, XU L, ZHANG Z, et al. The research progress on utilization and biological control of Alternanthera philoxeroides[J]. Chinese Agricultural Science Bulletin, 2013, 29(1):71-75.
[10]	郭伟, 李钧敏, 胡正华. 酸雨和采食模拟胁迫下克隆整合对空心莲子草生长的影响[J]. 生态学报, 2012,32(1):151-158. DOI:10. 5846/stxb201011031575. GUO W, LI J M, HU Z H. Effects of clonal integration on growth of Alternanthera philoxeroides under simulated acid rain and herbivory[J]. Acta Ecological Sinica, 2012, 32(1):151-158. DOI:10. 5846/stxb201011031575.
[11]	肖强, 高建明, 罗立廷, 等. 干旱胁迫对空心莲子草抗氧化酶活性和组织学的影响[J]. 生物技术通讯, 2006, 17(4):807-815. XIAO Q, GAO J M, LUO L T, et al. Effects of drought stress on activities of anti-oxidant enzymes and histology in Alternanthera philoxeroides[J]. Letters in Biotechnology, 2006, 17(4):807-815.
[12]	许建平, 张小萍, 曾波, 等. 完全水淹环境中光照和溶氧对喜旱莲子草表型可塑性的影响[J]. 生态学报, 2014, 34(2):258-268. DOI:10. 5846/stxb201301110081. XU J P, ZHANG X P, ZENG B, et al. Effects of light and dissolved oxygen on the phenotypic plasticity of Alternanthera philoxeroides in submergence conditions[J]. Acta Ecologica Sinica, 2014, 34(2):258-268. DOI:10.5846/stxb201301110081.
[13]	SUN Y, DING J, FRYE M J. Effects of resource availability on tolerance of herbivory in the invasive Alternanthera philoxeroides and the native Alternanthera sessilis[J]. Weed Research, 2010, 50:527-536.
[14]	张文艳, 庞静. 空心莲子草的入侵机制及其防治对策[J]. 作物研究, 2013, 27(3):302-306. ZHANG W Y, PANG J. Invasion mechanisms of Alternanthera philoxeroides and its control countermeasures[J]. Crop Research, 2013, 27(3):302-306.
[15]	RANE N R, CHANDANSHIVE V V, WATHARKAR A D, et al. Phytoremediation of sulfonated Remazol Red dye and textile effluents by Alternanthera philoxeroides:an anatomical, enzymatic and pilot scale study[J]. Water Research, 2015, 83:271-281.
[16]	WEI H, LU X M, DING J Q. Direct and indirect impacts of different water regimes on the invasive plant, alligator weed (Alternanthera philoxeroides), and its biological control agent, Agasicles hygrophila[J]. Weed Biology and Management, 2015, 15:1-10.
[17]	LIAO J X, TAO M, JIANG M J. Spatial arrangements affect suppression of invasive Alternanthera philoxeroides by native Hemarthria compressa[J]. Acta Oecologica, 2014, 59:46-51.
[18]	LU J J, ZHAO L L, MA R Y. Non-target plant testing of the flea beetle Agasicles hygrophila, a biological control agent for Alternanthera philoxeroides (alligatorweed) in China[J]. Biocontrol Science and Technology, 2012, 22:1093-1097.
[19]	高宗军, 李美, 高兴祥, 等. 24种除草剂对空心莲子草的生物活性[J]. 中国农学通报, 2010, 26(21):256-261. GAO Z J, LI M, GAO X X, et al. Biological activity of 24 herbicides against Alternanthera philoxeroides (Mart.) Griseb[J]. Chinese Agricultural Science Bulletin, 2010, 26(21):256-261.
[20]	SCHOOLER S S, YEATES A G, WILSON J R U, et al. Herbivory, mowing and herbicides differently affect production and nutrient allocation of Alternanthera philoxeroides[J]. Aquat Bot, 2007, 86:62-68.
[21]	陈燕丽, 陈中义. 空心莲子草入侵控制的生态学研究进展[J]. 湖北农业科学, 2010, 49(9):2260-2263,2267. CHEN Y L, CHEN Z Y. Ecology research progress on invasion control of alligator weed Alternanthera philo-xeroides(Mart.) Griseb[J]. Hubei Agricultural Sciences, 2010, 49(9):2260-2263,2267.
[22]	SMALL C C, HASHISHO Z, ULRICH A C. Preparation and characterisation of activated carbon from oil sands coke[J]. Fuel, 2012, 92:69-76.
[23]	GURTEN I I, OZMAK M, YAGMUR E, et al. Preparation and characterisation of activated carbon from waste tea using K2CO3[J]. Biomass and Bioenergy, 2012, 37:73-81.
[24]	TONGOPOTHORN W, SRIUTTHA M, HOMCHAN P, et al. Preparation of activated carbon derived from Jatropha curcas fruit shell by simple thermo-chemical activation and characterisation of their physico-chemical properties[J]. Chemical Engineering Research and Design, 2011, 89:335-340.

K₂CO₃活化空心莲子草制备活性炭及表征

Preparation and characterization of activated carbon from Alternanthera philoxeroides by K₂CO₃ activation

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献 24

相关文章 15

编辑推荐

Metrics

本文评价

[1]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[2]	胡超, 董玉明, 张伟, 张红玲, 周鹏, 徐红彬. 浓硫酸活化五氧化二钒制备高浓度全钒液流电池正极电解液[J]. 化工学报, 2023, 74(S1): 338-345.
[3]	杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH₃的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755.
[4]	高燕, 伍鹏, 尚超, 胡泽君, 陈晓东. 基于双流体喷嘴的磁性琼脂糖微球的制备及其蛋白吸附性能探究[J]. 化工学报, 2023, 74(8): 3457-3471.
[5]	吕龙义, 及文博, 韩沐达, 李伟光, 高文芳, 刘晓阳, 孙丽, 王鹏飞, 任芝军, 张光明. 铁基导电材料强化厌氧去除卤代有机污染物：研究进展及未来展望[J]. 化工学报, 2023, 74(8): 3193-3202.
[6]	盛冰纯, 于建国, 林森. 铝基锂吸附剂分离高钠型地下卤水锂资源过程研究[J]. 化工学报, 2023, 74(8): 3375-3385.
[7]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[8]	陈吉, 洪泽, 雷昭, 凌强, 赵志刚, 彭陈辉, 崔平. 基于分子动力学的焦炭溶损反应及其机理研究[J]. 化工学报, 2023, 74(7): 2935-2946.
[9]	吴文涛, 褚良永, 张玲洁, 谭伟民, 沈丽明, 暴宁钟. 腰果酚生物基自愈合微胶囊的高效制备工艺研究[J]. 化工学报, 2023, 74(7): 3103-3115.
[10]	王志龙, 杨烨, 赵真真, 田涛, 赵桐, 崔亚辉. 搅拌时间和混合顺序对锂离子电池正极浆料分散特性的影响[J]. 化工学报, 2023, 74(7): 3127-3138.
[11]	屈园浩, 邓文义, 谢晓丹, 苏亚欣. 活性炭/石墨辅助污泥电渗脱水研究[J]. 化工学报, 2023, 74(7): 3038-3050.
[12]	康超, 乔金鹏, 杨胜超, 彭超, 付元鹏, 刘斌, 刘建荣, Aleksandrova Tatiana, 段晨龙. 煤矸石中有价关键金属活化提取研究进展[J]. 化工学报, 2023, 74(7): 2783-2799.
[13]	王杰, 丘晓琳, 赵烨, 刘鑫洋, 韩忠强, 许雍, 蒋文瀚. 聚电解质静电沉积改性PHBV抗氧化膜的制备与性能研究[J]. 化工学报, 2023, 74(7): 3068-3078.
[14]	朱风, 陈凯琳, 黄小凤, 鲍银珠, 李文斌, 刘嘉鑫, 吴玮强, 高王伟. KOH改性电石渣脱除羰基硫的性能研究[J]. 化工学报, 2023, 74(6): 2668-2679.
[15]	卫雪岩, 钱勇. 微米级铁粉燃料中低温氧化反应特性及其动力学研究[J]. 化工学报, 2023, 74(6): 2624-2638.