二甲醚在低到中温的着火延迟特性

doi:10.11949/j.issn.0438-1157.20161513

化工学报 ›› 2017, Vol. 68 ›› Issue (5): 2140-2147.DOI: 10.11949/j.issn.0438-1157.20161513

二甲醚在低到中温的着火延迟特性

张红光^1,2, 石智成^1,2, 高翔^1,2, 李佳政^1,2, 支淑梅^1,2

1 北京工业大学环境与能源工程学院, 北京 100124;
2 北京电动车辆协同创新中心, 北京 100124

收稿日期:2016-10-26 修回日期:2016-12-02 出版日期:2017-05-05 发布日期:2017-05-05
通讯作者: 张红光
基金资助:
国家自然科学基金项目（51376011）；北京市自然科学基金项目（3152005）；北京市教育委员会科技计划重点项目（KZ201410005003）。

Ignition delay characteristics of dimethyl ether under low-to-medium temperature ranges

ZHANG Hongguang^1,2, SHI Zhicheng^1,2, GAO Xiang^1,2, LI Jiazheng^1,2, ZHI Shumei^1,2

1 College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China;
2 Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100124, China

Received:2016-10-26 Revised:2016-12-02 Online:2017-05-05 Published:2017-05-05
Supported by:
supported by the National Natural Science Foundation of China (51376011), the Natural Science Foundation of Beijing (3152005) and the Scientific Research Key Program of Beijing Municipal Commission of Education (KZ201410005003).

摘要/Abstract

摘要：

在上止点温度656～814 K，上止点压力1.2～3.5 MPa，当量比（φ）0.83～1.25实验条件下，利用快速压缩机（RCM）研究了上止点压力和燃料浓度对二甲醚着火延迟期的影响及二甲醚三阶段燃烧现象。利用CHEMKIN-PRO软件在更宽广温度范围内对混合气着火延迟进行了同等条件下的模拟计算及反应动力学分析。结果表明：随着上止点压力及燃料浓度的增加，第1阶段着火延迟期均略有缩短，总着火延迟期明显缩短；二甲醚总着火延迟期存在明显的负温度系数（NTC）现象，且在较低上止点压力和燃料浓度下NTC现象更加明显；在稀燃条件下（φ=0.83）二甲醚混合气出现低温放热和高温两阶段放热的三阶段放热现象，其高温第1阶段放热主要由CH₂O生成大量CO引起，高温第2阶段放热主要由生成燃烧最终产物CO₂和H₂O引起。

关键词: 压缩机, 燃料, 着火延迟期, 反应动力学

Abstract:

Effects of the compressed pressure and fuel concentration on ignition delay of DME mixture were investigated using a rapid compressor at compressed temperature of 656—814 K, compressed pressure of 1.2—3.5 MPa and equivalence ratio (φ) of 0.83—1.25. Kinetics model was built to predict the ignition delay and simulate the combustion process using CHEMKIN-PRO software, meanwhile, reaction kinetics analysis was conducted. The results show that with increasing compressed pressure and fuel concentration, the first-stage ignition delay decreases slightly, while a significant decrease in the total ignition delay is observed. The ignition delay of DME presents well known negative temperature coefficient (NTC) and which is noted to become more prominent at lower compressed pressure and fuel concentration. DME mixture presents three-stage heat release at lean-fuel(φ=0.83), which includes low-temperature heat release and a two-stage high temperature heat release. Kinetics analysis indicates that the first-stage high temperature heat release is mainly caused by the production of CO from CH₂O, and the reactions produce CO₂ and H₂O contribute to the second-stage high temperature heat release.

Key words: compressor, fuel, ignition delay, reaction kinetics

中图分类号:

TK401

张红光, 石智成, 高翔, 李佳政, 支淑梅. 二甲醚在低到中温的着火延迟特性[J]. 化工学报, 2017, 68(5): 2140-2147.

ZHANG Hongguang, SHI Zhicheng, GAO Xiang, LI Jiazheng, ZHI Shumei. Ignition delay characteristics of dimethyl ether under low-to-medium temperature ranges[J]. CIESC Journal, 2017, 68(5): 2140-2147.

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二甲醚在低到中温的着火延迟特性

Ignition delay characteristics of dimethyl ether under low-to-medium temperature ranges

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